Outlining zircon growth in a granitic pluton using 3D cathodoluminescence patterns, U-Pb age, titanium concentration, and Th/U; Implications for the magma chamber process of Okueyama granite, Kyushu, Japan

Yuguchi, Takashi*; Ito, Daichi*; Yokoyama, Tatsunori; Sakata, Shuhei*; Suzuki, Satoshi*; Ogita, Yasuhiro; Yagi, Koshi*; Imura, Takumi*; Motai, Satoko*; Ono, Takeshi*

Lithos, 440-441, p.107026_1 - 107026_14, 2023/03

https://doi.org/10.1016/j.lithos.2023.107026

We propose a new method for elucidating zircon growth in granitic plutons, based on variations in three-dimensional 3D cathodoluminescence (CL) patterns, U-Pb ages, titanium concentration, and Th/U ratios. We focused on the zircon growth processes in the Okueyama granite (OKG) in central Kyushu, Japan, to obtain interpretations of magma chamber processes that result in the formation of granitic plutons. The OKG consists of three lithofacies: biotite granite (BG), hornblende granite (HG), and hornblende granodiorite (HGD). To determine the 3D internal structure and growth pattern of a zircon crystal, we performed CL observations for multi-sections of the samples. Simultaneously, we also determined the zircon U-Pb age and titanium concentration of the center sections of the samples. The 3D distribution of the oscillatory zoning can be used to determine the crystal nucleus. The simultaneous determination of zircon U-Pb ages and Ti concentrations of the granite samples indicates the time-temperature (t-T) history of granitic magma before its solidification. The t-T histories of the BG, HG, and HGD represented similar cooling behaviors within the magma chamber: rapid cooling from the zircon crystallization temperature to the closure temperature of the biotite K-Ar system between 16 Ma and 10 Ma. The variations in the Th/U ratios against temperature also demonstrate a different trend at the boundary of approximately 670 C. Fractional crystallization in the magma chamber progressed significantly at temperatures above 670 C; below 670 C, crystallization progressed slowly, indicating only minimal changes in the magma composition. The variations in the Th/U ratio against temperature in the BG, HG, and HGD portrayed common tendencies, indicating the same behavior in the progression of fractional crystallization among the three lithofacies, which in turn, represented the same behavior within the entire magma chamber.

Simultaneous determination of zircon crystallisation age and temperature; Common thermal evolution of mafic magmatic enclaves and host granites in the Kurobegawa granite, central Japan

Yuguchi, Takashi*; Yamazaki, Hayato*; Ishibashi, Kozue*; Sakata, Shuhei*; Yokoyama, Tatsunori; Suzuki, Satoshi*; Ogita, Yasuhiro; Sando, Kazusa*; Imura, Takumi*; Ono, Takeshi*

Journal of Asian Earth Sciences, 226, p.105075_1 - 105075_9, 2022/04

https://doi.org/10.1016/j.jseaes.2021.105075

Simultaneous determination of the U-Pb age of zircon and concentration of titanium in a single analysis spot, using inductively coupled plasma mass spectrometry with laser ablation sample introduction, produces paired age and temperature data of zircon crystallisation, potentially revealing time-temperature () histories for evolved magma. The Kurobegawa granite, central Japan, contains abundant mafic magmatic enclaves (MMEs). We applied this method to evaluate MMEs and their host (enclosing) granites. Cooling behaviour common to both MMEs and host rocks was found between 1.5 and 0.5 Ma. Rapid cooling from the zircon crystallisation temperature to the closure temperature of biotite K-Ar system was within 1 million year. Combining the obtained paths of MMEs and host rocks with petrological information can provide insights into magma chamber processes. This suggests that MME flotation, migration, and spread through the magma chamber ceased at 1.5-0.5 Ma, indicating the emplacement age of the Kurobegawa granitic pluton, as no large-scale reheating episodes have occurred since then.

