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X-ray diffraction study on GaAs(001)-2$$times$$4 surfaces under molecular-beam epitaxy conditions

Takahashi, Masamitsu; Yoneda, Yasuhiro   ; Mizuki, Junichiro

The GaAs(001)-$$(2times4)$$ reconstructed surface was investigated by in situ surface X-ray diffraction. The sample was subjected to measurements under molecular-beam epitaxy conditions without being transferred another chamber. Several X-ray diffraction patterns were measured with increasing the substrate temperature within the $$beta$$-phase of GaAs(001)-$$(2times4)$$ in a constant As flux of 5$$times$$10$$^{-7}$$ Torr. At relatively low temperatures up to 545$$^circ$$C, the observed X-ray diffraction patterns agree well to the $$beta$$2(2$$times$$4) surface. However, a different X-ray diffraction pattern was obtained at 585$$^circ$$C, while the $$2times 4$$ periodicity still persited. This change is explained by partial As-dimer desorption which results in a mixture of the $$beta$$2(2$$times$$4) and $$alpha$$2(2$$times$$4) structures.

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Category:Chemistry, Physical

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