Pd nanoparticles on the outer surface of microporous aluminosilicates for the direct alkylation of benzenes using alkanes

アルカンを用いたベンゼンの直接アルキル化のための多孔質アルミノケイ酸塩の外表面にPdナノ粒子を担持した触媒

美崎 慧*; 三輪 寛子*; 伊藤 孝   ; 吉田 健文*; 長谷川 慎吾*; 中村 由紀奈*; 徳竹 駿太*; 高畠 萌*; 下村 浩一郎*; Chun, W.-J.*; 眞中 雄一*; 本倉 健*

Misaki, Satoshi*; Miwa, Hiroko*; Ito, Takashi; Yoshida, Takefumi*; Hasegawa, Shingo*; Nakamura, Yukina*; Tokutake, Shunta*; Takabatake, Moe*; Shimomura, Koichiro*; Chun, W.-J.*; Manaka, Yuichi*; Motokura, Ken*

The direct alkylation of benzenes with simple alkanes is one of the ideal processes for the production of alkylbenzenes. We demonstrated that Pd nanoparticles on the outer surface of H-ZSM-5 are efficient catalysts for direct alkylation. The reaction proceeds through the activation of an alkane on the acid sites present inside the zeolite pores. This process is followed by the nucleophilic addition of an arene to the activated alkane. The spillover of the abstracted hydrogen atoms from the acid sites to the Pd nanoparticles on the outer surface accelerates recombination to H. A maximum toluene conversion of 58.5% and selectivity of 95.6% for the alkylated products are achieved when toluene is reacted with -heptane. -selective alkylation is achieved, due to the effect of the pore size of H-ZSM-5. The SR study of muonium, a pseudo-isotope of hydrogen, in aluminosilicates suggested that the formation of atomic hydrogen is possible and its lifetime is in the sub-microsecond range or longer, which is long enough for chemical reactions.