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Separation and recovery of radioactive ions by metal-organic-frameworks

Nankawa, Takuya; Yamada, Teppei*; Ogoshi, Yurie; Kuwahara, Akira; Alexandros, K.*; David, S.*; Marco, Z.*; Jansat, S.*; Troy, D. M.*; Matthew, J. R.*

In this study, we synthesized series of MOFs with the formula of (NH$$_{4}$$)[Ln(C$$_{2}$$O$$_{4}$$)$$_{2}$$(HO] (Ln = Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb) to remove radioactive ions from solution. And we investigated the behavior of ion uptake by changing the host metals. Moreover, we tried a new radioactive ion recovery cycle by recovering the radioactive ions from the MOF and the starting MOF from the resulting MOFs.

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