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論文

Simultaneous measurement of neutron-induced fission and capture cross sections for $$^{241}$$Am at neutron energies below fission threshold

廣瀬 健太郎; 西尾 勝久; 牧井 宏之; 西中 一朗*; 太田 周也*; 永山 達郎*; 田村 信行*; 後藤 真一*; Andreyev, A. N.; Vermeulen, M. J.; et al.

Nuclear Instruments and Methods in Physics Research A, 856, p.133 - 138, 2017/06

https://doi.org/10.1016/j.nima.2016.12.021
 被引用回数：5 パーセンタイル：44.54(Instruments & Instrumentation)

Fission and capture reactions were simultaneously measured in the neutron-induced reactions of $$^{241}$$Am at J-PARC. Data were taken with the TOF method in $$E_n$$ = 0.1$$sim$$20 eV. The fission events were observed by detecting prompt fission neutrons using liquid organic scintillators. The capture reaction was measured by detecting $$gamma$$ rays from the compound nuclei using the same detectors, where the prompt fission neutrons and capture $$gamma$$ rays were separated by a pulse shape analysis. The cross sections were obtained by normalizing the relative yields at the first resonance to evaluations or other experimental data. The ratio of the fission to capture cross sections at each resonance is compared with those from an evaluated nuclear data library and other experimental data. Some differences were found between the present values and the library/literature values at several resonances.

論文

Ground-state configuration of the $$N=157$$ nucleus $$^{259}$$No

浅井 雅人; 塚田 和明; 阪間 稔*; 羽場 宏光*; 市川 隆敏*; 石井 康雄; 豊嶋 厚史; 石井 哲朗; 西中 一朗; 永目 諭一郎; et al.

Physical Review C, 87(1), p.014332_1 - 014332_6, 2013/01

https://doi.org/10.1103/PhysRevC.87.014332
 被引用回数：6 パーセンタイル：43.66(Physics, Nuclear)

$$^{259}$$Noの基底状態のスピン・パリティ,中性子軌道配位を$$alpha$$崩壊核分光により初めて実験的に同定した。$$^{259}$$Noは、これまでにスピン・パリティや一粒子軌道配位が同定された原子核の中で最も中性子数の多い原子核である。本研究により$$^{259}$$Noの基底状態と娘核$$^{255}$$Fmの231.4keV励起準位の中性子軌道配位が9/2$$^{+}$$[615]と同定され、この領域の原子核における中性子一粒子軌道のエネルギー間隔と順序が明らかになった。中性子数$$N$$=157における9/2$$^{+}$$[615]基底状態の出現は、$$N$$=152と$$N$$=162に存在する変形殻ギャップ間の中性子軌道のエネルギー順序が中性子数が増えるにつれて大きく変化していることを示唆している。

論文

Tilted-foil technique for producing a spin-polarized radioactive isotope beam

平山 賀一*; 三原 基嗣*; 渡辺 裕*; Jeong, S. C.*; 宮武 宇也*; 百田 佐多夫*; 橋本 尚志*; 今井 伸明*; 松多 健策*; 石山 博恒*; et al.

European Physical Journal A, 48(5), p.54_1 - 54_10, 2012/05

https://doi.org/10.1140/epja/i2012-12054-1
 被引用回数：2 パーセンタイル：16.82(Physics, Nuclear)

The tilted-foil method for producing spin-polarized radioactive isotope beams has been studied for the application to nuclear physics and materials science, using the radioactive nucleus $$^8$$Li produced at the Tokai Radioactive Ion Accelerator Complex (TRIAC). We successfully produced polarization in a $$^8$$Li beam using 15 thin polystyrene foils fabricated especially for this purpose. A systematic study of the nuclear polarization as a function of the number of foils, beam energy, tilt angles and foil material has been performed, confirming the features of the tilted-foil technique experimentally. The contributions made to the nuclear polarization of $$^8$$Li nuclei by the atomic states was investigated.

