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Fujihara, Hiro*; Toda, Hiroyuki*; Ebihara, Kenichi; Kobayashi, Masakazu*; Mayama, Tsuyoshi*; Hirayama, Kyosuke*; Shimizu, Kazuyuki*; Takeuchi, Akihisa*; Uesugi, Masayuki*
International Journal of Plasticity, 174, p.103897_1 - 103897_22, 2024/03
Times Cited Count:0Hydrogen(H) embrittlement in high-strength aluminum(Al) alloys is a crucial problem. H accumulation at the interface of precipitates in Al alloy is considered to cause embrittlement. However, there is no quantitative knowledge regarding the interaction between H distribution and stress field near cracks. In this study, using a multi-modal three-dimensional image-based simulation combining the crystal plasticity finite element method and H diffusion analysis, we tried to capture the stress distribution near the crack, its influence on the H distribution, and the probability of crack initiation in the experimental condition. As a result, it was found that grain boundary cracks transition to quasi-cleavage cracks in the region where the cohesive energy of the semi-coherent interface of MgZn precipitates decreases due to H accumulation near the tip. We believe the present simulation method successfully bridges nanoscale delamination and macroscale brittle fracture.
Tang, J.*; Wang, Y.*; Fujihara, Hiro*; Shimizu, Kazuyuki*; Hirayama, Kyosuke*; Ebihara, Kenichi; Takeuchi, Akihisa*; Uesugi, Masayuki*; Toda, Hiroyuki*
Scripta Materialia, 239, p.115804_1 - 115804_5, 2024/01
Times Cited Count:0 Percentile:0(Nanoscience & Nanotechnology)Stress corrosion cracking (SCC) behaviors induced by the combination of external and internal hydrogen (H) in an Al-Zn-Mg-Cu alloy were systematically investigated via in situ 3D characterization techniques. SCC of the Al-Zn-Mg-Cu alloy could initiate and propagate in the potential crack region where the H concentration exceeded a critical value, in which the nanoscopic H-induced decohesion of -MgZn precipitates resulted in macroscopic cracking. External H that penetrated the alloy from the environment played a crucial role during the SCC of the Al-Zn-Mg-Cu alloy by generating gradient-distributed H-affected zones near the crack tips, which made Al alloys in water environment more sensitive to SCC. Additionally, the pre-existing internal H was driven toward the crack tips during plastic deformation. It was involved in the SCC and made contributions to both the cracks initiation and propagation.
Takahashi, Seiki*; Kikuchi, Hiroaki*; Ara, Katsuyuki*; Ebine, Noriya; Kamada, Yasuhiro*; Kobayashi, Satoru*; Suzuki, Masahide
Journal of Applied Physics, 100(2), p.023902_1 - 023902_6, 2006/07
Times Cited Count:36 Percentile:75.26(Physics, Applied)Magnetic minor hysteresis loops of low carbon steel and Fe metal have been measured during neutron radiation at 563 K in a nuclear reactor. For investigation of nucleation mechanism of copper precipitates and dislocation loops, special attention was paid to minor-loop coefficients, which are deduced from simple relations between minor-loop parameters and are very sensitive to lattice defects. We found that with increasing neutron fluence, the minor-loop coefficients of low carbon steel sharply increase and show a maximum at the fluence of 110 cm, followed by a slow decrease. The appearance of the maximum suggests the presence of two mechanisms of internal stress; while copper precipitates and dislocation loops in the matrix make the internal stress increase, those grown in the vicinity of dislocations compensate the internal stress of dislocations. On the other hand, the minor-loop coefficients show a monotonic increase with neutron fluence in Fe metal.
Ebihara, Kenichi; Fujihara, Hiro*; Shimizu, Kazuyuki*; Yamaguchi, Masatake; Toda, Hiroyuki*
no journal, ,
Hydrogen embrittlement (HE) is an inevitable problem in strengthening aluminum alloys. In the alloys, H diffusively segregates into interfacial defects such as grain boundaries and phase interfaces, weakening the atomic bonds there and causing embrittlement. Hence there is a possibility to suppress HE by reducing the interfacial segregation of H. Recently, atomic-level calculations have revealed that a second-phase particle of tin (Sn) in aluminum alloys can trap H in its interior. Furthermore, suppression of HE has been reported experimentally in tin-doped aluminum alloys. In this study, a code for simulating H diffusion in duplex steels was applied to H diffusion in aluminum containing a Sn second-phase particle to evaluate the possibility of H penetration into the particle according to the experimental conditions. As a result, it was confirmed that some amount of H can penetrate into the particles. This contributes to the verification of the experiment by simulation.