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Journal Articles

Estimation of external dose for wild Japanese macaques captured in Fukushima prefecture; Decomposition of electron spin resonance spectrum

Mitsuyasu, Yusuke*; Oka, Toshitaka; Takahashi, Atsushi*; Kino, Yasushi*; Okutsu, Kenichi*; Sekine, Tsutomu*; Yamashita, Takuma*; Shimizu, Yoshinaka*; Chiba, Mirei*; Suzuki, Toshihiko*; et al.

Radiation Protection Dosimetry, 199(14), p.1620 - 1625, 2023/09

 Times Cited Count:0 Percentile:0.01(Environmental Sciences)

We have been conducting dose assessments for Japanese macaques captured in Fukushima to reveal radiobiological effects on the low-dose expose animals. To accurately determine the external exposure dose, it is desirable to examine the analysis of the CO$$_{2}^{-}$$ radical intensity. We examined ESR spectra of teeth of 10 macaques captured in Fukushima by two spectrum-decomposition algorithms.

Journal Articles

Comprehensive analysis and evaluation of Fukushima Daiichi Nuclear Power Station Unit 3

Yamashita, Takuya; Honda, Takeshi*; Mizokami, Masato*; Nozaki, Kenichiro*; Suzuki, Hiroyuki*; Pellegrini, M.*; Sakai, Takeshi*; Sato, Ikken; Mizokami, Shinya*

Nuclear Technology, 209(6), p.902 - 927, 2023/06

 Times Cited Count:2 Percentile:87.3(Nuclear Science & Technology)

Journal Articles

A Study on accuracy of analysis of the radiation-induced component in the ESR spectra of teeth

Mitsuyasu, Yusuke*; Oka, Toshitaka; Takahashi, Atsushi*; Kino, Yasushi*; Okutsu, Kenichi*; Sekine, Tsutomu*; Yamashita, Takuma*; Shimizu, Yoshinaka*; Chiba, Mirei*; Suzuki, Toshihiko*; et al.

KEK Proceedings 2022-2, p.120 - 125, 2022/11

We investigate the effect of sample's anisotropy and measurement condition to obtain the higher reproducibility for the shape of the ESR spectrum and the intensity of CO$$_{2}^{-}$$ radical.

Journal Articles

Radiation exposure and oxidative stress status of wild Japanese macaques in the ex-evacuation zone of the Fukushima Daiichi Nuclear Power Plant accident

Ishikawa, Ryoya*; Suzuki, Masatoshi*; Kino, Yasushi*; Endo, Satoru*; Nakajima, Hiroo*; Oka, Toshitaka; Takahashi, Atsushi*; Shimizu, Yoshinaka*; Suzuki, Toshihiko*; Shinoda, Hisashi*; et al.

KEK Proceedings 2022-2, p.61 - 66, 2022/11

The balance between oxidative stress and antioxidant activity, which is a defense mechanism against oxidative stress, was investigated in the liver and bladder of wild Japanese macaques captured in Fukushima Prefecture. No significant induction of oxidative stress by exposure to environmental radionuclides after the Fukushima nuclear accident was observed, suggesting that the stress defense mechanism of the organism is activated in some organs.

Journal Articles

Development of dose estimation method using wild animal teeth for low dose exposure

Mitsuyasu, Yusuke*; Oka, Toshitaka; Takahashi, Atsushi*; Koarai, Kazuma; Kino, Yasushi*; Okutsu, Kenichi*; Sekine, Tsutomu*; Yamashita, Takuma*; Shimizu, Yoshinaka*; Chiba, Mirei*; et al.

KEK Proceedings 2021-2, p.91 - 96, 2021/12

We examined whether the ESR dose estimation method could be applied to wild Japanese macaque. In this work, we investigated the enamel preparation protocol and the analytical method of the ESR spectra.

