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Kitatsuji, Yoshihiro; Okugaki, Tomohiko*; Kasuno, Megumi*; Kubota, Hiroki*; Maeda, Koji*; Kimura, Takaumi; Yoshida, Zenko; Kihara, Sorin*
Journal of Chemical Thermodynamics, 43(6), p.844 - 851, 2011/06
Times Cited Count:8 Percentile:30.19(Thermodynamics)Standard Gibbs energies for transfer (G) of actinyl ions (AnO; z = 2 or 1; An: U, Np or Pu) between an aqueous solution and an organic solution were determined based on distribution method combined with voltammetry for ion transfer at the interface of two immiscible electrolyte solutions. The organic solutions examined were nitrobenzene, 1,2-dichloroethane, benzonitrile, acetophenone and 2-nitrophenyl octyl ether. Irrespective of the type of organic solutions, G of UO, NpO and PuO were nearly equal to each other and slightly larger than that of Mg. The G of NpO was extraordinary large compared with those of ordinary monovalent cations. The dependence of G of AnO on the type of organic solutions was similar to that of H or Mg. The G of An and An were also discussed briefly.
Inoue, Kazuko*; Yamaguchi, Yasuo*; Ishii, Yoshinobu; Yamauchi, Hiroki; Shishido, Toetsu*
Materials Science Forum, 539-543, p.3267 - 3272, 2007/00
Magnetic field effect on a Heusler-type NiMnGa off-stoichiometric alloy having a martensitic transformation temperature around room temperature which is coincident with a Curie temperature has been investigated. The precess of martensitic transforation of a single crystal was investigated by neutron diffraction under the magnetic field up to 8 Tesla. It was found that the magnetic field, which is applied at a temperature near the transformation temperature, causes the martensitic transformation. The process of the transformation caused by the increase of magnetic field is quite similar to the process caused by the decrease of temperature.
Inoue, Kazuko*; Yamaguchi, Yasuo*; Ishii, Yoshinobu; Yamauchi, Hiroki; Hiraka, Haruhiro*
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