論文

Investigation of fission properties and evaporation residue measurement in the reactions using $$^{238}$$U target nucleus

西尾 勝久; 池添 博; Hofmann, S.*; Ackermann, D.*; Antalic, S.*; 有友 嘉浩; Comas, V. F.*; D$"u$llmann, Ch. E.*; Gorshkov, A.*; Graeger, R.*; et al.

EPJ Web of Conferences, 17, p.09005_1 - 09005_4, 2011/10

https://doi.org/10.1051/epjconf/20111709005
 被引用回数：1 パーセンタイル：47.57(Physics, Nuclear)

Fission fragment mass distributions after full momentum transfer of the projectile were measured in the reactions using a $$^{238}$$U target nucleus bombarded by $$^{30}$$Si, $$^{31}$$P, $$^{34,36}$$S, $$^{40}$$Ar, $$^{40,48}$$Ca projectiles. We observed a strong variation of the distribution as function of bombarding energy. The results were interpreted by the effects of nuclear deformation of the target nucleus on the competition between fusion and quasifission. The symmetric fission includes fusion-fission, wheres as the asymmetric fission represents quasifission. The fusion probabilities were determined with the help of fluctuation-dissipation model. The estimated evaporation residue cross sections ($$^{263,264}$$Sg and $$^{267,268}$$Hs) produced in $$^{30}$$Si + $$^{238}$$U and $$^{34}$$S+$$^{238}$$U reproduced the experimental data.

論文

Nuclear-charge polarization at scission in proton-induced fission of $$^{233}$$U

西中 一朗; 谷川 勝至*; 永目 諭一郎; 中原 弘道*

European Physical Journal A, 47(1), p.1 - 8, 2011/01

https://doi.org/10.1140/epja/i2011-11001-0
 被引用回数：18 パーセンタイル：72.25(Physics, Nuclear)

$$^{233}$$Uの11.5MeV陽子誘起核分裂における二次分裂片の最確核電荷を二重飛行時間法で測定した質量収率と放射化学的手法で測定し文献に報告された部分累積収率と独立収率から決定した。二次分裂片質量数について放出中性子数を補正し、切断点での一次分裂片の核電荷分極を求めた。その結果から、切断点での核電荷分極は、原子核のポテンシャルエネルギーによって決まり、分裂核の質量数,励起エネルギー、そして中性子-陽子数比にほとんど依存しないことを明らかにした。

論文

Neutron one-quasiparticle states in $$^{251}$$Fm$$_{151}$$ populated via the $$alpha$$ decay of $$^{255}$$No

浅井 雅人; 塚田 和明; 羽場 宏光*; 石井 康雄; 市川 隆敏*; 豊嶋 厚史; 石井 哲朗; 永目 諭一郎; 西中 一朗; 小島 康明*; et al.

Physical Review C, 83(1), p.014315_1 - 014315_12, 2011/01

https://doi.org/10.1103/PhysRevC.83.014315
 被引用回数：24 パーセンタイル：79.14(Physics, Nuclear)

$$^{255}$$Noの$$alpha$$崩壊によって励起される$$^{251}$$Fmの励起準位を、$$alpha$$-$$gamma$$同時計数測定並びに$$alpha$$線微細構造測定により詳細に調べた。測定で得られた$$gamma$$遷移の内部転換係数や寿命,一準粒子軌道状態の回転バンドのエネルギー,$$alpha$$遷移の抑止係数をもとに、$$^{251}$$Fmの励起準位と$$^{255}$$Noの基底状態のスピン・パリティ並びに中性子軌道配位を実験的に決定した。中性子数151の原子核における1/2$$^{+}$$[620]準位の励起エネルギーは、陽子数の増加に伴って特に陽子数100以上の原子核において顕著に増加するが、1/2$$^{+}$$[631]準位のエネルギーは陽子数100において減少することが明らかとなった。これらの一準粒子軌道状態のエネルギーの系統性から、陽子数の増加に伴って原子核の変形がどのように変化しているのかを、16重極変形や64重極変形といった高次の変形まで含めて議論した。

論文

Nuclear orientation in the reaction $$^{34}$$S+$$^{238}$$U and synthesis of the new isotope $$^{268}$$Hs

西尾 勝久; Hofmann, S.*; He${ss}$berger, F. P.*; Ackermann, D.*; Antalic, S.*; 有友 嘉浩; Comas, V. F.*; D$"u$llmann, Ch. E.*; Gorshkov, A.*; Graeger, R.*; et al.