Journal Articles

Mass production of Nb$$_{3}$$Sn conductors for ITER toroidal field coils in Japan

Takahashi, Yoshikazu; Isono, Takaaki; Hamada, Kazuya; Nunoya, Yoshihiko; Nabara, Yoshihiro; Matsui, Kunihiro; Hemmi, Tsutomu; Kawano, Katsumi; Koizumi, Norikiyo; Oshikiri, Masayuki; et al.

IEEE Transactions on Applied Superconductivity, 22(3), p.4801904_1 - 4801904_4, 2012/06

 Times Cited Count:7 Percentile:41.31(Engineering, Electrical & Electronic)

Japan Atomic Energy Agency is the first to start the mass production of the TF conductors in Phase IV in March 2010 among the 6 parties who are procuring TF conductors in the ITER project. The conductor is cable-in-conduit conductor with a central spiral. A total of 900 Nb$$_{3}$$Sn strands and 522 copper strands are cabled around the central spiral and then wrapped with stainless steel tape whose thickness is 0.1 mm. Approximately 60 tons of Nb$$_{3}$$Sn strands were manufactured by the two suppliers in December 2010. This amount corresponds to approximately 55% of the total contribution from Japan. Approximately 30% of the total contribution from Japan was completed as of February 2011. JAEA is manufacturing one conductor per month under a contract with two Japanese companies for strands, one company for cabling and one company for jacketing. This paper summarizes the technical developments including a high-level quality assurance. This progress is a significant step in the construction of the ITER machine.

Journal Articles

Spin-trapping reactions of a novel gauchetype radical trapper G-CYPMPO

Oka, Toshitaka; Yamashita, Shinichi; Midorikawa, Masamichi*; Saiki, Seiichi; Muroya, Yusa*; Kamibayashi, Masato*; Yamashita, Masayuki*; Anzai, Kazunori*; Katsumura, Yosuke*

Analytical Chemistry, 83(24), p.9600 - 9604, 2011/10

 Times Cited Count:39 Percentile:78.07(Chemistry, Analytical)

Chemical reactions of a novel gauche-type spin trap, G-CYPMPO ($textit{sc}$-5-(5,5-dimethyl-2-oxo-1,3,2-dioxaphosphinan-2-yl)-5-methy-1-pyrroline 1-oxide, torsion angle: O1-P1-C6-N1 of 52.8$$^{circ}$$), with reactive oxygen species were examined by pulse radiolysis technique with 35 MeV electron beam and electron spin resonance spectroscopy after $$^{60}$$Co $$gamma$$-ray irradiation. The spin trapping reaction rate constants of G-CYPMPO toward hydroxyl radical and hydrated electron were estimated to be (4.2$$pm$$0.1)$$times$$10$$^{9}$$ and (11.8$$pm$$0.2)$$times$$10$$^{9}$$ M$$^{-1}$$s$$^{-1}$$, respectively. Half-lives of spin adducts, hydroxyl radical and perhydroxyl radical adducted G-CYPMPO were estimated to be $$sim$$35 and $$sim$$90 min, respectively. A comparison of the results with earlier reports using different radical sources suggests that the purity of the solution and/or the radical generation technique may influence the stability of spin adducts.

Journal Articles

Synchrotron radiation study on structure of atmospheric corrosion products formed on steel surfaces

Konishi, Hiroyuki; Yamashita, Masato*; Mizuki, Junichiro; Uchida, Hitoshi*

Characterization of Corrosion Products on Steel Surfaces, p.199 - 222, 2006/00

no abstracts in English

Journal Articles

X-ray absorption fine structure spectra of rust layers on Fe-based binary alloys exposed to Cl-rich environment

Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro

Proceedings of 16th International Corrosion Congress (CD-ROM), 6 Pages, 2005/09

XANES measurements of rust layers formed on Fe, Fe-Cr alloys and Fe-Ni alloys exposed to a Cl-rich atmosphere have been performed using synchrotron radiation in order to clarify the relation between the structural properties of the rust layer on weathering steel and anticorrosive alloying elements and/or chloride ions. The XANES spectra around Cl K-edge revealed that the rust layer on the Fe-based binary alloys contains unidentified chloride in addition to akagan$'e$iteite. The Fe K-edge XANES results indicated that the rust layers are composed mainly of well-known iron oxides, goethite, akagan$'e$ite, lepidocrocite and magnetite. In particular, the mole ratio of akagan$'e$ite in the rust layers on the Fe-Ni alloys is relatively higher than that of the Fe-Cr alloys. The Cr K-edge XANES spectra of the rust layers on the Fe-Cr alloys depends on the Cr alloy content. Therefore, the local structure of Cr in the rust layer is variable with the Cr density. In contrast, the Ni K-edge XANES results show that the local structure of Ni in the rust layer are unique in a certain Ni content range.

Journal Articles

Characterization of rust layer formed on Fe, Fe-Ni and Fe-Cr alloys exposed to Cl-rich environment by Cl and Fe K-edge XANES measurements

Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro

Materials Transactions, 46(2), p.329 - 336, 2005/02

 Times Cited Count:28 Percentile:80.32(Materials Science, Multidisciplinary)

Chloride in atmosphere considerably reduces the corrosion resistance of conventional weathering steel containing a small amount of Cr. Ni is an effective anticorrosive element for improving the corrosion resistance of steel in a Cl-rich environment. In order to clarify the structure of the protective rust layer of weathering steel, Cl and Fe K-edge X-ray absorption near edge structure (XANES) spectra of atmospheric corrosion products (rust) formed on Fe, Fe-Ni and Fe-Cr alloys exposed to Cl-rich atmosphere were measured. The Fe K-XANES measurements enable the characterization of a mixture of iron oxides such as rust. The chemical composition of the rust was determined by performing pattern fitting of the measured spectra. All the rust is composed mainly of goethite, akagan$'e$ite, lepidocrocite and magnetite. Among these iron oxides, akagan$'e$ite in particular is the major component in the rust. Additionally, the amount of akagan$'e$ite in the rust of Fe-Ni alloy is much greater than that in rust of Fe-Cr alloy. Akagan$'e$ite is generally considered to facilitate the corrosion of steel, but our results indicate that akagan$'e$ite in the rust of Fe-Ni alloy is quantitatively different from that in rust of Fe-Cr alloy and does not facilitate the corrosion of steel. The shoulder peak observed in Cl K-XANES spectra reveals that the rust contains a chloride other than akagan$'e$ite. The energy of the shoulder peak does not correspond to that of any well-known chlorides. In the measured spectra, there is no proof that Cl, by combining with the alloying element, inhibits the alloying element from acting in corrosion resistance. The shoulder peak appears only when the content of the alloying element is lower than a certain value. This suggests that the generation of the unidentified chloride is related to the corrosion rate of steel.

Journal Articles

Structure analysis of cation selective Cr-goethite as protective rust of weathering steel

Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro

Materials Transactions, 46(2), p.337 - 341, 2005/02

 Times Cited Count:9 Percentile:57.22(Materials Science, Multidisciplinary)

We have performed extended X-ray absorption fine structure (EXAFS) analysis for artificial Cr-goethite to elucidate the local structure around Cr in Cr-goethite. The spectra were obtained using synchrotron radiation X-rays at the Photon Factory in Tsukuba. The first shell contributions were isolated by Fourier filtering the EXAFS data, and the inverse Fourier transformed single-shell data were analyzed using curve fitting method. The results show that Cr is coordinated with (7$$pm$$1) O$$^{2-}$$ ions. The protective character of Cr-goethite protective rust layer on weathering steel can be interpreted in terms of the O$$^{2-}$$ coordination around Cr$$^{3+}$$ resulting in creation of negative fixed-charge in the Cr-goethite particles.

