The Contribution of Cr and Ni to hydrogen absorption energy in Fe-Cr-Ni austenitic systems; A First-principles study

Moriyama, Junichiro*; Takakuwa, Osamu*; Yamaguchi, Masatake; Ogawa, Yuhei*; Tsuzaki, Kaneaki*

Computational Materials Science, 232, p.112650_1 - 112650_11, 2024/01

https://doi.org/10.1016/j.commatsci.2023.112650

The present study focuses on a novel hydrogen-improved strength-ductility balance in some practical Fe-Cr-Ni-based austenitic alloys, which directly depends on the solute hydrogen content. The hydrogen absorption energy of the Fe-Cr-Ni model alloys with the face-centered cubic structure was examined using first-principles calculations to verify the contribution of Cr and Ni substitutions from Fe to the hydrogen solubility in the alloys. The Cr substitution substantially reduced the hydrogen absorption energy compared to the Ni substitution, whereby the increased Cr/Ni ratio exerts higher hydrogen solubility. The propensity in the calculations coincided with the experimental results obtained previously in the practical alloys with various Cr / Ni ratios.

Interlaboratory comparison of electron paramagnetic resonance tooth enamel dosimetry with investigations of the dose responses of the standard samples

Toyoda, Shin*; Inoue, Kazuhiko*; Yamaguchi, Ichiro*; Hoshi, Masaharu*; Hirota, Seiko*; Oka, Toshitaka; Shimazaki, Tatsuya*; Mizuno, Hideyuki*; Tani, Atsushi*; Yasuda, Hiroshi*; et al.

Radiation Protection Dosimetry, 199(14), p.1557 - 1564, 2023/09

https://doi.org/10.1093/rpd/ncad150

Interlaboratory comparison studies are important for radiation dosimetry in order to demonstrate how the technique is universally available. The set of standard samples are examined in each participating laboratory in the present study. After a set of standard samples together with the samples with unknown doses, which were prepared in the same laboratory as the standard samples, are measured at a participating laboratory, those samples are sent to another participating laboratory for next measurement. There is some small difference observed in the sensitivity (the slope of the dose response line) of the standard samples while the differences in the obtained doses for the samples with unknown doses are rather systematic, implying that the difference is mostly due to the samples but not to measurements.

Reports of electro-polishing implementation for quarter-wave resonators, 2

Nii, Keisuke*; Ida, Yoshiaki*; Ueda, Hideki*; Yamaguchi, Takanori*; Kabumoto, Hiroshi; Kamiya, Junichiro; Kondo, Yasuhiro; Tamura, Jun; Harada, Hiroyuki; Matsui, Yutaka; et al.

Proceedings of 19th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.601 - 604, 2023/01

no abstracts in English

Activity review of Working Group on Accidents Relating X-ray Equipment, Japan Health Physics Society

Igarashi, Yu; Yamaguchi, Ichiro*; Oda, Keiji*; Fukushi, Masahiro*; Sakama, Minoru*; Iimoto, Takeshi*

Nihon Hoshasen Anzen Kanri Gakkai-Shi, 21(2), p.74 - 76, 2022/11

https://doi.org//10.11269/jjrsm.21.69

no abstracts in English

Thermally altered subsurface material of asteroid (162173) Ryugu

Kitazato, Kohei*; Milliken, R. E.*; Iwata, Takahiro*; Abe, Masanao*; Otake, Makiko*; Matsuura, Shuji*; Takagi, Yasuhiko*; Nakamura, Tomoki*; Hiroi, Takahiro*; Matsuoka, Moe*; et al.

Nature Astronomy (Internet), 5(3), p.246 - 250, 2021/03

https://doi.org/10.1038/s41550-020-01271-2

Here we report observations of Ryugu's subsurface material by the Near-Infrared Spectrometer (NIRS3) on the Hayabusa2 spacecraft. Reflectance spectra of excavated material exhibit a hydroxyl (OH) absorption feature that is slightly stronger and peak-shifted compared with that observed for the surface, indicating that space weathering and/or radiative heating have caused subtle spectral changes in the uppermost surface. However, the strength and shape of the OH feature still suggests that the subsurface material experienced heating above 300 C, similar to the surface. In contrast, thermophysical modeling indicates that radiative heating does not increase the temperature above 200 C at the estimated excavation depth of 1 m, even if the semimajor axis is reduced to 0.344 au. This supports the hypothesis that primary thermal alteration occurred due to radiogenic and/or impact heating on Ryugu's parent body.

The Surface composition of asteroid 162173 Ryugu from Hayabusa2 near-infrared spectroscopy

Kitazato, Kohei*; Milliken, R. E.*; Iwata, Takahiro*; Abe, Masanao*; Otake, Makiko*; Matsuura, Shuji*; Arai, Takehiko*; Nakauchi, Yusuke*; Nakamura, Tomoki*; Matsuoka, Moe*; et al.

