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Journal Articles

Evidence of electronic polarization of the As ion in the superconducting phase of F-doped LaFeAsO

Kim, J.*; Fujiwara, Akihiko*; Sawada, Tomohiro*; Kim, Y.*; Sugimoto, Kunihisa*; Kato, Kenichi*; Tanaka, Hiroshi*; Ishikado, Motoyuki*; Shamoto, Shinichi; Takata, Masaki*

IUCrJ, 1(3), p.155 - 159, 2014/05

 Times Cited Count:2 Percentile:21.58(Chemistry, Multidisciplinary)

Using a charge density analysis based on synchrotron radiation X-ray powder diffraction data, we found that the charge carriers only accumulated in the iron layer of the superconducting phase of LaFeAsO$$_{1-x}$$F$$_{x}$$ at low temperatures. Analysis of the electrostatic potential distribution revealed the concerted enhancement of the electronic polarization of the As ions and the carrier redistribution.

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