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Hexagonal BCN films prepared by RF plasma-enhanced CVD

Mannan, M. A.*; Nagano, Masamitsu*; Hirao, Norie*; Baba, Yuji  

Hexagonal boron carbonitride (h-BCN) films have been synthesized on silicon (100) substrate by radio frequency plasma enhanced chemical vapor deposition from tris(dimethylamino)-borane (TDMAB) as a precursor. X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy revealed that the film with a composition of B$$_{46}$$C$$_{18}$$N$$_{36}$$ had sp$$^{2}$$ B-C-N atomic hybridization. Near edge X-ray absorption fine structure suggested that the local structure of BCN showed different atomic orientation to the substrate.

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Category:Chemistry, Multidisciplinary

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