Physical Review C, 82(2), p.024611_1 - 024611_9, 2010/08

https://doi.org/10.1103/PhysRevC.82.024611
 被引用回数：79 パーセンタイル：96.03(Physics, Nuclear)

Synthesis of isotopes of the element hassium was studied using the reaction $$^{34}$$S+$$^{238}$$U$$rightarrow$$$$^{272}$$Hs*. At a kinetic energy of 163.0 MeV in the center of mass system we observed one $$alpha$$-decay chain starting at the isotope $$^{267}$$Hs. The cross-section was 1.8$$^{+4.2}_{-1.5}$$pb. At 152.0 MeV one decay of the new isotope $$^{268}$$Hs was observed. It decays with a half-life of 0.38$$^{+1.8}_{-0.17}$$s by 9479$$pm$$16 keV $$alpha$$-particle emission. Spontaneous fission of the daughter nucleus $$^{264}$$Sg was confirmed. The measured cross-section was 0.54$$^{+1.3}_{-0.45}$$pb. In-beam measurements of fission fragment mass distributions were performed to obtain information on the fusion probability at various orientation of the deformed target nucleus. The distributions changed from symmetry to asymmetry when the beam energy was changed from above-barrier to sub-barrier values, indicating orientation effects on fusion and/or quasifission. It was found that the distribution of symmetric mass fragments originates not only from fusion-fission, but has a strong component from quasifission. This result significantly influences the interpretation of data obtained from measurements of symmetric mass distributions with respect to extracting evaporation residue cross-sections.

論文

Extraction of chromatographic behavior of Rf, Zr, and Hf in HCl solution with styrenedivinylbenzene copolymer resin modified by TOPO (trioctylphosphine oxide)

豊嶋 厚史; 笠松 良崇*; 塚田 和明; 浅井 雅人; 石井 康雄; 當銘 勇人*; 西中 一朗; 佐藤 哲也; 永目 諭一郎; Sch$"a$del, M.; et al.

Journal of Nuclear and Radiochemical Sciences, 11(1), p.7 - 11, 2010/06

https://doi.org/10.14494/jnrs.11.7

本研究では、ラザホージウム(Rf)並びに同族元素Zr, Hfの2.0-7.0M塩酸水溶液からトリオクチルホスフィンオキシド(TOPO)への抽出挙動を調べた。塩酸水溶液の濃度増加に伴ってこれらの元素の抽出率は増加し、その抽出順はZr$$>$$Hf$$geq$$Rfであることを明らかにした。この実験結果から、RfCl$$_{4}$$$$cdot$$2(TOPO)錯体の安定性は同族元素の同じ錯体よりも低いことが考えられる。

論文

Effects of nuclear orientation on fusion and fission process for reactions using uranium target nuclei

西尾 勝久; 池添 博; 光岡 真一; 西中 一朗; 牧井 宏之; 渡辺 裕*; 永目 諭一郎; 大槻 勤*; 廣瀬 健太郎*; Hofmann, S.*

AIP Conference Proceedings 1224, p.301 - 310, 2010/04

https://doi.org/10.1063/1.3431429
 被引用回数：5 パーセンタイル：84.69(Physics, Nuclear)

