Yoneda, Yasuhiro; Noguchi, Yuji*
Japanese Journal of Applied Physics, 60(SF), p.SFFA08_1 - SFFA08_10, 2021/11
BiNaTiO (abbreviated as BNT) is a lead-free material but exhibits relatively large piezoelectric properties, a lot of researches have been conducted. We performed local structural analysis using high-quality BNT with a stoichiometrically correct composition, and found a chemical order structure of Bi/Na in locally. BNT undergoes a phase transition to a cubic phase at 400C. We estimated that a new disorder structure will appear in the high-temperature phase. In the high temperature phase, pair distribution function (PDF) analysis using synchrotron radiation high-energy X-rays was performed. As a result, we found that Bi shifts from 200C, and this shift becomes an order parameter for the phase transition.
Im, S.*; Jee, H.*; Suh, H.*; Kanematsu, Manabu*; Morooka, Satoshi; Koyama, Taku*; Nishio, Yuhei*; Machida, Akihiko*; Kim, J.*; Bae, S.*
Journal of the American Ceramic Society, 104(9), p.4803 - 4818, 2021/09
Fujiwara, Hidenori*; Umetsu, Rie*; Kuroda, Fumiaki*; Miyawaki, Jun*; Kashiuchi, Toshiyuki*; Nishimoto, Kohei*; Nagai, Kodai*; Sekiyama, Akira*; Irizawa, Akinori*; Takeda, Yukiharu; et al.
Scientific Reports (Internet), 11(1), p.18654_1 - 18654_9, 2021/09
Kubota, Takahide*; Shimada, Yusuke*; Tsuchiya, Tomoki*; Yoshikawa, Tomoki*; Ito, Keita*; Takeda, Yukiharu; Saito, Yuji; Konno, Toyohiko*; Kimura, Akio*; Takanashi, Koki*
Nanomaterials (Internet), 11(7), p.1723_1 - 1723_11, 2021/07
Fujimori, Shinichi; Takeda, Yukiharu; Yamagami, Hiroshi; Yamamoto, Etsuji; Haga, Yoshinori
Electronic Structure (Internet), 3(2), p.024008_1 - 024008_8, 2021/06
Sekine, Yurina; Nankawa, Takuya; Yamada, Teppei*; Matsumura, Daiju; Nemoto, Yoshihiro*; Takeguchi, Masaki*; Sugita, Tsuyoshi; Shimoyama, Iwao; Kozai, Naofumi; Morooka, Satoshi
Journal of Environmental Chemical Engineering, 9(2), p.105114_1 - 105114_12, 2021/04
Remediating toxic ion contamination is crucial for protecting human health and the environment. This study aimed to provide a powerful strategy for effectively utilizing bone waste from the food production and preparation industries for removal of toxic ions. Here, we show that immersing pig bone in NaHCO solution produced a carbonated nanohydroxyapatites (C-NHAP). The C-NHAP exhibited high adsorptivity for Sr, Cd, Pb, and Cu. The strontium adsorptivity was about 250 and 4,500 times higher than that of normal bone and synthetic HAP, respectively. The C-NHAP is an eco-friendly, high-performance material that is simple to prepare and should be useful for tackling problems of food waste disposal and environmental pollution.
Fukuda, Tatsuya*; Takahashi, Ryo*; Hara, Takuhi*; Ohara, Koji*; Kato, Kazuo*; Matsumura, Daiju; Inaba, Yusuke*; Nakase, Masahiko*; Takeshita, Kenji*
Journal of Nuclear Science and Technology, 58(4), p.399 - 404, 2021/04
Hiraka, Haruhiro*; Matsumura, Daiju; Horigane, Kazumasa*; Mizuki, Junichiro*
Journal of Physics and Chemistry of Solids, 150, p.109870_1 - 109870_8, 2021/03
Shick, A. B.*; Fujimori, Shinichi; Pickett, W. E.*
Physical Review B, 103(12), p.125136_1 - 125136_12, 2021/03
Tanida, Hajime; Okamoto, Yoshihiro
X-sen Bunseki No Shimpo, 52, p.69 - 80, 2021/03
In the two-dimensional imaging XAFS method using an X-ray CCD detector, a transmission method has been applied to heavy elements with absorption edges at relatively high energies. Although the transmission method requires the sample to be an optimal thickness, the high-energy X-rays have high transmission capability, and can be applied to relatively thick samples. In this study, we attempted to develop a fluorescence method for fast screening of transition metal elements with the low energy X-ray absorption edges and their valence distribution in the samples such as glass materials, which are difficult to make thin. In order to obtain XAFS spectra with high sensitivity and positional resolution, a direct imaging detector without a scintillator and a pinhole were used. The results were demonstrated with a highly brilliant synchrotron radiation undulator X-ray with variable incident energy.
