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Journal Articles

Xe K-shell X-ray generation using conical nozzle and 25 TW laser

Hayashi, Yukio; Pirozhkov, A. S.; Kando, Masaki; Ogura, Koichi; Kotaki, Hideyuki; Kiriyama, Hiromitsu; Okada, Hajime; Goto, Hideki*; Nishikawa, Tadashi*

Laser and Particle Beams, 31(3), p.419 - 425, 2013/09

 Times Cited Count:1 Percentile:4.63(Physics, Applied)

To increase X-ray photon number generated by laser-cluster interaction, it is important to understand the dependence of X-ray generation on cluster size. We carried out Xe K-shell X-ray generation using a conical nozzle with Xe clusters, the radius of which was controllable by adjusting the backing pressure. The experiment clarifies the result that the Xe K-shell X-ray photon number increases with increasing cluster radius from 8 to 12 nm, and saturates at the radius between 12 and 17 nm. We also investigated the Xe K-shell X-ray photon number dependence on laser intensity, and found that the threshold laser intensity of the Xe K-shell X-ray generation exists between 2$$times$$10$$^{17}$$ and 5$$times$$10$$^{18}$$ W/cm$$^2$$.

Journal Articles

Novel electron-beam-induced reaction of a sulfonium salt in the solid state

Enomoto, Kazuyuki*; Moon, S.*; Maekawa, Yasunari; Shimoyama, Junji*; Goto, Kazuyuki*; Narita, Tadashi*; Yoshida, Masaru

Journal of Vacuum Science and Technology B, 24(5), p.2337 - 2349, 2006/09

 Times Cited Count:5 Percentile:33.55(Engineering, Electrical & Electronic)

The electron beam (EB)-induced reaction of triphenylsulfonium methanesulfonate (1-Ms) in the solid state afforded the benzene-substituted product, biphenyldiphenylsulfonium methanesulfonate (2-Ms), which has not been observed by either photolysis or EB-induced reaction in a solution. The kinetic data revealed that the biphenyl salt 2-Ms exhibited 3.7 times greater kinetic constants for consumption than that of 1-Ms. The EB-induced reaction of benzene-substituted triphenylsulfonium salts, p-biphenyldiphenylsulfonium methanesulfonate (2p-Ms) and (4-phenylthiophenyl)diphenyl- sulfonium methanesulfonate (7) showed the consumption rates of 3.8 and 5.7 times greater than that of 1-Ms. The sulfonium salts with aromatic counter anions showed somewhat higher reactivity than those with aliphatic counter anions. Accordingly, it is concluded that the triphenylsulfonium salts having aryl groups, which exhibit lower ionization potential (Ip), in both cation and anion moieties should exhibit greater decomposition rates.

Journal Articles

Electron-beam induced reactions of sulfonium salts in a crystalline state

Enomoto, Kazuyuki*; Maekawa, Yasunari; Moon, S.; Shimoyama, Junji*; Goto, Kazuyuki*; Narita, Tadashi*; Yoshida, Masaru

Journal of Photopolymer Science and Technology, 17(1), p.41 - 44, 2004/06

 Times Cited Count:2 Percentile:9.04(Polymer Science)

The Electron beams (EB)-induced reactions of triphenylsulfonium methanesulfonate (1) in the crystalline state gave benzene-substituted product, biphenylsulfonium methanesulfonate (2), which has not been observed by either photolysis. In this paper, the EB-induced reactions of triphenylsulfonium salt derivatives, which possesses aromatic/aliphatic counter anions, have been examined. The anionic moiety of sulfonium salts has practically little effect on the formation of biphenyl salt 2 as well as the other products. The consumption rates of the sulfonium salts containing aromatic counter anions are somewhat smaller in a crystalline state and about two times larger than those of the salts with aliphatic counter anions. The greater decomposition rates of the sulfonium salts with aromatic counter anions than those of aliphatic counter anions in an amorphous state are elucidated by lower ionization potential of the salts with aromatic counter anions such as tosyl and naphthyl groups than those with aliphatic counter anions.

Journal Articles

Single crystal growth of the high pressure phase of (VO)$$_{2}$$P$$_{2}$$O$$_{7}$$ at 3GPa

Saito, Takashi*; Terashima, Takashi*; Azuma, Masaki*; Takano, Mikio*; Goto, Tadashi*; Ota, Hiroshi*; Utsumi, Wataru; Bordet, P.*; Johnston, D. C.*

Journal of Solid State Chemistry, 153(1), p.124 - 131, 2000/08

 Times Cited Count:37 Percentile:79.52(Chemistry, Inorganic & Nuclear)

no abstracts in English

JAEA Reports

Report of lower end plug welding, and test and inspection for the JOYO 6th refueling core fuel assembly

