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Yang, Q.*; Yang, X.*; Wang, Y.*; Fei, Y.*; Li, F.*; Zheng, H.*; Li, K.*; Han, Y.*; Hattori, Takanori; Zhu, P.*; et al.
Nature Communications (Internet), 15, p.7778_1 - 7778_9, 2024/09
Luminescent materials that simultaneously embody bright singlet and triplet excitons hold great potential in optoelectronics, signage, and information encryption. However, achieving high-performance white-light emission is severely hampered by their inherent unbalanced contribution of fluorescence and phosphorescence. Herein, we address this challenge by pressure treatment engineering via hydrogen bonding cooperativity effect to realize the mixture of n-- transitions, where the triplet state emission was boosted from 7% to 40% in isophthalic acid (IPA). A superior white-light emission based on hybrid fluorescence and phosphorescence was harvested in pressure-treated IPA, and the photoluminescence quantum yield was increased to 75% from the initial 19% (blue-light emission). In-situ high-pressure IR spectra, X ray diffraction, and neutron diffraction reveal continuous strengthening of the hydrogen bonds with the increase of pressure. Furthermore, this enhanced hydrogen bond is retained down to the ambient conditions after pressure treatment, awarding the targeted IPA efficient intersystem crossing for balanced singlet/triplet excitons population and resulting in efficient white-light emission. This work not only proposes a route for brightening triplet states in organic small molecule, but also regulates the ratio of singlet and triplet excitons to construct high-performance white-light emission.
Li, J.*; Li, X.*; Zhang, Y.*; Zhu, J.*; Zhao, E.*; Kofu, Maiko; Nakajima, Kenji; Avdeev, M.*; Liu, P.-F.*; Sui, J.*; et al.
Applied Physics Reviews (Internet), 11(1), p.011406_1 - 011406_8, 2024/03
Times Cited Count:0 Percentile:0.00(Physics, Applied)Nara, Yoshitaka*; Kashiwaya, Koki*; Oketani, Kazuki*; Fujii, Hirokazu*; Zhao, Y.*; Kato, Masaji*; Aoyagi, Kazuhei; Ozaki, Yusuke; Matsui, Hiroya; Kono, Masanori*
Zairyo, 73(3), p.220 - 225, 2024/03
The fractures in the rock are the main pass of groundwater flow and solute transport. The filling of fine-grained particle, such as clay minerals, was confirmed to decrease the permeability of rock by laboratory experiment. This research aimed to verify the occurrence of the phenomena in the field. The water containing the clay minerals was injected into the rock at the 200m stage of the Mizunami Underground research laboratory. The hydraulic conductivity decreased two order before and after the injection. This result suggested that the decrease of hydraulic conductivity by the filling of fine-grained particle in the fractures occurred in the real field.
Zhou, Y.*; Song, W.*; Zhang, F.*; Wu, Y.*; Lei, Z.*; Jiao, M.*; Zhang, X.*; Dong, J.*; Zhang, Y.*; Yang, M.*; et al.
Journal of Alloys and Compounds, 971, p.172635_1 - 172635_7, 2024/01
Times Cited Count:0 Percentile:0.00(Chemistry, Physical)Chong, Y.*; Gholizadeh, R.*; Guo, B.*; Tsuru, Tomohito; Zhao, G.*; Yoshida, Shuhei*; Mitsuhara, Masatoshi*; Godfrey, A.*; Tsuji, Nobuhiro*
Acta Materialia, 257, p.119165_1 - 119165_14, 2023/09
Times Cited Count:5 Percentile:90.07(Materials Science, Multidisciplinary)Metastable titanium alloys possess excellent strain-hardening capability, but suffer from a low yield strength. As a result, numerous attempts have been made to strengthen this important structural material in the last decade. Here, we explore the contributions of grain refinement and interstitial additions in raising the yield strength of a Ti-12Mo (wt.%) metastable titanium alloy. Surprisingly, rather than strengthening the material, grain refinement actually lowers the ultimate tensile strength in this alloy. This unexpected and anomalous behavior is attributed to a significant enhancement in strain-induced martensite phase transformation, where in-situ synchrotron X-ray diffraction analysis reveals, for the first time, that this phase is much softer than the parent phase. Instead, a combination of both oxygen addition and grain refinement is found to realize an unprecedented strength-ductility synergy in a Ti-12Mo-0.3O (wt.%) alloy. The advantageous effect of oxygen solutes in this ternary alloy is twofold. Firstly, solute oxygen largely suppresses strain-induced transformation to the martensite phase, even in a fine-grained microstructure, thus avoiding the softening effect of excessive amounts of martensite. Secondly, oxygen solutes readily segregate to twin boundaries, as revealed by atom probe tomography. This restricts the growth of deformation twins, thereby promoting more extensive twin nucleation, leading to enhanced microstructural refinement. The insights from our work provide a cost-effective rationale for the design of strong yet tough metastable titanium alloys, with significant implications for more widespread use of this high strength-to-weight structural material.
