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Time-resolved observation of molecular adsorbed oxygen at Si(100)-2$$times$$1 surface using real-time synchrotron radiation photoelectron spectroscopy

Yoshigoe, Akitaka ; Okada, Ryuta; Teraoka, Yuden; Iwai, Yutaro*; Yamada, Yoichi*; Sasaki, Masahiro*

Understanding of fundamental aspects of oxidation at Si(100) surface using O$$_{2}$$ gas is essential for fabrication of gate-oxide films with the thickness of atomic-scale in Si-based MOSFET. The study of precursor states prior to dissociative adsorption is important to clarify the oxidation mechanism. We present the time-evolution of molecular chemisorbed oxygen observed by synchrotron radiation real-time photoelectron spectroscopy.

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