Impact of molybdenum on iodine chemistry during fission product transport phenomenology

Rizaal, M.; Nakajima, Kunihisa; Suzuki, Eriko; Miwa, Shuhei

Annals of Nuclear Energy, 218, p.111433_1 - 111433_10, 2025/08

https://doi.org/10.1016/j.anucene.2025.111433

Neutron capture cross-section measurement at TC-Pn in KUR for holmium among nuclides in decommissioning

Nakamura, Shoji; Endo, Shunsuke; Rovira Leveroni, G.; Kimura, Atsushi; Shibahara, Yuji*

KURNS Progress Report 2024, P. 31, 2025/06

no abstracts in English

Nacre-like MXene/polyacrylic acid layer-by-layer multilayers as hydrogen gas barriers

Auh, Y. H.*; Neal, N. N.*; Arole, K.*; Regis, N. A.*; Nguyen, T.*; Ogawa, Shuichi*; Tsuda, Yasutaka; Yoshigoe, Akitaka; Radovic, M.*; Green, M. J.*; et al.

ACS Applied Materials & Interfaces, 17(21), p.31392 - 31402, 2025/05

https://doi.org/10.1021/acsami.5c03632

Synthesis of BaSiH hydridosilicate at high pressures; A Bridge to BaSiH polyhydride

Beyer, D. C.*; Spektor, K.*; Vekilova, O. Y.*; Grins, J.*; Barros Brant Carvalho, P. H.*; Leinbach, L. J.*; Sannemo-Targama, M.*; Bhat, S.*; Baran, V.*; Etter, M.*; et al.

ACS Omega (Internet), 10(15), p.15029 - 15035, 2025/04

https://doi.org/10.1021/acsomega.4c10502

Hydridosilicates featuring SiH octahedral moieties represent a rather new class of compounds with potential properties relating to hydrogen storage and hydride ion conductivity. Here, we report on the new representative BaSiH obtained from reacting the Zintl phase hydride BaSiH with H fluid at pressures above 4 GPa and subsequent decompression to ambient pressure. It consists of complex SiH ions, which are octahedrally coordinated by Ba counterions. The arrangement of Ba and Si atoms deviates only slightly from an ideal fcc NaCl structure. IR and Raman spectroscopy showed SiH bending and stretching modes in the ranges 800-1200 and 1400-1800 cm, respectively. BaSiH is thermally stable up to 95C above which decomposition into BaH and Si takes place. DFT calculations indicated a direct band gap of 2.5 eV. The discovery of BaSiH consolidates the compound class of hydridosilicates, accessible from hydrogenations of silicides at gigapascal pressures (10 GPa). The structural properties of BaSiH suggest that it presents an intermediate (or precursor) for further hydrogenation at considerably higher pressures to the predicted superconducting polyhydride BaSiH.

Enhanced strength and ductility in an additively manufactured Al10SiMg alloy at cryogenic temperatures

Naeem, M.*; Rehman, A. U.*; Romero Resendiz, L.*; Salamci, E.*; Aydin, H.*; Ansari, P.*; Harjo, S.; Gong, W.; Wang, X.-L.*; 3 of others*

Communications Materials (Internet), 6, p.65_1 - 65_13, 2025/04

https://doi.org/10.1038/s43246-025-00793-4

Magnetite stoichiometry (Fe(II)/Fe(III)) controls on trivalent chromium surface speciation

Scaria, J.*; Pdrot, M.*; Fablet, L.*; Yomogida, Takumi; Nguyen, T. T.*; Sivry, Y.*; Catrouillet, C.*; Pradas del Real, A. E.*; Choueikani, F.*; Vantelon, D.*; et al.

Environmental Science & Technology, 59(11), p.5747 - 5755, 2025/03

https://doi.org/10.1021/acs.est.4c12899

Understanding and predicting the interaction mechanisms between chromium and magnetite is of particular interest to elucidate the biogeochemical behavior of Cr in the environment and to develop optimal soil remediation and water treatment strategies. However, while the elimination of the most toxic form of (Cr(VI)) by its reduction to Cr(III) has widely been documented, elucidating the exact mechanism involved in Cr(III) sorption to magnetite has attracted less attention. This study examined the interaction of Cr(III) solution with 10 nm-sized magnetites, whose stoichiometries were carefully defined and preserved in anaerobic conditions. This study reveals the joint effects of pH and magnetite stoichiometry on Cr(III) sorption mechanism, and that Cr(III)-(hydr)oxide precipitation is not necessarily the driving process of Cr(III) elimination from solutions. These results will help predict the fate and transport of chromium, as well as developing magnetite-based chromium remediation processes.