Bao, S.*; Gu, Z.-L.*; Shangguan, Y.*; Huang, Z.*; Liao, J.*; Zhao, X.*; Zhang, B.*; Dong, Z.-Y.*; Wang, W.*; Kajimoto, Ryoichi; et al.
Nature Communications (Internet), 14, p.6093_1 - 6093_9, 2023/09
Times Cited Count:2 Percentile:72.40(Multidisciplinary Sciences)Esser, S. P.*; Rahlff, J.*; Zhao, W.*; Predl, M.*; Plewka, J.*; Sures, K.*; Wimmer, F.*; Lee, J.*; Adam, P. S.*; McGonigle, J.*; et al.
Nature Microbiology (Internet), 8(9), p.1619 - 1633, 2023/09
Times Cited Count:2 Percentile:71.89(Microbiology)Li, H.*; Liu, Y.*; Zhao, W.*; Liu, B.*; Tominaga, Aki; Shobu, Takahisa; Wei, D.*
International Journal of Plasticity, 165, p.103612_1 - 103612_20, 2023/06
Times Cited Count:3 Percentile:81.78(Engineering, Mechanical)In order to clarify the strength properties of Co-free maraging steel, tensile experiment using high energy synchrotron X-ray diffraction was performed. Diffraction profiles from the martensitic and austenitic phases were obtained, and their strength and width were observed to vary as loading. Analysis of the diffraction profiles showed that the content of martensite in the as-aged material decreased slowly at low stress levels and decreased rapidly at high stress levels. On the other hand, the austenite phase in the as-solution materials was significantly transformed the martensite phase as the stress increased. It was clarified to be responsible for their respective strength properties.
Wu, P.*; Murai, Naoki; Li, T.*; Kajimoto, Ryoichi; Nakamura, Mitsutaka; Kofu, Maiko; Nakajima, Kenji; Xia, K.*; Peng, K.*; Zhang, Y.*; et al.
New Journal of Physics (Internet), 25(1), p.013032_1 - 013032_11, 2023/01
Times Cited Count:0 Percentile:0.00(Physics, Multidisciplinary)Sheng, J.*; Wang, L.*; Candini, A.*; Jiang, W.*; Huang, L.*; Xi, B.*; Zhao, J.*; Ge, H.*; Zhao, N.*; Fu, Y.*; et al.
Proceedings of the National Academy of Sciences of the United States of America, 119(51), p.e2211193119_1 - e2211193119_9, 2022/12
Times Cited Count:4 Percentile:63.40(Multidisciplinary Sciences)Sheng, Q.*; Kaneko, Tatsuya*; Yamakawa, Kohtaro*; Guguchia, Z.*; Gong, Z.*; Zhao, G.*; Dai, G.*; Jin, C.*; Guo, S.*; Fu, L.*; et al.
Physical Review Research (Internet), 4(3), p.033172_1 - 033172_14, 2022/09
Suzuki, Hakuto*; Zhao, G.*; Okamoto, Jun*; Sakamoto, Shoya*; Chen, Z.-Y.*; Nonaka, Yosuke*; Shibata, Goro; Zhao, K.*; Chen, B.*; Wu, W.-B.*; et al.
Journal of the Physical Society of Japan, 91(6), p.064710_1 - 064710_5, 2022/06
Times Cited Count:0 Percentile:0.00(Physics, Multidisciplinary)Zhao, Y.*; Suzuki, T.*; Iimori, T.*; Kim, H.-W.*; Ahn, J. R.*; Horio, Masafumi*; Sato, Yusuke*; Fukaya, Yuki; Kanai, T.*; Okazaki, K.*; et al.
