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Report No.
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Oxide conversion of salt waste from dry reprocessing

Sato, Fuminori ; Terunuma, Hitoshi*; Arai, Osamu*; Myochin, Munetaka

Oxide conversion using water vapor and boron oxide (B$$_{2}$$O$$_{3}$$) was studied to treat salt waste from dry reprocessing. Parameter tests to CsCl and NaCl-2CsCl salt were performed and fundamental data such as conversion rate, etc. were acquired. To understand the process behavior, a reaction analysis based on thermodynamic equilibrium calculation considering salt (NaCl, CsCl), oxide (Na$$_{2}$$O, Cs$$_{2}$$O, B$$_{2}$$O$$_{3}$$) and gas (H$$_{2}$$O, Ar, HCl, NaCl, CsCl) phase was performed. The validity of analysis was confirmed by comparison with the experiment. Using this result, process condition of the oxide conversion (ex. temperature, added amount of H$$_{2}$$O and B$$_{2}$$O$$_{3}$$, etc.) was discussed.

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