Development of advanced reprocessing system using high selective and controllable precipitants, 1; Overview of system and recent advances on precipitation behavior of uranyl ions

Nogami, Masanobu*; Kawasaki, Takeshi*; Takao, Koichiro*; Noda, Kyoko*; Sugiyama, Yuichi*; Harada, Masayuki*; Ikeda, Yasuhisa*; Morita, Yasuji  ; Chikazawa, Takahiro*; Kikuchi, Toshiaki*; Nishimura, Kenji*

A reprocessing system for spent FBR fuels based on the two precipitation processes has been proposed. In this system, first only U(VI) species are precipitated using pyrrolidone derivatives (NRP) with low hydrophobicity and donicity, and secondly residual U(VI) and Pu(IV, VI) are precipitated simultaneously using pyrrolidone derivative with high precipitation ability. In order to develop such a reprocessing method, behavior of uranyl ions in HNO has been studied using various novel NRP. In this presentation, recent advances on precipitation behavior and of uranyl ions and calcination of U(VI)-NRP will be introduced.