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圧縮ベントナイト中のフミン酸の拡散挙動

Diffusion behavior of humic acid in compacted bentonite

飯島 和毅  ; 吉川 英樹; 黒澤 精一*

Iijima, Kazuki; Yoshikawa, Hideki; Kurosawa, Seiichi*

透過拡散法を用いて、0.1mol/dm$$^{3}$$のNaCl溶液条件下で、圧縮ベントナイト(クニゲルV1)中のフミン酸の拡散挙動を調べた。乾燥密度1.2Mg/m$$^{3}$$の条件で約100日後にフミン酸の破過が認められたが、乾燥密度1.6及び1.8では500日経過後も破過が認められなかった。GPCによる透過前後のフミン酸の分子量分布測定結果から、圧縮ベントナイトのフィルター効果により、比較的分子量の大きいフミン酸は拡散できず、小さいフミン酸分子だけが拡散している可能性が示唆された。

Diffusion behavior of humic acid in compacted bentonite was investigated with Kunigel V1 in 0.1M NaCl solution. In case of 1.2 Mg/m$$^{3}$$ of dry density, breakthrough of the fumic acid was observed after 100 days. On the other hand, in case of 1.6 and 1.8 of dry density, no breakthrough was observed even after 500 days. Based on the measurement of size distribution of humic acid by GPC, it is suggested that relatively bigger humic acid cannot diffuse but smaller one due to the filtration effect of compacted bentonite.

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