Experimental evidence for the existence of a second partially-ordered phase of ice VI

Yamane, Ryo*; Komatsu, Kazuki*; Gochi, Jun*; Uwatoko, Yoshiya*; Machida, Shinichi*; Hattori, Takanori; Ito, Hayate*; Kagi, Hiroyuki*

Nature Communications (Internet), 12, p.1129_1 - 1129_6, 2021/02

https://doi.org/10.1038/s41467-021-21351-9

Ice exhibits extraordinary structural variety in its polymorphic structures. The existence of a new form of diversity in ice polymorphism has recently been debated in both experimental and theoretical studies, questioning whether hydrogen-disordered ice can transform into multiple hydrogen-ordered phases, contrary to the known one-to-one correspondence between disordered ice and its ordered phase. Here we report a new high-pressure phase, ice XIX, which is a second hydrogen-ordered phase of ice VI. This is the first discovery to demonstrate that disordered ice undergoes different manners of hydrogen ordering. Such multiplicity can appear in all disordered ice, and it widely provides a new research approach to deepen our knowledge, for example of the crucial issues of ice: the centrosymmetry of hydrogen-ordered configurations and potentially induced (anti-)ferroelectricity. Ultimately, this research opens up the possibility of completing the phase diagram of ice.

Ice I without stacking disorder by evacuating hydrogen from hydrogen hydrate

Komatsu, Kazuki*; Machida, Shinichi*; Noritake, Fumiya*; Hattori, Takanori; Sano, Asami; Yamane, Ryo*; Yamashita, Keishiro*; Kagi, Hiroyuki*

Nature Communications (Internet), 11, p.464_1 - 464_5, 2020/02

https://doi.org/10.1038/s41467-020-14346-5

Water freezes below 0C at ambient pressure ordinarily to ice I, with hexagonal stacking sequence. Under certain conditions, ice with a cubic stacking sequence can also be formed, but ideal ice I without stacking-disorder has never been formed until recently. Here we demonstrate a route to obtain ice I without stacking-disorder by degassing hydrogen from the high-pressure form of hydrogen hydrate, C, which has a host framework isostructural with ice I. The stacking-disorder free ice I is formed from C via an intermediate amorphous or nano-crystalline form under decompression, unlike the direct transformations occurring in ice XVI from neon hydrate, or ice XVII from hydrogen hydrate. The obtained ice I shows remarkable thermal stability, until the phase transition to ice I at 250 K, originating from the lack of dislocations. This discovery of ideal ice I will promote understanding of the role of stacking-disorder on the physical properties of ice as a counter end-member of ice I.

Development of laser system for a proof-of-principle experiment of laser stripping injection

Harada, Hiroyuki; Saha, P. K.; Yoneda, Hitoki*; Michine, Yurina*; Inoue, Shunsuke*; Sato, Atsushi*; Suganuma, Kazuaki; Yamane, Isao*; Kinsho, Michikazu; Irie, Yoshiro*

Proceedings of 15th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.811 - 815, 2018/08

https://www.pasj.jp/web_publish/pasj2018/proceedings/PDF/THP0/THP017.pdf

The high-intensity proton accelerator adopts a charge exchange injection scheme, which injects with exchanging from negative Hydrogen ion to proton by using carbon foil. This scheme can realize high intensity proton beam but the uncontrolled beam losses occur by scattering at the foil. Additionally, the beam collision at the foil may cause the break itself. Therefore, a new injection scheme for higher intensity is needed as an alternative to the foil. We newly propose and develop a laser stripping injection scheme. At the first step, we propose a proof-of-principle (POP) experiment of the scheme in J-PARC and develop a laser system. In this presentation, we will introduce the laser stripping injection scheme and describe an overview of a POP experiment. We will report a current status of the laser system.

Laser storage ring with high power for realization of laser stripping injection

Harada, Hiroyuki; Yamane, Isao*; Saha, P. K.; Suganuma, Kazuaki; Kinsho, Michikazu; Irie, Yoshiro*; Kato, Shinichi

Proceedings of 14th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.684 - 688, 2017/12

http://www.pasj.jp/web_publish/pasj2017/proceedings/PDF/TUP1/TUP117.pdf

The high-intensity proton accelerator adopts a charge exchange injection scheme, which injects with exchanging from negative Hydrogen ion to proton by using carbon foil. This scheme can realize high intensity proton beam but the uncontrolled beam losses are caused by scattering between beams and the foil. Additionally, the collision may occur the foil beak. Therefore, a new injection scheme for higher intensity is needed as an alternative to the foil. In the J-PARC 3GeV RCS, we newly propose and develop a laser stripping injection scheme. However, it is necessary that laser power is two order higher than latest laser one. To realize this big issue, we develop the laser storage ring, which can provide laser pulse of high repetition rate by recycling one. In this presentation, we will introduce the laser stripping injection scheme and describe the concept of the laser storage ring with high repetition rate and report the current status.

Laser storage ring with high power for realization of laser stripping injection

Harada, Hiroyuki; Saha, P. K.; Yamane, Isao*; Kato, Shinichi; Kinsho, Michikazu; Irie, Yoshiro*

Proceedings of 13th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.983 - 986, 2016/11

http://www.pasj.jp/web_publish/pasj2016/proceedings/PDF/TUP0/TUP051.pdf

The high-intensity proton accelerator adopts a charge exchange injection scheme, which injects with exchanging from negative Hydrogen ion to proton by using carbon foil. This scheme can realize high intensity proton beam but the uncontrolled beam losses are caused by scattering between beams and the foil. Additionally, the collision may occur the foil beak. Therefore, a new injection scheme for higher intensity is needed as an alternative to the foil. In the J-PARC 3GeV RCS, we newly propose and develop a laser stripping injection scheme However, it is necessary that laser power is two order higher than latest laser one. To realize this big issue, we develop the laser storage ring, which can provide laser pulse of high repetition rate by recycling one. In this presentation, we will introduce the laser stripping injection scheme and describe the concept of the laser storage ring with high repetition rate.

Partially ordered state of ice XV

Komatsu, Kazuki*; Noritake, Fumiya*; Machida, Shinichi*; Sano, Asami; Hattori, Takanori; Yamane, Ryo*; Kagi, Hiroyuki*

Scientific Reports (Internet), 6, p.28920_1 - 28920_11, 2016/07

https://doi.org/10.1038/srep28920

We investigate in-situ neutron diffraction measurements and density functional theory calculations to revisit the structure and stability of ice XV. We find that none of the completely ordered configurations are particular favored; instead, partially ordered states are established as a mixture of ordered domains in disordered ice VI. This scenario in which several kinds of ordered configuration coexist dispels the contradictions in previous studies. It means that the order disorder pairs in ice polymorphs are not one-to-one correspondent pairs but rather have one-to-n correspondence, where there are possible configurations at finite temperature.

Progress of 400 MeV H stripping to protons by using lasers at J-PARC RCS

Saha, P. K.; Harada, Hiroyuki; Kinsho, Michikazu; Miura, Akihiko; Yamane, Isao*

no journal, ,