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High-pressure synthesis and physical properties of new iron (nickel)-based superconductors

新鉄(ニッケル)系超伝導体の物性と高圧合成法

Shirage, P. M.*; 宮沢 喜一*; 石角 元志; 木方 邦宏*; Lee, C.-H.*; 竹下 直*; 松畑 洋文*; 熊井 玲児*; 富岡 泰秀*; 伊藤 利充*; 鬼頭 聖*; 永崎 洋*; 社本 真一  ; 伊豫 彰*

Shirage, P. M.*; Miyazawa, Kiichi*; Ishikado, Motoyuki; Kiho, Kunihiro*; Lee, C.-H.*; Takeshita, Nao*; Matsuhata, Hirofumi*; Kumai, Reiji*; Tomioka, Yasuhide*; Ito, Toshimitsu*; Kito, Hijiri*; Eisaki, Hiroshi*; Shamoto, Shinichi; Iyo, Akira*

高圧合成を用いてLnFeAsO系超伝導体の合成を行いその評価を行い、特に酸素欠損,Lnイオン半径の変動,外圧のTcに与える影響を調べた。すべての実験データは結晶構造と超伝導の強い相関を示している。単結晶PrFeAsO$$_{1-y}$$の上部臨界磁場測定より異方性は5程度で銅酸化物より小さいことがわかった。また、高圧合成法は122系の物質合成・単結晶に対しても有効であることを示す。

We have utilized a high-pressure (HP) technique to synthesize a series of newly-discovered iron (nickel)-based superconductors. The effect of (O)-deficiency, variation of $$Ln$$ ions, and the external pressure on $$T$$$$_{rm c}$$ are examined. All the experimental data indicate strong correlation between the crystal structure and the superconductivity of the oxypnictide superconductors. Upper critical field measurement on single crystalline sample of PrFeAsO$$_{1-y}$$ shows the superconducting anisotropy of 5, which is smaller than cuprates. We also demonstrate that HP technique is applicable for the so-called "122" systems.

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パーセンタイル:79.84

分野:Physics, Applied

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