Study on coated layer materia1 performance of coated particle fuel FBR (II); High temperature property and capability of coating to thick layer of TiN

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"Helium Gas Cooled Coated Particle Fue1 FBR" is one of attractive core concepts in the Feasibility Study on Commercialized Fast Reactor Cycle System in Japan, and the design study is presently proceeded. As one of key technologies of this concept, the coated layer material is important, and ceramics is considered to be a candidate material because of the superior refractory. Based on existing knowledge, TiN is regarded to be a possible candidate material, to which some property tests and evaluations have been conducted. In this study, preliminary tests about the high temperature property and the capability of thick layer coating of TiN have been conducted. Results of these tests come to the following conclusions. (1)Heating tests of two kinds of TiN layer specimens coated by PVD (Physical Vapor Deposition) and CVD (Chemical Vapor Deposition) were conducted. As a result, as for CVD coating specimens, remarkable change was not observed on the layer up to 2,000C, therefore we concluded that the layer by CVD had applicability up to high temperature of actual operation level. On the other hand, as for PVD coating specimens, an unstable behavior that the layer changed to a mesh like texture was observed on a 2,000C heated specimen, therefore the applied PVD method is not considered to be promising as the coating technique. (2)The surface conditions of some parts inside CVD device were investigated in order to evaluate possibility of TiN thick coating (100m). As a result, around 500m of TiN coating layer was observed on the condition of multilayer. Therefore, we conclude that CVD has capability of coating up to thick layer in actual coated particle fuel fabrication.