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Report No.

Radiation-induced reactions $$via$$ the lowest excited states in cinnamic acid crystals

Maekawa, Yasunari; Inaba, Tomonori; Hobo, Hiroki; Narita, Tadashi*; Koshikawa, Hiroshi; Moon, S.; Kato, Jun; Yoshida, Masaru

Radiation-induced reactions of cinnamic acid derivatives have been examined and compared them with photoreactions in the crystalline states; all the reaction products were exactly the same as those of the photoreactions, indicating that the reactions proceed only via the lowest excited state to give [2+2]cycloadducts, E/Z isomerization products, or starting molecules.



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