Results on the measurements of (1) evaporation residue (ER) cross-sections for $$^{30}$$Si, $$^{34}$$S + $$^{238}$$U and of (2) fission fragment mass distributions for $$^{30}$$Si,$$^{34,36}$$S, $$^{40}$$Ar + $$^{238}$$U will be discussed. Measurement of ER cross-section was carried out at GSI by using the velocity filter SHIP. Measurement of fission fragment mass distributions was made by using the JAEA tandem accelerator. In the reaction $$^{30}$$Si + $$^{238}$$U, the ER cross-section for $$^{263}$$Sg(5n) suggested no fusion hindance at above-barrier energy, whereas the one for $$^{264}$$Sg(4n) suggested competition between fusion and quasi-fission at sub-barrier energy. This conclusion is consistent with the measured fragment mass distributions, where the asymmetric fission component associated with quasi-fission appears only at sub-barrier energies. In the reaction of $$^{34}$$S + $$^{238}$$U, the ER cross-sections for $$^{267}$$Hs(5n) and $$^{268}$$Hs(4n, new isotope) suggested fusion hindrance both for above- and sub-barrier energies. With the results of fission fragment mass distributions, it is found that quasi-fission has symmetric fission components when projectile mass is relatively large. We will also discuss the variation of the fragment mass distributions for $$^{30}$$Si,$$^{34,36}$$S, $$^{40}$$Ar + $$^{238}$$U.

論文

Effects of nuclear orientation on fusion and fission in the reaction using $$^{238}$$U target nucleus

西尾 勝久; 池添 博; 光岡 真一; 西中 一朗; 永目 諭一郎; 大槻 勤*; 廣瀬 健太郎*; Hofmann, S.*

EPJ Web of Conferences, 2, p.10001_1 - 10001_3, 2010/03

https://doi.org/10.1051/epjconf/20100210001
 被引用回数：0 パーセンタイル：0.07(Physics, Nuclear)

We have measured the (1) evaporation residue (ER) cross-sections for $$^{30}$$Si, $$^{34}$$S + $$^{238}$$U and (2) fission fragment mass distributions for $$^{30}$$Si,$$^{34,36}$$S, $$^{40}$$Ar. Measurement of ER cross-section was carried out at GSI by using the velocity filter SHIP. Measurement of fission fragment mass distribution was made by using the JAEA tandem accelerator. In the reaction $$^{30}$$Si + $$^{238}$$U, the ER cross-section for $$^{263}$$Sg(5n) suggested no fusion hindrance at above-barrier energy, whereas the one for $$^{264}$$Sg(4n) suggested competition between fusion and fission at sub-barrier energy. This conclusion is consistent with the measured fragment mass distributions, where the asymmetric fission component associated with quasi-fission appears only at sub-barrier energies. In the reaction of $$^{34}$$S + $$^{238}$$U, the ER cross-sections for $$^{267}$$Hs(5n) and $$^{268}$$Hs(4n, new isotope) suggested fusion hindrance both for above- and sub-barrier energies. With the results of fission fragment mass distributions, it is found that quasi-fission has symmetric fission components when projectile mass is relatively large. We will also discuss the variation of the fragment mass distributions for $$^{30}$$Si,$$^{34,36}$$S, $$^{40}$$Ar + $$^{238}$$U.

論文

Effects of nuclear orientation on fission fragment mass distributions in the reactions using actinide target nuclei

西尾 勝久; 池添 博; 光岡 真一; 西中 一朗; 牧井 宏之; 渡辺 裕*; 永目 諭一郎; 大槻 勤*; 廣瀬 健太郎*; Hofmann, S.*

AIP Conference Proceedings 1175, p.111 - 118, 2009/10

https://doi.org/10.1063/1.3258209

Fission fragment properties for the reactions involving actinide target nuclei have been investigated at the JAEA tandem facility. The results showed firstly the appearance of new fission channels. The experimental data are useful for the theoretical study to produce super heavy elements. Also the new fission channels suggested the possible production of the neutron rich nuclei by taking advantage of the new fission channels.