Journal Articles

Difference between Cr and Ni K-edge XANES spectra of rust layers formed on Fe-based binary alloys exposed to Cl-rich environment

Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro

Materials Transactions, 46(1), p.136 - 139, 2005/01

 Times Cited Count:2 Percentile:25.76(Materials Science, Multidisciplinary)

The rust layer formed on weathering steel possesses a strong protective ability against corrosives in an atmosphere. This ability is related to the structure of the rust layer. The difference in the protective ability of a rust layer in a Cl-rich environment between conventional weathering steel containing Cr and advanced weathering steel containing Ni is believed to be caused by the differences in local structural and chemical properties between alloying elements, Cr and Ni, in the rust layer. In order to examine the effect of these alloying elements on the structure of the rust layer formed on steel in a Cl-rich environment, we have performed Cr and Ni K-edge X-ray absorption near-edge structure (XANES) measurements for the rust layer of Fe-Cr and Fe-Ni binary alloys exposed to a Cl-rich atmosphere using synchrotron radiation. The results of the Cr K-edge XANES measurements for the rust layer of Fe-Cr binary alloys show that the atomic geometry around Cr depends on the concentration of Cr. Therefore, it is expected that the local structure around Cr in the rust layer is unstable. On the other hand, from the results of the Ni K-edge XANES measurements for the rust layer of Fe-Ni binary alloys, Ni is considered to be positioned at a specific site in the crystal structure of a constituent of the rust layer, such as akagan$'e$ite or magnetite. As a consequence, Ni negligibly interacts with Cl$$^{-}$$ ions in the rust layer.

Journal Articles

Cl K-edge XANES spectra of atmospheric rust on Fe, Fe-Cr and Fe-Ni alloys exposed to saline environment

Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro

Materials Transactions, 45(12), p.3356 - 3359, 2004/12

 Times Cited Count:10 Percentile:53.05(Materials Science, Multidisciplinary)

Cl K-edge XANES measurements of atmospheric corrosion products (rust) formed on Fe, Fe-Ni and Fe-Cr alloys in chloride pollution have been performed using synchrotron radiation in order to clarify roles of anticorrosive alloying elements and of Cl in the corrosion resistance of weathering steel. The spectra of binary alloys show a shoulder structure near the absorption edge. The intensity of the shoulder peak depends on the kind and amount of the alloying element, whereas the energy position is invariant. This indicates that Cl is not combined directly with alloying elements in the rust.

JAEA Reports

Feasibility Study on Commercialization of Fast Breeder Reactor Cycle Systems Interim Report of Phase II; Technical Study Report for Reactor Plant Systems

Konomura, Mamoru; Ogawa, Takashi; Okano, Yasushi; Yamaguchi, Hiroyuki; Murakami, Tsutomu; Takaki, Naoyuki; Nishiguchi, Youhei; Sugino, Kazuteru; Naganuma, Masayuki; Hishida, Masahiko; et al.

JNC TN9400 2004-035, 2071 Pages, 2004/06

JNC-TN9400-2004-035.pdf:76.42MB

The attractive concepts for Sodium-, lead-bismuth-, helium- and water-cooled FBRs have been created through using typical plant features and employing advanced technologies. Efforts on evaluating technological prospects of feasibility have been paid for these concepts. Also, it was comfirmed if these concepts satisfy design requierments of capability and performance presumed in the feasibilty study on commertialization of Fast Breeder Reactor Systems. As results, it was concluded that the selection of sodium-cooled reactor was most rational for practical use of FBR technologies in 2015.

Journal Articles

New type of Monk-Gillieson monochromator capable of covering a 0.7- to 25-nm range

Koike, Masato; Sano, Kazuo*; Harada, Yoshihisa*; Yoda, Osamu; Ishino, Masahiko; Tamura, Keisuke*; Yamashita, Kojun*; Moriya, Naoji*; Sasai, Hiroyuki*; Jinno, Masafumi*; et al.