Physical Review B, 105(11), p.115304_1 - 115304_8, 2022/03
Times Cited Count:1 Percentile:14.73(Materials Science, Multidisciplinary)no abstracts in English
Shangguan, Y.*; Bao, S.*; Dong, Z.-Y.*; Cai, Z.*; Wang, W.*; Huang, Z.*; Ma, Z.*; Liao, J.*; Zhao, X.*; Kajimoto, Ryoichi; et al.
Physical Review B, 104(22), p.224430_1 - 224430_8, 2021/12
Times Cited Count:1 Percentile:7.22(Materials Science, Multidisciplinary)Fukaya, Yuki; Zhao, Y.*; Kim, H.-W.*; Ahn, J.-R.*; Fukidome, Hirokazu*; Matsuda, Iwao*
Physical Review B, 104(18), p.L180202_1 - L180202_5, 2021/11
Times Cited Count:9 Percentile:63.89(Materials Science, Multidisciplinary)no abstracts in English
Miyabe, Masabumi; Satou, Yukihiko; Wakaida, Ikuo; Terabayashi, Ryohei*; Sonnenschein, V.*; Tomita, Hideki*; Zhao, Y.*; Sakamoto, Tetsuo*
Journal of Physics B; Atomic, Molecular and Optical Physics, 54(14), p.145003_1 - 145003_8, 2021/07
Times Cited Count:0 Percentile:0.01(Optics)Two-color two-step photoionization optogalvanic spectroscopy was performed using high-repetition-rate titanium sapphire lasers and a uranium hollow cathode lamp to find the two-step resonance ionization schemes of uranium. Many ionization transitions were observed by exciting uranium atoms in a ground state into five, even parity, excited levels with the first-step laser and by scanning the second-step laser wavelengths. By blocking the first-step laser, single-color, two-photon ionization transitions were also identified. From these results, we have found more than 50 odd-parity autoionizing levels of uranium in the energy, ranging from the ionization potential (49958.4 cm) to 51150 cm. The determined energy levels are within 1 cm of previously reported values.
Hao, Y. Q.*; Wo, H. L.*; Gu, Y. M.*; Zhang, X. W.*; Gu, Y. Q.*; Zheng, S. Y.*; Zhao, Y.*; Xu, G. Y.*; Lynn, J. W.*; Nakajima, Kenji; et al.
Science China; Physics, Mechanics & Astronomy, 64(3), p.237411_1 - 237411_6, 2021/03
Times Cited Count:6 Percentile:59.12(Physics, Multidisciplinary)Wang, Y.*; Jia, G.*; Cui, X.*; Zhao, X.*; Zhang, Q.*; Gu, L.*; Zheng, L.*; Li, L. H.*; Wu, Q.*; Singh, D. J.*; et al.
Chem, 7(2), p.436 - 449, 2021/02
Times Cited Count:199 Percentile:99.80(Chemistry, Multidisciplinary)He, H.*; Naeem, M.*; Zhang, F.*; Zhao, Y.*; Harjo, S.; Kawasaki, Takuro; Wang, B.*; Wu, X.*; Lan, S.*; Wu, Z.*; et al.
Nano Letters, 21(3), p.1419 - 1426, 2021/02
Times Cited Count:41 Percentile:95.16(Chemistry, Multidisciplinary)Li, X.*; Liu, P.-F.*; Zhao, E.*; Zhang, Z.*; Guide, T.*; Le, M. D.*; Avdeev, M.*; Ikeda, Kazutaka*; Otomo, Toshiya*; Kofu, Maiko; et al.
Nature Communications (Internet), 11, p.942_1 - 942_9, 2020/02
Times Cited Count:37 Percentile:90.10(Multidisciplinary Sciences)In high-performance thermoelectric materials, there are two main low thermal conductivity mechanisms: the phonon anharmonic and phonon scattering resulting from the dynamic disorder, which have been successfully revealed by inelastic neutron scattering. Using neutron scattering and ab initio calculations, we report here a mechanism of static local structure distortion combined with phonon-anharmonic-induced ultralow lattice thermal conductivity in -MgAgSb. Since the transverse acoustic phonons are almost fully scattered by the intrinsic distorted rocksalt sublattice in this compound, the heat is mainly transported by the longitudinal acoustic phonons. The ultralow thermal conductivity in -MgAgSb is attributed to its atomic dynamics being altered by the structure distortion, which presents a possible microscopic route to enhance the performance of similar thermoelectric materials.