論文

Effects of nuclear orientation on fission fragment mass distributions in the reactions using actinide target nuclei

西尾 勝久; 池添 博; 光岡 真一; 西中 一朗; 牧井 宏之; 渡辺 裕*; 永目 諭一郎; 大槻 勤*; 廣瀬 健太郎*; Hofmann, S.*

AIP Conference Proceedings 1175, p.111 - 118, 2009/10

https://doi.org/10.1063/1.3258209

The influence of nuclear deformation of $$^{238}$$U target nucleus on fusion and fission process was investigated. The study was motivated by larger cross-sections to produce super-heavy nuclei in reactions using actinide target nuclei, compared to those using lead or bismuth target nuclei. We have measured fission fragment mass distributions in the reaction of $$^{30}$$Si,$$^{31}$$P,$$^{34,36}$$S,$$^{40}$$Ar + $$^{238}$$U at JAEA tandem facility. We observed strong variation of the distributions on bombarding energy of projectiles, which indicates that competition between fusion and fission is sensitive to the colliding angle of the projectile to the symmetric axis of $$^{238}$$U. We also measured the evaporation residue cross-sections for $$^{30}$$Si+$$^{238}$$U and $$^{34}$$S+$$^{238}$$U as a direct evidence for fusion. The experiment was carried out at GSI. The results showed that fusion is much hindered in the subbarrier energy, where projectile collides only on the pollar side of the $$^{238}$$U nucleus, whereas the equatorial collision has smaller fusion hindrance. These results indicate that the initial touching configuration influence the subsequent reaction process.

論文

Anionic fluoro complex of element 105, Db

笠松 良崇*; 豊嶋 厚史; 浅井 雅人; 塚田 和明; Li, Z.; 石井 康雄; 當銘 勇人*; 佐藤 哲也; 菊池 貴宏; 西中 一朗; et al.

Chemistry Letters, 38(11), p.1084 - 1085, 2009/10

https://doi.org/10.1246/cl.2009.1084
 被引用回数：15 パーセンタイル：48.93(Chemistry, Multidisciplinary)

105番元素ドブニウム(Db)のフッ化水素酸と硝酸混合水溶液中における陰イオン交換挙動を、新規に開発した迅速イオン交換分離装置を用いて調べた。Dbのフッ化物陰イオン錯体の挙動は、近接の第6周期同族元素タンタル(Ta)の挙動とは大きく異なり、第5周期のニオブ(Nb)の挙動と似ているという特徴的な性質を示すことがわかった。

論文

Oxidation of element 102, nobelium, with flow electrolytic column chromatography on an atom-at-a-time scale

豊嶋 厚史; 笠松 良崇*; 塚田 和明; 浅井 雅人; 北辻 章浩; 石井 康雄; 當銘 勇人; 西中 一朗; 羽場 宏光*; 大江 一弘*; et al.

Journal of the American Chemical Society, 131(26), p.9180 - 9181, 2009/07

https://doi.org/10.1021/ja9030038
 被引用回数：13 パーセンタイル：45.54(Chemistry, Multidisciplinary)

新たに開発したフロー電解カラムクロマトグラフ装置を用い、0.1M$$alpha$$-ヒドロキシイソ酪酸($$alpha$$-HIB)水溶液中における102番元素ノーベリウム(No)の酸化反応をシングルアトムレベルで調べた。最も安定なNo$$^{2+}$$がNo$$^{3+}$$に酸化され、1.0V以上の印加電圧において酸化された$$alpha$$-HIB錯体がカラム中で三価状態を保持することを明らかとした。

論文

Effects of nuclear orientation on fusion and fission process in heavy ion reactions

西尾 勝久; 池添 博; 光岡 真一; 西中 一朗; 渡辺 裕*; 永目 諭一郎; 大槻 勤*; 廣瀬 健太郎*; Hofmann, S.*

AIP Conference Proceedings 1120 (Internet), p.275 - 279, 2009/05

https://doi.org/10.1063/1.3141660

Effects of nuclear deformation of $$^{238}$$U on fusion and fission was investigated in the reactions of $$^{30}$$Si+$$^{238}$$U and $$^{36}$$S + $$^{238}$$U. From the measurement of evaporation residue cross-sections for $$^{30}$$Si+$$^{238}$$U, carried out at GSI, it is concluded that in the sub-barrier region competition between fusion and quasi-fission was suggested whereas at the above barrier region fusion is the main process after the system is captured inside the Coulomb barrier. The fission fragment mass distributions were measured in $$^{30}$$Si+$$^{238}$$U and $$^{36}$$S+$$^{238}$$U at the JAEA tandem facility. Symmetric fission was observed at the above-barrier region, showing the fusion-fission character. In decreasing the energy to the sub-barrier, the asymmetric fission starts to dominate, showing the signature of quasi-fission. The results suggest that the equatorial collision results in fusion whereas the polar collision results in quasi-fission.

