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Woo, W.*; Kim, Y. S.*; Chae, H. B.*; Lee, S. Y.*; Jeong, J. S.*; Lee, C. M.*; Won, J. W.*; Na, Y. S.*; 川崎 卓郎; Harjo, S.; et al.
Acta Materialia, 246, p.118699_1 - 118699_13, 2023/03
被引用回数:4 パーセンタイル:97.51(Materials Science, Multidisciplinary)In situ neutron diffraction experiments have been performed under loading in cast-wrought (CW) and additively manufactured (AM) equiatomic CoCrNi medium-entropy alloys. The diffraction line profile analysis correlated the faulting-embedded crystal structure to the dislocation density, stacking/twin fault probability, and stacking fault energy as a function of strain. The results showed the initial dislocation density of 1.810 m in CW and 1.310 m in AM. It significantly increased up to 1.310 m- in CW and 1.710 m in AM near fracture. The dislocation density contributed to the flow stress of 470 MPa in CW and 600 MPa in AM, respectively. Meanwhile, the twin fault probability of CW (2.7%) was about two times higher than AM (1.3%) and the stacking fault probability showed the similar tendency. The twinning provided strengthening of 360 MPa in CW and 180 MPa in AM. Such a favorable strengthening via deformation twinning in CW and dislocation slip in AM was attributed to the stacking fault energy. It was estimated as 18.6 mJ/m in CW and 37.5 mJ/m in AM by the strain field of dislocations incorporated model. Dense dislocations, deformation twinning, and atomic-scale stacking structure were examined by using electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM).
Kwon, H.*; Pietrasiak, E.*; 大原 高志; 中尾 朗子*; Chae, B.*; Hwang, C.-C.*; Jung, D.*; Hwang, I.-C.*; Ko, Y. H.*; Kim, K.*; et al.
Inorganic Chemistry, 60(9), p.6403 - 6409, 2021/05
被引用回数:0 パーセンタイル:0.01(Chemistry, Inorganic & Nuclear)The synthesis of sandwich-shaped multinuclear silver complexes with planar penta- and tetranuclear wheel-shaped silver units and a central anion is reported, along with complete spectroscopic and structural characterization. An NMR mechanistic study reveals that silver complexes were formed in the following order: 2Ag 3Ag 5Ag 4Ag. The central hydroxides in 4Ag and 5Ag exhibit exotic physical properties due to the confined environment inside the complex. The size of these silver wheels can be tuned by changing the central anion or extracting/adding one silver atom. This study provides the facile way to synthesize discrete wheel-shaped multinuclear silver complexes and provides valuable insights into the dynamics of the self-assembly process.
Lorusso, G.*; 西村 俊二*; Xu, Z. Y.*; Jungclaus, A.*; Shimizu, Y.*; Simpson, G. S.*; Sderstrm, P.-A.*; Watanabe, H.*; Browne, F.*; Doornenbal, P.*; et al.
Physical Review Letters, 114(19), p.192501_1 - 192501_7, 2015/05
被引用回数:149 パーセンタイル:97.96(Physics, Multidisciplinary)The -decay half-lives of 110 neutron-rich isotopes of the elements from Rb to Sn were measured at the RIBF Facility at RIKEN, Japan. The new data demonstrate the persistence of shell structure far from stability and have direct implications for the -process calculations. In particular, the new half-lives have a global impact on the calculated -process elemental abundances, and alleviate the underproduction of isotopes just above and below the A=130 peak, which in the past required the introduction of shell structure modifications. Reaction-network calculations based on the new data reinforce the notion that the r-process abundance pattern may result from the freeze-out of a (n,)(,n) equilibrium.
Watanabe, H.*; Lorusso, G.*; 西村 俊二*; Otsuka, T.*; Ogawa, K.*; Xu, Z. Y.*; 炭竃 聡之*; Sderstrm, P.-A.*; Doornenbal, P.*; Li, Z.*; et al.
Physical Review Letters, 113(4), p.042502_1 - 042502_6, 2014/07
被引用回数:24 パーセンタイル:77.04(Physics, Multidisciplinary)A new isomer with a half-life of 23.0(8) ms has been identified in Pd at 2406 keV excitation. The proposed spin and parity configuration is 10, with maximally aligned configuration of two neutron hole. -decay from the long-lived isomer was also observed to populated excited states at high spins in Ag. The small energy difference between the 10 and 7 isomers in Pd was interpreted in the frame of the monopole shift of the 1 neutron orbit. The effects of the monopole interaction on the evolution of single-neutron energies below Sn are discussed in terms of central and tensor forces.