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Report No.

Diffusion behavior of D$$_{2}$$O in the film on Fe oxidized at high temperature in air

Haruna, Takumi*; Yamamoto, Tatsuya*; Miyairi, Yoji*; Shibata, Toshio*; Taniguchi, Naoki ; Sakamaki, Keiko ; Tachikawa, Hirokazu*

Diffusion coefficients of D$$_{2}$$O in the films was determined in order to estimate corrosion rate of carbon steel for the overpack in ground water. Fe plates were heated to form oxide films. The films were characterized with XRD and SEM. After that, the specimen was contacted with D$$_{2}$$O for 5184 ks, followed by subjected to TDS to obtain an amount of D$$_{2}$$O absorbing into the film. As a result, single-layered film of Fe$$_{3}$$O$$_{4}$$ was formed at 573 and 723 K, and double-layered film of Fe$$_{2}$$O$$_{3}$$ and Fe$$_{3}$$O$$_{4}$$ was formed at 873 K. It was found that an amount of D$$_{2}$$O in the film correlated linearly with a square root of the absorption period, and that the amount was steady for a long period. From the results and Fick's second law, diffusion coefficients of D$$_{2}$$O was determined as 9.7$$times$$10$$^{-13}$$ cm$$^{2.}$$s$$^{-1}$$ for the Fe$$_{3}$$O$$_{4}$$ film, and 5.5$$times$$10$$^{-13}$$ cm$$^{2.}$$s$$^{-1}$$ to 2.2$$times$$10$$^{-12}$$ cm$$^{2.}$$s$$^{-1}$$ for Fe$$_{2}$$O$$_{3}$$ film.



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