論文

Effects of nuclear orientation on fission fragment mass distributions in the reactions of $$^{34,36}$$S+$$^{238}$$U

西尾 勝久; 池添 博; 光岡 真一; 西中 一朗; 渡辺 裕*; 永目 諭一郎; 大槻 勤*; 廣瀬 健太郎*; Hofmann, S.*

AIP Conference Proceedings 1098, p.289 - 294, 2009/03

https://doi.org/10.1063/1.3108831

Fragment mass distributions for fission after full momentum transfer were measured for the reaction $$^{36,34}$$S,+,$$^{238}$$U at bombarding energies around the Coulomb barrier. The experiment was carried out by using the sulfur beams supplied by the JAEA tandem accelerator. The experimental data revealed a transition from symmetry to asymmetry mass distributions when the beam energies were decreased from above-barrier to sub-barrier values. The main components of the asymmetric mass distribution are at $$A$$=200 and $$A=$$74. The asymmetric fission is attributed to quasifission of the reacting system at polar collisions, whereas the symmetric fission originates from the compound nucleus produced in equatorial collisions. The results suggest a strong influence of orientation effects of the deformed target nuclei on fusion.

論文

Adsorption of Db and its homologues Nb and Ta, and the pseudo-homologue Pa on anion-exchange resin in HF solution

塚田 和明; 羽場 宏光*; 浅井 雅人; 豊嶋 厚史; 秋山 和彦*; 笠松 良崇; 西中 一朗; 市川 進一; 安田 健一郎; 宮本 ユタカ; et al.

Radiochimica Acta, 97(2), p.83 - 89, 2009/02

https://doi.org/10.1524/ract.2009.1577
 被引用回数：20 パーセンタイル：77.78(Chemistry, Inorganic & Nuclear)

105番元素ドブニウム(Db)及び周期表上同族の5族元素ニオブ(Nb),タンタル(Ta),擬5族のプロトアクチニウム(Pa)のフッ化水素酸水溶液中における陰イオン交換挙動を観測した。実験にはタンデム加速器施設に設置したオンライン自動迅速イオン交換分離装置を利用し、$$^{248}$$Cm+$$^{19}$$F反応で生成する$$^{262}$$Db(半減期34秒)を対象に13.9Mフッ化水素酸水溶液におけるイオン交換樹脂への分配係数を測定した。上記元素とDbの溶離挙動を比較すると、Dbの分配係数は5族元素Nb及びTaに比べて小さく、その傾向はむしろ擬5族のPaに近いという結果を得た。この結果は超アクチノイド元素であるDbのフッ化物陰イオン錯体が同族元素と異なるという興味深いものである。

論文

Effects of nuclear orientation on the mass distribution of fission fragments in the reaction of $$^{36}$$S + $$^{238}$$U

西尾 勝久; 池添 博; 光岡 真一; 西中 一朗; 永目 諭一郎; 渡辺 裕*; 大槻 勤*; 廣瀬 健太郎*; Hofmann, S.*

Physical Review C, 77(6), p.064607_1 - 064607_5, 2008/06

https://doi.org/10.1103/PhysRevC.77.064607
 被引用回数：121 パーセンタイル：98.15(Physics, Nuclear)

Fragment mass distributions for fission after full momentum transfer were measured for the reaction $$^{36}$$S + $$^{238}$$U at bombarding energies around the Coulomb barrier. The data revealed a transition from symmetry to asymmetry mass distributions when the beam energies were decreased from above-barrier to sub-barrier values. The main components of the asymmetric mass distribution are at $$A_{rm H} approx $$ 200 and $$A_{rm L} approx $$ 74. The asymmetric fission is attributed to quasifission of the reacting system at polar collisions, whereas the symmetric fission originates from the compound nucleus produced in equatorial collisions. The results suggest a strong influence of orientation effects of the deformed target nuclei on fusion.

