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炭酸ガス冷却炉におけるフェライト系炉心材料の腐食に関する調査・検討

lnvestigation for corrosion behavior of ferritic core materials in C0$$_{2}$$ gas cooled reactor

上平 明弘; 鵜飼 重治; 水田 俊治

not registered; not registered; Mizuta, Shunji

高速増殖炉(以下FBRという。)の実用化戦略調査研究の一環である炭酸ガス冷却炉の燃料設計評価に資するために、フェライト鋼の炭酸ガス腐食に関連する文献を調査し、炭酸ガス腐食に影響を及ぼす因子を整理した。特にブレイクアウェイが発生するまでの腐食挙動について、温度依存性・Si量依存性・Cr量依存性について定量的な評価を行い、次のような腐食評価式を策定した。(式省略)

The corrosion behavior of ferritic stainless steels applied to core components under C0$$_{2}$$ gas environment was investigated in order to be helpful to fuel design in C0$$_{2}$$ gas cooled reactor as the feasibility study for fast breeder reactor. The dependence of the corrosion behavior, before a breakaway occurs, on C0$$_{2}$$ gas temperature, Si and Cr contents of ferritic steels was determined quantitatively. The following correlations to calculate the metal loss thickness was established. X = 4.4w w = √(k$$times$$t) k = $$alpha$$ $$times$$ exp( - 5.45[Si]) $$times$$ exp( - 1.09[Cr]) $$times$$ exp( - 11253/T) $$alpha$$ = 1.65 $$times$$ 10$$^{8}$$$$sim$$4.40 $$times$$ 10$$^{9}$$ X : metal loss thickness[$$mu$$ml, w : corrosion weight gain [mg/cm$$^{2}$$] k : parabola constant [(mg/cm$$^{2}$$)$$^{2}$$/hr], t : time [hr], $$alpha$$ : constant [Si] : Si content[wt.%], [Cr] : Cr content [wt.%], T : temperature [K]

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