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Morphology-controlled graft polymerization in poly(ether ether ketone) films

Hasegawa, Shin; Iwase, Hiroki; Koizumi, Satoshi; Onuma, Masato*; Maekawa, Yasunari

Radiation grafting of ethyl styrylsulfonate (EtSS) onto poly(ether ether ketone) (PEEK) film with various crystallinity was performed. The crystallinity in the range of 10$$sim$$30% has strong influence on the grafting degrees. The PEEK film with crystallinity of 11$$sim$$25% showed any dose effect on grafting degrees with 60%. By SAXS analysis, it was found that grafting process strongly depended on lamellar structure into PEEK membrane.

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