論文

Fluoride complexation of element 104, rutherfordium (Rf), investigated by cation-exchange chromatography

石井 康雄; 豊嶋 厚史; 塚田 和明; 浅井 雅人; 當銘 勇人; 西中 一朗; 永目 諭一郎; 宮下 直*; 森 友隆*; 菅沼 英夫*; et al.

Chemistry Letters, 37(3), p.288 - 289, 2008/03

https://doi.org/10.1246/cl.2008.288
 被引用回数：20 パーセンタイル：55.03(Chemistry, Multidisciplinary)

104番元素ラザホージウム(Rf)の低次フッ化物錯体の形成を調べるため、HF/HNO$$_{3}$$水溶液系におけるRfの陽イオン交換挙動を4価の陽イオンであるZr, Hf及びThの挙動と比較を行った。AIDA(${it $alpha$}$線測定装置結合型自動迅速イオン交換分離装置)を用いた加速器オンライン実験でRfの陽イオン交換挙動を調べた。原子力機構タンデム加速器施設において、$$^{248}$$Cm($$^{18}$$O,5${it n}$)により合成した$$^{261}$$Rf(半減期: 78s)をHe/KClガスジェット搬送法によりAIDAへ搬送し130秒間捕集した。これを250$$mu$$LのHF/0.1M HNO$$_{3}$$水溶液で溶解し、1.6mm i.d.$$times$$7.0mm又は1.0mm i.d.$$times$$3.5mmの陽イオン交換カラムへ溶離展開させ、その溶出液をTa皿に捕集した。その後、0.1M HF/0.1M HNO$$_{3}$$によってカラム中の残留物を溶出させ、別のTa皿に捕集した。これらを蒸発乾固させた後、600mm$$^{2}$$のPIPS検出器で$$^{261}$$Rfの${it $alpha$}$線を測定しその分配係数を求めた。HF/0.1M HNO$$_{3}$$においてZr, Hf, Th及びRfは、フッ化物イオン濃度の増加に従いその${it K}$ $$_{d}$$値が減少した。これは、これらのイオンにフッ化物イオンが配位することによって、陽イオン交換樹脂への吸着性能が減少したものと考えられる。陽イオン交換樹脂への吸着の強さの順序はZr$$sim$$Hf$$>$$Rf$$>$$Thとなり、これは各元素のイオン半径の大きさの順序と一致した。

論文

Hexafluoro complex of rutherfordium in mixed HF/HNO$$_{3}$$ solutions

豊嶋 厚史; 羽場 宏光*; 塚田 和明; 浅井 雅人; 秋山 和彦*; 後藤 真一*; 石井 康雄; 西中 一朗; 佐藤 哲也; 永目 諭一郎; et al.

Radiochimica Acta, 96(3), p.125 - 134, 2008/03

https://doi.org/10.1524/ract.2008.1474
 被引用回数：28 パーセンタイル：85.1(Chemistry, Inorganic & Nuclear)

$$^{248}$$Cm($$^{18}$$O,5n)$$^{261}$$Rf反応により104番元素ラザホージウム(Rf)を生成し、陰イオンフッ化物錯体の形成を陰イオン交換法を用いて調べた。フッ化物イオン濃度0.0005-0.013MでRfヘキサフルオロ錯体[RfF$$_{6}$$]$$^{2-}$$が形成することを初めて明らかにした。[RfF$$_{6}$$]$$^{2-}$$の形成は同族元素Zr, Hfのヘキサフルオロ錯体と著しく異なり、[RfF$$_{6}$$]$$^{2-}$$の錯形成定数は同族元素Zr, Hfの錯形成定数より少なくとも一桁小さいことを明らかにした。

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