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Studies of ion-exchange chromatographic behavior of Rf and Db using automated rapid chemical separation apparatuses in JAEA

Tsukada, Kazuaki  ; Toyoshima, Atsushi; Asai, Masato  ; Kasamatsu, Yoshitaka*; Li, J.*; Ishii, Yasuo; Haba, Hiromitsu*; Sato, Tetsuya   ; Nagame, Yuichiro ; Sch$"a$del, M.

We will report studies of ion-exchange chromatographic behavior of element 104, rutherfordium (Rf), and element 105, dubnium (Db), in JAEA. The experiments based on an atom-at-a-time scale have been performed using an automated rapid ion-exchange separation apparatuses, AIDA and AIDA-II. We have found interesting information for the complex formations of Rf with chloride, nitrate, sulfate, and fluoride ions and Db with fluoride ions in aqueous solutions.

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