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Report No.

Treatment of pharmaceuticals/antibiotics in wastewater by combination of zeolite adsorbent with ionizing radiation

Taguchi, Mitsumasa*; Kumagai, Yuta   ; Kimura, Atsushi*

The technology for the decomposition of trace amounts of halogenated pharmaceuticals/antibiotics was developed in wastewater by use of the combination method of zeolite adsorbent and ionizing radiation. HMOR, a hydrophobic high-silica mordenite-type zeolite, was employed to concentrate 2-chlorophenol (2-ClPh) as a simple model of halogenated pharmaceuticals/antibiotics. HMOR adsorbed above 99% of 2-ClPh from dilute aqueous solutions. The yield of Cl$$^{-}$$ production in HMOR mixture corresponded to the aqueous solution containing 10 fold higher concentration of dissolved 2-ClPh. Clofibrate and triclosan, one of chlorinated pharmaceuticals/antibiotics, in real wastewater were treated by use of the combination method of HMOR and ionizing radiation. Production yield of Cl$$^{-}$$ by use of the adsorbent was about twice higher than that in aqueous solution, and HMOR was contributed for effective reduction of chlorinated pharmaceuticals/antibiotics in real wastewater.



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