Kajiyama, Tadashi; Numata, Kazuaki; Otani, Seiji; *; *; Goto, Tatsuro*; Takahashi, Hideki*

JNC TN8440 2000-010, 45 Pages, 2000/02

JNC-TN8440-2000-010.pdf:1.45MB

This report describes about procedure and consequence of the welding process of the cladding tube and the lower end plug, the process of the test and inspection and the process of shipment for the 6th refueling core fuel assembly (46 fuel assemblies) of the experimental fast reactor JOYO. These works were carried out on July, 1996 from January, 1993 in Tamatukuri inspection branch of quality assurance section, technical administration division, plutonium fuel center. The 6th refueling core fuel assemblies are two kinds of the fuel assembly (1) and (2). The material of the lower end plug and the cladding tube used for the fuel assembly (1) is the type 316 stainless steel grade (here in after referred to as SUS316 grade) and austenitic stainless steel of high nickel content (here in after referred to as PNC 1520). That material used for the fuel assembly (2) is all SUS316 grade. The result of welding and the inspection is shown in the following table.

JAEA Reports

Report of lower endplug welding, and testing and inspecting result for MONJU 1$$^{st}$$ reload core fuel assembly

Kajiyama, Tadashi; Numata, Kazuaki; Otani, Seiji; *; *; Goto, Tatsuro*; Takahashi, Hideki*

JNC TN8440 2000-008, 34 Pages, 2000/02

JNC-TN8440-2000-008.pdf:2.13MB

The procedure and result of lower endplug welding, Test and Inspection and Shipment of the 1$$^{st}$$ reload core fuel assembly (80 Fuel Assemblies) for the fast breeder reactor MONJU should be report, which had examined and inspected in Tamatsukuri Branch, Material Insurance office, Quality Assurance Section, Technical Administration Division, Plutonium Fuel Center (before: Inspection Section, Plutonium Fuel Division), from June 1994 to January 1996. The number of cladding tubes welded to the endplug were total to 13,804, 7,418 for Core - Inside of 43 fuel Assemblies and 6,386 for Core-Outside of 37 fuel Assemblies. 13,794 of them, 7,414 Core-Inside and 6,379 Core-Outside were approved by the test and sent to Plutonium Fuel Center. 10 of them weren't approved mainly because of default welding. Disapproval rating is 0.07%.

JAEA Reports

An investigation report on the defective occurrence of the lower end plug welded section for JOYO MK-III.; An investigation result about the inclusion occurrence

Kajiyama, Tadashi; Numata, Kazuaki; Otani, Seiji; Goto, Tatsuro*; Takahashi, Hideki*

JNC TN8430 2000-007, 44 Pages, 2000/02

JNC-TN8430-2000-007.pdf:5.32MB

Fabrication of the cladding tube with the lower end plug for the core fuel assembly of the experimental fast reactor JOYO and the proto-type fast breeder reactor MONJU has been performed by Tamatsukuri inspection branch of quality assurance section, Technical administration division, Plutonium fuel center since 1989. The fabrication process of the cladding tube with the lower end plug consists of numbering process of fuel element number to the lower end plug, welding process of the lower end plug and the cladding tube, and inspection process after welding (visual inspection, dimensional inspection and X-ray radiography). The processing of cladding tube with the lower end plug which is used for the initial loading core fuel assembly of JOYO MK-III has been carried out from August to May in 1996. The many tungsten inclusions were observed by X-ray radiography in the welds of the cladding tube with the lower end plug that were fabricated in the fourth fabrication campaign performed from July to August in 1996. The investigation of the causes was carried out about the welding process of the cladding tube and the lower end plug based on the fabrication record. The following three items were confirmed as a result. (1)As for the ingredients of inclusions observed by the X-ray radiography, it was proved by EPMA(Electron Probe X-ray Micro-analyzer) analysis that it was the same as the tungsten electrode. (2)Cracks, chips and consumption were observed in the tip of the electrodes used for welding of the lower end plug. And, cracks and chips were observed in the electrodes as well which hadn't been used. (3)It was proved that the tip of the electrode was exhausted remarkably when the distance between the tip of the electrode and the welding section became less than 0.08mm. (here in after to as the distance between the electrodes) Based on the above result, examination of reappearance for the inclusion generation was performed simulating the shape of cracks and chips ...

Oral presentation

Study on improvement of safety for accident conditions in spent fuel pool, 3; Evaluation of decay heat and cladding temperature during accident

Kobayashi, Kensuke*; Goto, Daisuke*; Tojo, Masayuki*; Ikehara, Tadashi*; Kaji, Yoshiyuki; Nemoto, Yoshiyuki

no journal, , 

We evaluate fuel temperature based on the steady state heat transfer analysis with considering accurate fuel history and storage conditions.

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