Remote alpha/beta measurement system with support vector machine algorithm

Morishita, Yuki; Miyamura, Hiroko; Sato, Yuki; Matsubara, Jun*; Sumali, B.*; Mitsukura, Yasue*

Nuclear Instruments and Methods in Physics Research A, p.170368_1 - 170368_16, 2025/03

https://doi.org/10.1016/j.nima.2025.170368

Decommissioning nuclear reactor sites presents challenges due to the presence of various radionuclides, including alpha emitters (e.g., Pu, Am, Cm) and beta emitters (e.g., Cs, Sr-Y), which pose significant internal exposure risks to workers. Traditional measurement methods require multiple instruments and are time-consuming, particularly in high gamma-ray environments. To address these issues, we developed a remote alpha and beta discrimination measurement system that integrates a stilbene scintillator detector with a silicon photomultiplier, enabling simultaneous detection of both alpha and beta particles. This study further incorporates machine learning techniques, specifically Support Vector Machines (SVM), for automatic discrimination, eliminating the need for user-defined thresholds and ensuring consistent operational conditions. The system was tested with known radiation sources, demonstrating over 96% classification accuracy for alpha and beta particles. Measurements conducted in motion effectively identified contamination sources, confirming the system's capability for real-time analysis. This innovative approach enhances radiation safety and efficiency in nuclear decommissioning operations, making it particularly beneficial in environments where human access is limited.

Analytic and Monte Carlo calculations of dose-mean lineal energy for 1 MeV-1 GeV protons with application to radiation protection quality factor

Papadopoulos, A.*; Kyriakou, I.*; Matsuya, Yusuke; Corts-Giraldo, M. A.*; Galocha-Oliva, M.*; Plante, I.*; Steward, R. D.*; Tran, N. H.*; Li, W.*; Daglis, I. A.*; et al.

Radiation and Environmental Biophysics, 64(1), p.117 - 135, 2025/03

https://doi.org//10.1007/s00411-025-01110-w

Radiation quality for determining biological effects is commonly linked to the microdosimetric quantity, especially dose-mean lineal energy y. Calculations of y can be performed by sophisticated Monte Carlo track structure (MCTS) codes. The y estimate depends on the type of the MCTS code and analysis model. This study focused on proton beams with 1 MeV-1 GeV, which are important in radiation protection, space applications, radiation therapy, etc., and compared the estimates of the y in liquid water by various MCTS codes (PHITS, RITRACK, and Geant4-DNA) and analysis models (refined Xapsos model). The comparison results showed that good agreement with the refined Xapsos model and various MCTS codes can be attained at less than 10-20% level, and Q values by the analytic model are also in better agreement with MCTS simulation data. These findings conclude that the refined analytic model might be used as an alternative to time- and CPU-intensive MCTS simulations and advance practical calculations of radiation qualities and risk assessment.

Transport and confinement physics Chapter 2 of the special issue: on the path to tokamak burning plasma operation

Yoshida, M.*; McDermott, R. M.*; Angioni, C.*; Camenen, Y.*; Citrin, J.*; Jakubowski, M.*; Hughes, J. W.*; Idomura, Yasuhiro; Mantica, P.*; Mariani, A.*; et al.

Nuclear Fusion, 65(3), p.033001_1 - 033001_132, 2025/02

https://doi.org/10.1088/1741-4326/ad8ced

Progress in physics understanding and theoretical model development of plasma transport and confinement in the ITPA Transport and Confinement Topical Group since the publication of the ITER Physics Basis was summarized focusing on the contributions to ITER and burning plasma prediction and control. This paper provides a general and streamlined overview on the advances that were mainly led by the ITPA TC joint experiments and joint activities for the last 15 years. This paper starts with the scientific strategy and scope of the ITPA TC Topical group and overall picture of the major progress, followed by the progress of each research field: particle transport, impurity transport, ion and electron thermal turbulent transport, momentum transport, impact of 3D magnetic fields on transport, confinement mode transitions, global confinement, and reduced transport modeling.

Comparison of correlations for thermal creep of FBR MOX

Calabrese, R.*; Hirooka, Shun

Progress in Nuclear Energy, 178, p.105516_1 - 105516_11, 2025/01

https://doi.org/10.1016/j.pnucene.2024.105516

Thermal creep is one of the key properties of mixed oxide (MOX) fuel for innovative fast reactors. Thermal creep of fuel affects markedly the interaction between the fuel and the cladding. A review of correlations available in the literature is presented. The effect of porosity, plutonium concentration, and stoichiometry are discussed also in the light of recent numerical results. Our analysis pointed out some inconsistencies concerning the modelling of the effect of porosity on diffusional creep and a re-evaluation of the effect of plutonium concentration. The discussion suggested that Evans's findings on the effect of stoichiometry should be better assessed as well as the level of increase in creep moving towards stoichiometry. Typical operating conditions of fast breeder reactors confirmed the need for an extension of porosity and temperature correlations' domains. Besides this, a new correlation based on a separate-effect approach has been proposed for fuel performance codes.