Organization of malonamides from the interface to the organic bulk phase

Micheau, C.; Ueda, Yuki; Motokawa, Ryuhei; Akutsu, Kazuhiro*; Yamada, Norifumi*; Yamada, Masako*; Moussaoui, S. A.*; Makombe, E.*; Meyer, D.*; Berthon, L.*; et al.

Journal of Molecular Liquids, 401, p.124372_1 - 124372_12, 2024/05

https://doi.org/10.1016/j.molliq.2024.124372

Supramolecular organization of extractant molecules impacts metal ions separation behavior. Probing bulk and interfacial structures of the relevant systems is expected to provide key insights into the metal ion selectivity and kinetic aspects. The supramolecular features of two solvent extraction systems based on malonamide extractants THMA in toluene and DBMA in n-heptane were studied using small-angle X-ray scattering for the organic bulk phases, as well as interfacial tension and neutron reflectivity measurements for the interfaces. In the bulk solution, THMA forms dimeric/trimeric associates but no aggregates in toluene, while DBMA forms large aggregates in n-heptane. On the other hand, THMA accumulates in a diffuse layer at the interface at high THMA concentration, whereas DBMA forms a compact but thinner layer. After Pd(II) extraction, the thickness of interfacial layers decreases in the case of THMA, and totally vanishes in the case of DBMA. Based on these new structural information, two mechanisms are proposed for Pd(II) and Nd(III) extraction with malonamides. In toluene, THMA associates slightly accumulate in the vicinity of the interface, then coordinate Pd(II) and diffuse into the organic bulk phase. In n-heptane, DBMA aggregates adsorb at the interface then pick up Nd(III) cations in their polar cores and finally diffuse into the bulk.

Quantum critical behavior of the hyperkagome magnet MnCoSi

Yamauchi, Hiroki; Sari, D. P.*; Yasui, Yukio*; Sakakura, Terutoshi*; Kimura, Hiroyuki*; Nakao, Akiko*; Ohara, Takashi; Honda, Takashi*; Kodama, Katsuaki; Igawa, Naoki; et al.

Physical Review Research (Internet), 6(1), p.013144_1 - 013144_9, 2024/02

https://doi.org/10.1103/PhysRevResearch.6.013144

Development of a non-destructive depth-selective quantification method for sub-percent carbon contents in steel using negative muon lifetime analysis

Ninomiya, Kazuhiko*; Kubo, Kenya*; Inagaki, Makoto*; Yoshida, Go*; Chiu, I.-H. ; Kudo, Takuto*; Asari, Shunsuke*; Sentoku, Sawako*; Takeshita, Soshi*; Shimomura, Koichiro*; et al.

Scientific Reports (Internet), 14, p.1797_1 - 1797_8, 2024/01

https://doi.org/10.1038/s41598-024-52255-5

The amount of C in steel, which is critical in determining its properties, is strongly influenced by steel production technology. We propose a novel method of quantifying the bulk C content in steel non-destructively using muons. This revolutionary method may be used not only in the quality control of steel in production, but also in analyzing precious steel archaeological artifacts. A negatively charged muon forms an atomic system owing to its negative charge, and is finally absorbed into the nucleus or decays to an electron. The lifetimes of muons differ significantly, depending on whether they are trapped by Fe or C atoms, and identifying the elemental content at the muon stoppage position is possible via muon lifetime measurements. The relationship between the muon capture probabilities of C/Fe and the elemental content of C exhibits a good linearity, and the C content in the steel may be quantitatively determined via muon lifetime measurements. Furthermore, by controlling the incident energies of the muons, they may be stopped in each layer of a stacked sample consisting of three types of steel plates with thicknesses of 0.5 mm, and we successfully determined the C contents in the range 0.20 - 1.03 wt% depth-selectively, without sample destruction.

