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Auh, Y. H.*; Neal, N. N.*; Arole, K.*; Regis, N. A.*; Nguyen, T.*; Ogawa, Shuichi*; Tsuda, Yasutaka; Yoshigoe, Akitaka; Radovic, M.*; Green, M. J.*; et al.
ACS Applied Materials & Interfaces, 17(21), p.31392 - 31402, 2025/05
phases in undoped and Ca-modified sodium niobatesAso, Seiyu*; Matsuo, Hiroki*; Yoneda, Yasuhiro; Morikawa, Daisuke*; Tsuda, Kenji*; Oyama, Kenji*; Ishigaki, Toru*; Noguchi, Yuji*
Physical Review B, 111(17), p.174114_1 - 174114_12, 2025/05
We investigate the crystal structures, phase transitions, and phase stability of undoped and Ca-modified NaNbO
through a combined analysis of high-resolution synchrotron radiation X-ray and neutron diffraction, convergent-beam electron diffraction, and density functional theory (DFT) calculations. It is demonstrated that the antiferroelectric (AFE)- phase is stabilized over a wide temperature range of 200 to 800 K by Ca modification, and that the NaNbO
is stabilized by temperature-driven isostatic pressure accompanied by lattice expansion, whereas the Ca-modified NaNbO is induced by composition-induced chemical pressure along with lattice shrinkage.
Kato, Masaru*; Zheng, J.*; Deng, Y.*; Saito, Fumie*; Unuma, Yuki*; Oka, Sayuki*; Tamura, Kazuhisa; Yagi, Ichizo*
ACS Catalysis, 15(10), p.7710 - 7719, 2025/04
Times Cited Count：0Shinotsuka, Hiroshi*; Nagata, Kenji*; Yoshikawa, Hideki*; Ogawa, Shuichi*; Yoshigoe, Akitaka
Applied Surface Science, 685, p.162001_1 - 162001_11, 2025/03
Times Cited Count：1 Percentile：0.00(Chemistry, Physical)Silicon (Si) 2p photoelectron spectra of thermally oxidized Si(001) surfaces were analyzed using Bayesian estimation, a type of mathematical statistical processing, considering spin-orbit interactions. The accuracy of the estimation of fitting parameters and the model selection of the number of peaks were discussed. The spectral analysis was performed without any prior information on the positions of other Si peaks, except for the prominent bulk Si peak, and without using chemical-state assumptions. Our method completely verified previous findings on the surface species and the changes in peaks due to oxidation-induced strain as oxidation progressed.
Nakasawa, Hayato*; Shobu, Takahisa; Tominaga, Aki; Fujii, Masashi*; Matsumoto, Hironari*; Matsuda, Michiko*; Shimada, Takeshi*; Trivedi, V.*; Tachibana, Makoto*; Tsujii, Naohito*; et al.
Funtai Oyobi Fummatsu Yakin, 72(Suppl.), p.S997 - S1001, 2025/03
Egashira, Naoya*; Matsuda, Tomoki*; Okuchi, Takuo*; Seto, Yusuke*; Ito, Yusuke*; Shobu, Takahisa; Nakanii, Nobuhiko*; Sano, Tomokazu*; 4 of others*
Journal of Applied Physics, 137(10), p.105903_1 - 105903_8, 2025/03
Times Cited Count：1 Percentile：0.00(Physics, Applied)Hojo, Tomohiko*; Koyama, Motomichi*; Kumai, Bakuya*; Zhou, Y.*; Shibayama, Yuki; Shiro, Ayumi*; Shobu, Takahisa; Saito, Hiroyuki*; Ajita, Saya*; Akiyama, Eiji*
ISIJ International, 65(2), p.284 - 296, 2025/02
O
, FeUO
, and UO
-Zr-stainless steel system samples generated in an oxidative atmosphere in the presence of malonic acidTonna, Ryutaro*; Sasaki, Takayuki*; Okamoto, Yoshihiro; Kobayashi, Taishi*
Journal of Nuclear Materials, 605, p.155561_1 - 155561_9, 2025/02
Times Cited Count：0 Percentile：0.00(Materials Science, Multidisciplinary)Yoshigoe, Akitaka; Tsuda, Yasutaka; Kobata, Masaaki; Okane, Tetsuo; Satou, Yukihiko; Okochi, Takuo*
e-Journal of Surface Science and Nanotechnology (Internet), 23(1), p.16 - 21, 2025/02
Yomogida, Takumi
Hoshako, 38(1), p.19 - 25, 2025/01
High-energy-resolution fluorescence detection-X-ray absorption near-edge structure (HERFD-XANES) spectroscopy has enabled us to discuss the electronic structure of actinide compounds in more detail than with conventional XANES spectroscopy. We are conducting research with the aim of contributing to the prediction of the migration behavior of trace actinide elements in the environment by performing actinide speciation in various environmental samples. In this paper, we introduce the content of the discussion of the electronic state of U from the perspective of basic science, which is important for advancing application of HERFD-XANES spectroscopy to environmental science.