X-Ray Mirrors, Crystals, and Multilayers II (Proceedings of SPIE Vol.4782), p.300 - 307, 2002/07

For the purpose of realizing an evaluation beamline for characterizing soft X-ray optical elements in a wide wavelength range of 0.7-25 nm, we have designed and constructed a new type of monochromator that combined two types of Monk-Gillieson monochromators. One is a conventional type equipped with three varied-line-spacing plane gratings, allowing a choice of two included angles. The other is a new type that employs a scanning mechanism based on Surface Normal Rotation (SNR). The SNR scheme provides high throughput at short wavelengths and simple scanning mechanism by means of a grating rotation about its normal. The monochromator is operated in the SNR and conventional modes over the ranges of 0.7-2.0 nm and 2.0-25 nm, respectively. In this paper we describe the optical and mechanical designs of the monochromator, wavelength calibrations in the SNR mode, and preliminary experimental data, such as the transmittance of an Al filter at $$sim$$0.8 nm and the total yield photoelectron measurement on a MgO powder in a wavelength rage of 0.7-2 nm.

Journal Articles

Structural analysis of corrosion product of Fe-Cr alloy film using synchrotron radiation

Yamashita, Masato*; Konishi, Hiroyuki; Takahashi, Masamitsu; Mizuki, Junichiro; Uchida, Hitoshi*

Materials Science Research International, Special Technical Publication, 1, p.398 - 401, 2001/05

A rust layer on a weathering low-alloy steel has strong protective ability for atmospheric corrosion of the steel. In order to control the rust layer on steels, it is so important to know the detailed structure of rust and relate it to the protective ability of the rust layer. Especially, the position of atoms of the alloying elements in the rust layer directly control the structure and properties of the rust layer. We tried to find the atomic arrangement of the rust layer of Fe-Cr alloy film covered with thin film of electrolyte using synchrotron radiation. Grazing incidence X-ray diffraction and M$"o$ssbauer spectra showed that the rust layer was composed of $$gamma$$-FeOOH and ultra-fine $$alpha$$-FeOOH. By examining EXAFS spectra, Cr coming from Fe-Cr alloy film would be present in the $$alpha$$-FeOOH. Some of Cr would be present between Fe-0-OH octahedron as interstitial atoms, as well as substituting Fe lattice site in the octahedron.

JAEA Reports

ITER neutral beam injection system; Japanese design proposal

Ohara, Yoshihiro; Tanaka, Shigeru; Akiba, Masato; Araki, Masanori; Fujisawa, Noboru; Hanada, Masaya; Inoue, Takashi; *; Mizuno, Makoto; Okumura, Yoshikazu; et al.

JAERI-M 91-052, 176 Pages, 1991/03

JAERI-M-91-052.pdf:4.07MB

no abstracts in English

Journal Articles

Neutronics of neutral beam injector for ITER; Japanese proposal

Inoue, Takashi; Akiba, Masato; Araki, Masanori; Hanada, Masaya; *; Mizuno, Makoto; Okumura, Yoshikazu; Ohara, Yoshihiro; Seki, Masahiro; Tanaka, Shigeru; et al.

Fusion Engineering and Design, 18, p.369 - 376, 1991/00

 Times Cited Count:3 Percentile:40.77(Nuclear Science & Technology)

no abstracts in English

JAEA Reports

Design and research of ice-blasting equipment

Shimizu, Makoto*; Kimuro, Harumi*; Ayabe, Muneo*; Kouno, Yasumasa*; Miyahara, Shuji*; Yamashita, Saburo*; Kanazawa, Kazuo*; Hayashi, Mitsuo*; Yoshizaki, Masato*

PNC TJ118 83-05VOL2, 222 Pages, 1984/03

PNC-TJ118-83-05VOL2.pdf:14.66MB

None

JAEA Reports

Design and research of ice-blasting equipment

Shimizu, Makoto*; Kimuro, Harumi*; Ayabe, Muneo*; Kouno, Yasumasa*; Miyahara, Shuji*; Yamashita, Saburo*; Kanazawa, Kazuo*; Hayashi, Mitsuo*; Yoshizaki, Masato*

PNC TJ118 83-05VOL1, 42 Pages, 1984/03

PNC-TJ118-83-05VOL1.pdf:1.06MB

None

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