Water fraction dependence of the aggregation behavior of hydrophobic fluorescent solutes in water-tetrahydrofuran

Tsuji, Hayato*; Nakahata, Masaki*; Hishida, Mafumi*; Seto, Hideki*; Motokawa, Ryuhei; Inoue, Takeru*; Egawa, Yasunobu*

Journal of Physical Chemistry Letters (Internet), 14(49), p.11235 - 11241, 2023/12

https://doi.org/10.1021/acs.jpclett.3c02882

Magnetic ordering and structural phase transitions of NdSn ( = Rh and Ir)

Shimoda, Ami*; Iwasa, Kazuaki*; Kuwahara, Keitaro*; Sagayama, Hajime*; Nakao, Hironori*; Ishikado, Motoyuki*; Ohara, Takashi; Nakao, Akiko*; Hoshikawa, Akinori*; Ishigaki, Toru*

JPS Conference Proceedings (Internet), 38, p.011091_1 - 011091_6, 2023/05

https://doi.org/10.7566/JPSCP.38.011091

Technology development of diamond-base neutron sensors and radiation-resistive integrated-circuits for shielding-free criticality approach monitoring system (Contract research); FY2021 Nuclear Energy Science & Technology and Human Resource Development Project

Collaborative Laboratories for Advanced Decommissioning Science; High Energy Accelerator Research Organization*

JAEA-Review 2022-031, 89 Pages, 2022/12

JAEA-Review-2022-031.pdf:8.45MB

The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2021. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station, Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2020, this report summarizes the research results of the "Technology development of diamond-base neutron sensors and radiation-resistive integrated-circuits for shielding-free criticality approach monitoring system" conducted in FY2021. The present study aims to develop key components of neutron detection system without a radiation shield for a criticality approach monitoring system. It is required high neutron detection efficiency for a few cps/nv under 1 kGy/h and compact-light-weight to fit constraints of the penetration size and the payload. The project aims to design and evaluate neutron detection devices based on diamond sensors and a high radiation resistive signal-processing data-transfer system based on radiation resistive integrated circuit technologies …

Measurement of differential cross sections for elastic scattering in the momentum range 0.44-0.80 GeV/c

Nanamura, Takuya; Fujita, Manami; Hasegawa, Shoichi; Ichikawa, Masaya; Ichikawa, Yudai; Imai, Kenichi*; Naruki, Megumi; Sato, Susumu; Sako, Hiroyuki; Tamura, Hirokazu; et al.

Progress of Theoretical and Experimental Physics (Internet), 2022(9), p.093D01_1 - 093D01_35, 2022/09

https://doi.org/10.1093/ptep/ptac101

What is chiral susceptibility probing?

Aoki, Shinya*; Aoki, Yasumichi*; Fukaya, Hidenori*; Hashimoto, Shoji*; Rohrhofer, C.*; Suzuki, Kei

Proceedings of Science (Internet), 396, p.050_1 - 050_9, 2022/07

https://doi.org/10.22323/1.396.0050

In the early days of QCD, the axial anomaly was considered as a trigger for the breaking of the symmetry through topological excitations of gluon fields. However, it has been a challenge for lattice QCD to quantify the effect. In this work, we simulate QCD at high temperatures with chiral fermions. The exact chiral symmetry enables us to separate the contribution from the axial breaking from others among the susceptibilities in the scalar and pseudoscalar channels. Our result in two-flavor QCD indicates that the chiral susceptibility, which is conventionally used as a probe for breaking, is actually dominated by the axial breaking at temperatures MeV.

Research and development of radiation-resistant sensor for fuel debris by integrating advanced measurement technologies (Contract research); FY2020 Nuclear Energy Science & Technology and Human Resource Development Project

Collaborative Laboratories for Advanced Decommissioning Science; High Energy Accelerator Research Organization*

JAEA-Review 2021-042, 115 Pages, 2022/01

JAEA-Review-2021-042.pdf:5.18MB

The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2020. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station, Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2018, this report summarizes the research results of the "Research and development of radiation-resistant sensor for fuel debris by integrating advanced measurement technologies" conducted from FY2018 to FY2020. Since the final year of this proposal was FY2020, the results for three fiscal years were summarized. The present study aims to in-situ measure and analyze the distribution status and criticality of flooded fuel debris. For this purpose, we construct a neutron measurement system by developing compact diamond neutron sensor and integrated circuit whose radiation resistance was improved by circuit design.

Study of and at GeV with the Belle detector

Kovalenko, E.*; Tanida, Kiyoshi; Belle Collaboration*; 181 of others*

Physical Review D, 104(11), p.112006_1 - 112006_12, 2021/12

https://doi.org/10.1103/PhysRevD.104.112006