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Degradation mechanism of graft-type polymer electrolyte membranes for fuel cells

Enomoto, Kazuyuki; Takahashi, Shuichi*; Iwase, Takanori*; Yamashita, Takashi*; Maekawa, Yasunari

Degradation mechanism of the graft-type polymer electrolyte membranes prepared by radiation techniques in the hot water have been studied in detail using UV-vis, GPC, NMR, and wide-angle X-ray scattering. The hydrothermal stability is found to be strongly related to the phase separation of the ion-containing hydrophilic grafts and hydrophobic polymers.

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