Wang, Y.*; Jia, G.*; Cui, X.*; Zhao, X.*; Zhang, Q.*; Gu, L.*; Zheng, L.*; Li, L. H.*; Wu, Q.*; Singh, D. J.*; et al.
Chem, 7(2), p.436 - 449, 2021/02
Tsuda, Yasutaka; Gueriba, J. S.*; Makino, Takamasa*; Dio, W. A.*; Yoshigoe, Akitaka; Okada, Michio*
Scientific Reports (Internet), 11, p.3906_1 - 3906_8, 2021/02
Matsumura, Daiju; Kato, Kazuo*
Hoshako, 34(1), p.3 - 11, 2021/01
no abstracts in English
Okamoto, Yoshihiro; Kobayashi, Hidekazu; Shiwaku, Hideaki; Sasage, Kenichi; Hatakeyama, Kiyoshi*; Nagai, Takayuki
Journal of Non-Crystalline Solids, 551, p.120393_1 - 120393_8, 2021/01
The chemical state of ruthenium in simulated iron phosphate radioactive waste glass was investigated by conventional X-ray absorption fine structure (XAFS) and imaging XAFS analyses. The EXAFS analysis suggested that ruthenium was contained as glass phase when content of the waste components was less than 10wt.% in 30 mol%FeO-PO base glass. In other samples, crystalline RuO was predominant. According to the imaging XAFS analysis, RuO particles in all samples had length smaller than 50m. Aggregations of RuO, which are found in nuclear waste borosilicate glass, were not seen in any of the iron phosphate glass samples.
Kataoka, Noriyuki*; Tanaka, Masashi*; Hosoda, Wataru*; Taniguchi, Takumi*; Fujimori, Shinichi; Wakita, Takanori*; Muraoka, Yuji*; Yokoya, Takashi*
Journal of Physics; Condensed Matter, 33(3), p.035501_1 - 035501_6, 2021/01
Fujimori, Shinichi; Kawasaki, Ikuto; Takeda, Yukiharu; Yamagami, Hiroshi; Nakamura, Ai*; Homma, Yoshiya*; Aoki, Dai*
Journal of the Physical Society of Japan, 90(1), p.015002_1 - 015002_2, 2021/01
Lai, W.-H.*; Wang, H.*; Zheng, L.*; Jiang, Q.*; Yan, Z.-C.*; Wang, L.*; Yoshikawa, Hirofumi*; Matsumura, Daiju; Sun, Q.*; Wang, Y.-X.*; et al.
Angewandte Chemie; International Edition, 59(49), p.22171 - 22178, 2020/12
Takeda, Yukiharu; Oya, Shinobu*; Pham, N. H.*; Kobayashi, Masaki*; Saito, Yuji; Yamagami, Hiroshi; Tanaka, Masaaki*; Fujimori, Atsushi*
Journal of Applied Physics, 128(21), p.213902_1 - 213902_11, 2020/12
Jee, H.*; Im, S.*; Kanematsu, Manabu*; Suzuki, Hiroshi; Morooka, Satoshi; Koyama, Taku*; Machida, Akihiko*; Bae, S.*
Journal of the American Ceramic Society, 103(12), p.7188 - 7201, 2020/12
Saeki, Morihisa*; Yomogida, Takumi; Matsumura, Daiju; Saito, Takumi*; Nakanishi, Ryuzo*; Tsuji, Takuya; Oba, Hironori*
Analytical Sciences, 36(11), p.1371 - 1378, 2020/11
We measured X-ray absorption fine structure (XAFS) and Raman spectra of isopolymolybdates(VI) in HNO solution (0.15- 4.0 M), which change their geometries depending on acid concentration, and performed simultaneous resolution of the XAFS and Raman data using a multivariate curve resolution by alternating least-squares (MCR-ALS) analysis. In iterative ALS optimization, initial data matrices were prepared by two different methods. The MCR-ALS result of single XAFS data matrix shows large dependence on the preparation method of the initial data matrices. The MCR-ALS result of an augmented matrix of Raman and XAFS data has little dependence on the initial data matrices. It indicates that the augmentation method effectively improves the rotation ambiguities in the MCR-ALS analysis of the XAFS data. Based on the model fitting of the pure EXAFS oscillations, we revealed the change of [MoO(HO)] [MoO(HO)] [HMoO(HO)] in the highly concentrated HNO solution.