Science, 364(6437), p.272 - 275, 2019/04

https://doi.org/10.1126/science.aav7432

The near-Earth asteroid 162173 Ryugu, the target of Hayabusa2 sample return mission, is believed to be a primitive carbonaceous object. The Near Infrared Spectrometer (NIRS3) on Hayabusa2 acquired reflectance spectra of Ryugu's surface to provide direct measurements of the surface composition and geological context for the returned samples. A weak, narrow absorption feature centered at 2.72 micron was detected across the entire observed surface, indicating that hydroxyl (OH)-bearing minerals are ubiquitous there. The intensity of the OH feature and low albedo are similar to thermally- and/or shock-metamorphosed carbonaceous chondrite meteorites. There are few variations in the OH-band position, consistent with Ryugu being a compositionally homogeneous rubble-pile object generated from impact fragments of an undifferentiated aqueously altered parent body.

Structure of active sites of Fe-N-C nano-catalysts for alkaline exchange membrane fuel cells

Kishi, Hirofumi*; Sakamoto, Tomokazu*; Asazawa, Koichiro*; Yamaguchi, Susumu*; Kato, Takeshi*; Zulevi, B.*; Serov, A.*; Artyushkova, K.*; Atanassov, P.*; Matsumura, Daiju; et al.

Nanomaterials (Internet), 8(12), p.965_1 - 965_13, 2018/12

https://doi.org/10.3390/nano8120965

Development of a method of safety assessment for geological disposal considering long-term evolution of geological and topographical environment by uplift and erosion

Wakasugi, Keiichiro; Yamaguchi, Masaaki; Koo, Shigeru*; Nagao, Fumiya; Kato, Tomoko; Suzuki, Yuji*; Ebashi, Takeshi; Umeki, Hiroyuki*; Niibori, Yuichi*

Nihon Genshiryoku Gakkai Wabun Rombunshi, 16(1), p.15 - 33, 2017/03

https://doi.org/10.3327/taesj.J16.010

This study provides a method of safety assessment for the geological disposal of HLW to evaluate the effects of uplift and erosion which are widespread phenomena identified on regional and global scales, and are more or less difficult to avoid in Japan. This method enables to deal with different uplift rate and erosion rate, and to evaluate repository depth, the time required for a repository to reach the weathered zone and surface of the ground, and the number of waste packages eroded as a function of time by using a landform evolution model. Based on trial analysis, the result shows that the maximum dose in the Base Case (uplift rate: 0.3 mm/y) is less than the targeted criterion suggested by the international organization even if the repository reaches the ground surface. Furthermore, the diversifying effect on timing the waste packages to reach to weathered zone due to heterogeneity on altitude of bottom of weathered zone reduces one order magnitude of result of the existed dose assessment. The new method is applicable to evaluate safety of geological disposal based on realistic phenomena of uplift and erosion and to quantify a safety margin and robustness of the disposal system.

On-site monitoring method of radioactive cesium in water sample using cesium adsorption disk and GM survey meter

Nagano, Tetsushi; Mitamura, Hisayoshi; Yanase, Nobuyuki; Naganawa, Hirochika; Yasuda, Kenichiro; Yamaguchi, Hiroaki*

Hoshasei Busshitsu No Kyuchaku, Josen Oyobi Taihoshasen Gjutsu Ni Okeru Zairyo, Seko, Sokutei No Shin Gijutsu, p.400 - 408, 2014/11

A method for monitoring radioactive cesium concentration in water using a cesium adsorption disk and a GM survey meter has been developed to ascertain whether the water quality meets standards on radiological contaminants in water. This method was successfully applied to monitoring of decontaminated water of an outdoor school swimming pool in Date City after Fukushima Daiichi Nuclear Power Plant accident.

Adsorption of H atoms on cubic ErO (001) surface; A DFT study

Mao, W.*; Chikada, Takumi*; Shimura, Kenichiro*; Suzuki, Akihiro*; Yamaguchi, Kenji; Terai, Takayuki*

Journal of Nuclear Materials, 443(1-3), p.555 - 561, 2013/11

https://doi.org/10.1016/j.jnucmat.2013.08.017

In this work, calculations based on density functional theory (DFT) and generalized gradient approximation were performed to investigate the structural and electronic properties of the cubic ErO (001) surface and H adsorption processes on this surface. Several stable adsorption sites were identified, and at the most energetically favorable adsorption sites it was found that H bonds with O atoms at the cubic ErO (001) surface with an adsorption energy of 295.68 kJ mol at coverage 1/8 ML, which was inclined to decrease with the increase of H coverage ( 1/4 ML). In addition, the calculations revealed that the dissociative H atom configurations have adsorption energies that are at least 152.64 kJ mol greater than the H molecule configurations on the surface. These results are discussed in regard of the hydrogen isotope permeation behavior in the tritium permeation barrier in a fusion reactor.