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Synthesis of endohedral $$^{133}$$Xe-fullerenol by using higher fullerene

高次フラーレンによる$$^{133}$$Xeフラレノールの合成

渡辺 智; 片渕 竜也*; 石岡 典子; 松橋 信平

Watanabe, Satoshi; Katabuchi, Tatsuya*; Ishioka, Noriko; Matsuhashi, Shimpei

Hydrophilic endohedral $$^{133}$$Xe-fullerenols [$$^{133}$$Xe@C$$_{76}$$(OH)$$_{x}$$ and $$^{133}$$Xe@C$$_{84}$$(OH)$$_{x}$$] were synthesized from hydrophobic endohedral $$^{133}$$Xe-fullerenes. The yields were found to depend on the solubility of endohedral $$^{133}$$Xe-fullerenols in o-dichlorobenzene and water phases, reflecting the number of OH groups of the product. The endohedral $$^{133}$$Xe-fullerenols stored in 0.9 % NaCl solution were stable enough for the use in nuclear medicine.

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