Basic study on the mineralization of organic solvents by the silver mediated electrochemical oxidation process with the ultrasound agitation

Kobayashi, Fuyumi ; Ishii, Junichi; Shirahashi, Koichi ; Umeda, Miki ; Sakuraba, Koichi

The silver mediated electrochemical oxidation (Ag/MEO) process with the ultrasound agitation has been developed for the purpose of the mineralization of organic wastes containing transuranium nuclides at the nuclear fuel reprocessing process. In the Ag/MEO process, organic solvents are decomposed by divalent silver cations under the relatively low temperature and the ambient pressure condition. The ultrasound agitation is effective in mixing the electrolytic solutions and the organic solvents, and is expected to promote the oxidation of the organic solvents. Therefore, the Ag/MEO process with the ultrasound agitation could be a candidate for the treatment of organic solvents. Destruction tests of TBP and dodecane by the Ag/MEO process were conducted to optimize some treatment conditions. Under optimized conditions, the destruction tests of kerosene and TODGA were carried out. It was confirmed that the Ag/MEO process is effective for the mineralization of these organic solvents.