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Photoluminescent dinuclear lanthanide complexes with Tris(2-pyridyl)carbinol acting as a new tetradentate bridging ligand

Watanabe, Masayuki   ; Nankawa, Takuya*; Yamada, Teppei*; Kimura, Takaumi ; Namiki, Kosuke*; Murata, Masaki*; Nishihara, Hiroshi*; Tachimori, Shoichi

A tripodal ligand, tris(2-pyridyl)carbinol affords a novel tetradentate coordination mode in homodinuclear lanthanide complexes, which exhibit remarkably short distance between the metal ions. Strong fluorescence of Eu(III) and Tb(III) complexes with the ligand demonstrate that the ligand has a suitable excited state for energy transfer from the ligand to Eu(III) and Tb(III) center.



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Category:Chemistry, Inorganic & Nuclear



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