Fukada, Yukimasa; Aoyagi, Yumito*; Yokoyama, Misaki*; Horibe, Yoichi*; Kano, Jun*; Kaneda, Miyu*; Fujii, Tatsuo*; Yoshigoe, Akitaka; Kobata, Masaaki; Fukuda, Tatsuo; et al.
Journal of Electronic Materials, 54, p.686 - 692, 2025/01
Times Cited Count：0 Percentile：0.00(Engineering, Electrical & Electronic)no abstracts in English
Nankawa, Takuya
Shikizai Kyokai-Shi, 98(1), p.2 - 6, 2025/01
The use of lacquer in Japan has a very long history dating back to the Jomon period. Lacquer painting is known for its beautiful colors and superior resistance to chemicals and seawater compared to today's petroleum products. Despite these excellent properties, it is very difficult to measure the structure of lacquer films, which cause the excellent physical properties and few people have investigated about it. In this study, we focused on the interactions between urushiol in raw lacquer and black lacquer and by using quantum beams, and we analyzed the nano-structure in raw lacquer and black lacquer, which is responsible for the color difference.
Sm synchrotron-radiation-based M
ssbauer and 
SR studies of SmRu
Ge
Tsutsui, Satoshi; Ito, Takashi; Nakamura, Jin*; Yoshida, Mio*; Kobayashi, Yoshio*; Yoda, Yoshitaka*; Nakamura, Jumpei*; Koda, Akihiro*; Higashinaka, Ryuji*; Aoki, Dai*; et al.
Interactions (Internet), 245(1), p.55_1 - 55_9, 2024/12
Sm synchrotron-radiation-based Mssbauer spectroscopy of Sm-based heavy fermion compoundsTsutsui, Satoshi; Higashinaka, Ryuji*; Mizumaki, Masaichiro*; Kobayashi, Yoshio*; Nakamura, Jin*; Ito, Takashi; Yoda, Yoshitaka*; Matsuda, Tatsuma*; Aoki, Yuji*; Sato, Hideyuki*
Interactions (Internet), 245(1), p.9_1 - 9_10, 2024/12
Kato, Yuto*; Sasaki, Takayuki*; Tonna, Ryutaro*; Kobayashi, Taishi*; Okamoto, Yoshihiro
Applied Geochemistry, 175, p.106196_1 - 106196_9, 2024/11
Times Cited Count：1 Percentile：0.00(Geochemistry & Geophysics)Cl on Cu oxide Surfaces; CuO(111) and bulk CuO precursor "29"; Structure on Cu(111)Hayashida, Koki*; Tsuda, Yasutaka; Murase, Natsumi*; Yamada, Takashi*; Yoshigoe, Akitaka; Di
o, W. A.*; Okada, Michio*
Applied Surface Science, 669, p.160475_1 - 160475_6, 2024/10
Times Cited Count：0 Percentile：0.00(Chemistry, Physical)Kobayashi, Taishi*; Sato, Yutaro*; Tonna, Ryutaro*; Matsumura, Daiju; Sasaki, Takayuki*; Ikeda, Atsushi
Dalton Transactions (Internet), 53(46), p.18616 - 18628, 2024/10
Times Cited Count：0 Percentile：0.00(Chemistry, Inorganic & Nuclear)Kato, Hiroyuki S.*; Muroyama, Mizuho*; Kobayakawa, Nano*; Muneyasu, Riku*; Tsuda, Yasutaka; Murase, Natsumi*; Watanabe, Seiya*; Yamada, Takashi*; Kanematsu, Yusuke*; Tachikawa, Masanori*; et al.
Journal of Physical Chemistry Letters (Internet), 15(43), p.10769 - 10776, 2024/10
Times Cited Count：1 Percentile：42.16(Chemistry, Physical)