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Oxygen hole state in A-site ordered perovskite ACu$$_3$$Ru$$_4$$O$$_{12}$$ (A = Na, Ca, and La) probed by resonant X-ray emission spectroscopy

Mizumaki, Masaichiro*; Mizokawa, Takashi*; Agui, Akane; Tanaka, Sotaro*; Takatsu, Hiroshi*; Yonezawa, Shingo*; Maeno, Yoshiteru*

In this study, we report the O 1$$s$$ and Cu 2$$p$$ X-ray absorption spectroscopy (XAS) and resonant X-ray emission spectroscopy (RXES) study on the A-site ordered perovskite ACu$$_3$$Ru$$_4$$O$$_{12}$$ (A = Na, Ca, and La). Hartree-Fock calculation and cluster model calculation were carried out to analyze O 1$$s$$ and Cu 2$$p$$ XAS spectra. The O 1$$s$$ RXES spectra indicate that the number of O 2$$p$$ holes increases in going from La to Ca to Na. In addition, the Cu 2$$p$$ RXES spectra reveal that the charge-transfer energy decreases in going from La to Ca to Na.

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Category:Physics, Multidisciplinary

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