• help
  • PC | SP
  • JP | EN
          
Refine your search：     
Report No.
 - 
Clear All
Return to the previous page

Speciation of isopolymolybdate(VI) in a highly concentrated HNO$$_{3}$$ solution by Raman and EXAFS spectroscopies

Saeki, Morihisa*; Yomogida, Takumi   ; Matsumura, Daiju   ; Saito, Takumi*; Nakanishi, Ryuzo*; Tsuji, Takuya  ; Okamoto, Yoshihiro  ; Oba, Hironori*  

Speciation of isopolymolybdates in a highly concentrated HNO$$_{3}$$ solution was investigated by Raman spectroscopy and Mo K-edge extended X-ray absorption fine structure (EXAFS). A series of Raman spectra and EXAFS oscillations were analyzed using Multivariate Curve Resolution-Alternating Least Squares (MCR-ALS). The MCR-ALS analysis gives us the fraction profile in change of [Mo$$_{36}$$O$$_{112}$$(H$$_{2}$$O)$$_{16}$$]$$^{8-}$$$$rightarrow$$[Mo$$_{2}$$O$$_{5}$$]$$^{2+}$$$$rightarrow$$[MoO$$_{2}$$]$$^{2+}$$ with the increase of the HNO$$_{3}$$ concentration.

Language

 :

Japanese

Journal

 :

Volume

 :

Number

 :

Pages

 :

Publication Year/Month

 :

Meeting title

 :

第12回分子科学討論会

Held date

 :

2018/09

Location (city)

 :

福岡

Location (country)

 :

日本

Patent information

 :

PDF

 :


Paper URL

 :

DOI for research data

 :

Keywords

 :

ラマン分光法; モリブデン; X線吸収分光

Research Facility

 :

第4研究棟  ;SPring-8(大型放射光施設)

Press Release

 :

Article of JAEA R&D Review

 :

Cooperating Institute

 :

Accesses

 :

- Accesses

InCites™

 :

Altmetrics

 :

[CLARIVATE ANALYTICS], [WEB OF SCIENCE], [HIGHLY CITED PAPER & CUP LOGO] and [HOT PAPER & FIRE LOGO] are trademarks of Clarivate Analytics, and/or its affiliated company or companies, and used herein by permission and/or license.

Return to the previous page