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Influence of diluent on radiolysis of amides in organic solution

Sugo, Yumi; Izumi, Yoshinobu*; Yoshida, Yoichi*; Nishijima, Shigehiro*; Sasaki, Yuji  ; Kimura, Takaumi ; Sekine, Tsutomu*; Kudo, Hiroshi*

The radiolytic behavior of ${it N,N,N',N'}$-tetraoctyldiglycolamide, ${it N,N'}$-dimethyl-${it N,N'}$-dioctyl-2-(3'-oxapentadecyl)malonamide, and ${it N,N}$-dioctylhexanamide in ${it n}$-dodecane was investigated by irradiation with $$gamma$$-rays and electron pulses. The results showed ${it n}$-dodecane has a sensitization effect on the radiolysis of these amides, owing mainly to a charge transfer from radical cations of ${it n}$-dodecane to the amide molecules in the primary process observed in pulse radiolysis.



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Category:Chemistry, Physical



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