Current situations and discussions in Japan in relation to the new occupational equivalent dose limit for the lens of the eye

Yokoyama, Sumi*; Hamada, Nobuyuki*; Hayashida, Toshiyuki*; Tsujimura, Norio; Tatsuzaki, Hideo*; Kurosawa, Tadahiro*; Nabatame, Kuniaki*; Oguchi, Hiroyuki*; Ono, Kazuko*; Kawaura, Chiyo*; et al.

Journal of Radiological Protection, 37(3), p.659 - 683, 2017/09

https://doi.org/10.1088/1361-6498/aa73e8

Since the International Commission on Radiological Protection recommended reducing the occupational equivalent dose limit for the lens of the eye in 2011, there have been extensive discussions in various countries. This paper reviews the current situations in radiation protection of the ocular lens and the discussions on the potential impact of the new lens dose limit in Japan. Topics include historical changes to the lens dose limit, the current situations in occupational lens exposures (e.g., in medical workers, nuclear workers, and Fukushima nuclear power plant workers) and measurements, and the current status of biological studies and epidemiological studies on radiation cataracts. Our focus is on the situations in Japan, but we believe such information sharing will be useful in many other countries.

Progress of ITER full tungsten divertor technology qualification in Japan

Ezato, Koichiro; Suzuki, Satoshi; Seki, Yohji; Mori, Kensuke; Yokoyama, Kenji; Escourbiac, F.*; Hirai, Takeshi*; Kuznetsov, V.*

Fusion Engineering and Design, 98-99, p.1281 - 1284, 2015/10

https://doi.org/10.1016/j.fusengdes.2015.03.009

Japan Atomic Energy Agency (JAEA) is now devoting to development of Full-W ITER divertor outer vertical target (OVT), especially, PFU that needs to withstand the repetitive heat load as high as 20MW/m. JAEA have succeeded in demonstrating that the soundness of a bonding technology is sufficient for the full-W ITER divertor. For the development of bonding technology, the load carrying capability test on the W monoblock with a leg attachment to an OVT support structure was carried out and shows that the attachment can withstand against the uniaxial load more than 20 kN which is three times higher than the IO requirement. JAEA manufactured 6 small-scale mock-ups and tested under the repetitive heat load of 10 and 20 MW/m to examine the durability of the divertor structure including W tile bonding and the cooling tube. All of the mock-ups could survived 5000 cycles at 10 MW/m and 1000 cycles 20 MW/m with no failure such as debonding of the W tile and water leak from the cooling tube. The number of cycles at 20 MW/m is three times longer than the requirement of ITER divertor.

Development of tungsten monoblock technology for ITER full-tungsten divertor in Japan

Seki, Yohji; Ezato, Koichiro; Suzuki, Satoshi; Yokoyama, Kenji; Mori, Kensuke; Hirai, Takeshi*; Escourbiac, F.*; Kuznetsov, V.*

Proceedings of 25th IAEA Fusion Energy Conference (FEC 2014) (CD-ROM), 8 Pages, 2014/10

Hydrogen-bond network and pH sensitivity in human transthyretin

Yokoyama, Takeshi*; Mizuguchi, Mineyuki*; Nabeshima, Yuko*; Kusaka, Katsuhiro*; Yamada, Taro*; Hosoya, Takaaki*; Ohara, Takashi; Kurihara, Kazuo; Tanaka, Ichiro*; Niimura, Nobuo*

