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Report No.

Electrodeposition of actinide; Reduction and deposition of Np

Kitatsuji, Yoshihiro  ; Ouchi, Kazuki  ; Otobe, Haruyoshi  ; Kihara, Sorin*

Electrolytic reduction of neptunium ion in the weak acidic solution was investigated. On the cyclic voltammogram of Np(V) in the solution of pH 3.8, reduction and deposition of Np was observed. Stripping current due to oxidation of deposited Np was also appeared. Stripping voltammetry after preelectrolysis at definite potential was carried out. Stripping currents were almost constant despite variation of preelectrolysis time and concentration of Np(V). Difference of reduction-deposition behavior between U and Np was discussed.



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