余裕深度処分環境におけるふげん圧力管(Zr-2.5wt%Nb合金)の腐食速度の評価,2; 5ヶ年経過データによる長期腐食の考察

Corrosion test of Fugen pressure tube (Zr-2.5wt%Nb alloy) under the sub-surface disposal environment, 2; Examination of long-term corrosion rate by 5 years keeping sample

菅谷 敏克; 中谷 隆良 ; 坂井 章浩 

Sugaya, Toshikatsu; Nakatani, Takayoshi; Sakai, Akihiro

【本報告書は、掲載論文に用いた腐食速度の算出にかかる水素発生データについて、データ取得の信頼性について問題があることが判明したため、一時的に公開を取りやめています。】処分事業の安全評価を行うために必要な核種溶出率の設定を目的に、Zr-2.5wt%Nb合金に対してガス蓄積型腐食試験法を適用し、低温、低酸素およびアルカリ条件下で長期の腐食速度を取得してきた。本報では、長期的な腐食速度の把握を目的に、試験期間5ヶ年(60ヶ月)の腐食速度を取得し、試験期間2ヶ年(24ヶ月)経過までの腐食速度と比較したところ、今回取得した試験期間5ヶ年(60ヵ月)の腐食速度は、試験期間2ヶ年(24ヶ月)までの結果同様、経過時間の-2/3乗に比例するとした評価が適用できると考える。

[The article has been found to have a problem about reliability of the corrosion data acquisition, and thus it is unavailable to download the full text in accordance with authors' intentions to retract the report.] For the purpose of the setting of the rate of nuclide elution necessary to safety assessment, we planned the gas-accumulating type corrosion test on Zr-2.5wt%Nb alloy in order to obtain long-term corrosion rate under low temperature, low oxygen and alkaline conditions assuming the disposal environment. A corrosion rate over a testing period of 5 years is acquired with the aim to grasp a long-term corrosion rate behavior in this report. This corrosion rate is compared with the same data that was previously acquired over a testing period of 2 years. As a result, it is confirmed that an evaluation method that is proportional to the minus cubic root of corrosion time squared can be applicable to the corrosion rate behavior acquired this time over a testing period of 5 years, which is the same result in evaluating the corrosion rate behavior acquired over a testing period of 2 years.