Journal of Synchrotron Radiation, 20(6), p.834 - 837, 2013/11

https://doi.org/10.1107/S090904951302075X

Transthyretin (TTR) is a tetrameric protein. TTR misfolding and aggregation are associated with human amyloid diseases. Dissociation of the TTR tetramer is believed to be the rate-limiting step in the amyloid fibril formation cascade. Low pH is known to promote dissociation into monomer and the formation of amyloid fibrils. In order to reveal the molecular mechanisms underlying pH sensitivity and structural stabilities of TTR, neutron diffraction studies were conducted using the IBARAKI Biological Crystal Diffractometer with the time-of-flight method. Crystals for the neutron diffraction experiments were grown up to 2.5 mm for four months. The neutron crystal structure solved at 2.0 revealed the protonation states of His88 and the detailed hydrogen-bond network depending on the protonation states of His88. This hydrogen-bond network is involved in monomer-monomer and dimer-dimer interactions, suggesting that the double protonation of His88 by acidification breaks the hydrogen-bond network and causes the destabilization of the TTR tetramer. Structural comparison with the X-ray crystal structure at acidic pH identified the three amino acid residues responsible for the pH sensitivity of TTR. Our neutron model provides insights into the molecular stability related to amyloidosis.

Hydrogen-bond network and pH sensitivity in transthyretin; Neutron crystal structure of human transthyretin

Yokoyama, Takeshi*; Mizuguchi, Mineyuki*; Nabeshima, Yuko*; Kusaka, Katsuhiro*; Yamada, Taro*; Hosoya, Takaaki*; Ohara, Takashi*; Kurihara, Kazuo; Tomoyori, Katsuaki*; Tanaka, Ichiro*; et al.

Journal of Structural Biology, 177(2), p.283 - 290, 2012/02

https://doi.org/10.1016/j.jsb.2011.12.022

Neutron structure analysis using the IBARAKI biological crystal diffractometer (iBIX) at J-PARC

Tanaka, Ichiro*; Kusaka, Katsuhiro*; Hosoya, Takaaki*; Niimura, Nobuo*; Ohara, Takashi*; Kurihara, Kazuo; Yamada, Taro*; Onishi, Yuki*; Tomoyori, Katsuaki*; Yokoyama, Takeshi*

Acta Crystallographica Section D, 66(11), p.1194 - 1197, 2010/11

https://doi.org/10.1107/S0907444910033020

The IBARAKI Biological Crystal Diffractometer (iBIX), a new diffractometer for protein crystallography at the next-generation neutron source at J-PARC (Japan Proton Accelerator Research Complex), has been constructed and has been operational since December 2008. Preliminary structure analyses of organic crystals showed that iBIX has high performance even at 120 kW operation and the first full data set is being collected from a protein crystal.

Degradation of charge collection efficiency obtained for 6H-SiC np diodes irradiated with gold ions

Oshima, Takeshi; Sato, Takahiro; Oikawa, Masakazu; Onoda, Shinobu; Hishiki, Shigeomi; Hirao, Toshio; Kamiya, Tomihiro; Yokoyama, Takuro*; Sakamoto, Airi*; Tanaka, Reisaburo*; et al.

Materials Science Forum, 556-557, p.913 - 916, 2007/00

https://doi.org/10.4028/www.scientific.net/MSF.556-557.913

no abstracts in English

Silicon isotope separation utilizing infrared multiphoton dissociation of SiF irradiated with two-frequency CO laser lights

Yokoyama, Atsushi; Oba, Hironori; Hashimoto, Masashi; Katsumata, Keiichi; Akagi, Hiroshi; Ishii, Takeshi*; Oya, Akio*; Arai, Shigeyoshi*

Applied Physics B, 79(7), p.883 - 889, 2004/11

https://doi.org/10.1007/s00340-004-1642-z

Silicon isotope separation has been done utilizing the Infrared Multiphoton Dissociation of SiF irradiated with two-frequency CO laser lights. The two-frequency excitation method improved the separation efficiency with keeping the high enrichment factors. For example, SiF with the Si fraction of 99.4 % was obtained at 40.0 % dissociation of SiF after the simultaneous irradiation of 100 pulses with 966.23 cm photons (0.089 J/cm) and 954.55 cm photons (0.92 J/cm), while 1000 pulses were needed to obtain 99.0 % of Si at 27.2 % dissociation in the case of single frequency irradiation at 954.55 cm (0.92 J/cm). The single-step enrichment factors of Si and Si increased with increasing SiF pressure. The reason for this enhancement has been discussed in terms of the rotational and vibrational relaxations by collisions with ambient gases.