Refine your search:     
Report No.
 - 

Oxidation and reduction behaviors of plutonium and uranium mixed oxide powders

Hiroka, Shun ; Kato, Masato  ; Tamura, Tetsuya*; Nelson, A. T.*; McClellan, K. J.*; Suzuki, Kiichi  

As research and development activities for MOX fuel pellet production, oxidation and reduction behaviors of MOX powders were investigated by thermogravimetry and X-ray diffraction measurements. It was observed that the oxidation limit decreased with oxidizing temperature and Pu content. The MOX powders showed a two-step oxidation and kinetic stability under non-stoichiometry. The oxidation rates were evaluated from the isothermal oxidation tests. It was found that the reduction temperature of M$$_{4}$$O$$_{9}$$ + M$$_{3}$$O$$_{8}$$ was higher than that of M$$_{4}$$O$$_{9}$$. This indicated that the reduction of M$$_{4}$$O$$_{9}$$ was prevented by the existence of M$$_{3}$$O$$_{8}$$. Activation energy of the reduction was derived from the non-isothermal reduction tests. The data are expected to contribute to establishing a control technique for O/M ratio during MOX powder storage and pellet production.

Accesses

:

- Accesses

InCites™

:

Altmetrics

:

[CLARIVATE ANALYTICS], [WEB OF SCIENCE], [HIGHLY CITED PAPER & CUP LOGO] and [HOT PAPER & FIRE LOGO] are trademarks of Clarivate Analytics, and/or its affiliated company or companies, and used herein by permission and/or license.