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Journal Articles

Quantum dynamics of hydrogen in the iron-based superconductor LaFeAsO$$_{0.9}$$D$$_{0.1}$$ measured with inelastic neutron spectroscopy

Yamaura, Junichi*; Hiraka, Haruhiro*; Iimura, Soshi*; Muraba, Yoshinori*; Bang, J.*; Ikeuchi, Kazuhiko*; Nakamura, Mitsutaka; Inamura, Yasuhiro; Honda, Takashi*; Hiraishi, Masatoshi*; et al.

Physical Review B, 99(22), p.220505_1 - 220505_6, 2019/06

AA2019-0126.pdf:0.9MB

 Times Cited Count:3 Percentile:16.31(Materials Science, Multidisciplinary)

Inelastic neutron scattering was performed for an iron-based superconductor, where most of D (deuterium) replaces oxygen, while a tiny amount goes into interstitial sites. By first-principle calculation, we characterize the interstitial sites for D (and for H slightly mixed) with four equivalent potential minima. Below the superconducting transition temperature Tc = 26 K, new excitations emerge in the range 5-15 meV, while they are absent in the reference system LaFeAsO$$_{0.9}$$F$$_{0.1}$$. The strong excitations at 14.5 meV and 11.1 meV broaden rapidly around 15 K and 20 K, respectively, where each energy becomes comparable to twice of the superconducting gap. The strong excitations are ascribed to a quantum rattling, or a band motion of hydrogen, which arises only if the number of potential minima is larger than two.

Journal Articles

Present status of J-PARC linac

Oguri, Hidetomo; Hasegawa, Kazuo; Ito, Takashi; Chishiro, Etsuji; Hirano, Koichiro; Morishita, Takatoshi; Shinozaki, Shinichi; Ao, Hiroyuki; Okoshi, Kiyonori; Kondo, Yasuhiro; et al.

Proceedings of 11th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.389 - 393, 2014/10

no abstracts in English

Journal Articles

Bipartite magnetic parent phases in the iron oxypnictide superconductor

Hiraishi, Masatoshi*; Iimura, Soshi*; Kojima, Kenji*; Yamaura, Junichi*; Hiraka, Haruhiro*; Ikeda, Kazutaka*; Miao, P.*; Ishikawa, Yoshihisa*; Torii, Shuki*; Miyazaki, Masanori*; et al.

Nature Physics, 10(4), p.300 - 303, 2014/04

 Times Cited Count:103 Percentile:95.46(Physics, Multidisciplinary)

Journal Articles

Neutron and X-ray crystallographic analysis of the human $$alpha$$-thrombin-bivalirubin complex at pD 5.0; Protonation states and hydration structure of the enzyme-product complex

Yamada, Taro*; Kurihara, Kazuo; Onishi, Yuki*; Tamada, Taro; Tomoyori, Katsuaki; Masumi, Kenji*; Tanaka, Ichiro*; Kuroki, Ryota; Niimura, Nobuo*

Biochimica et Biophysica Acta; Proteins and Proteomics, 1834(8), p.1532 - 1538, 2013/08

 Times Cited Count:17 Percentile:48.69(Biochemistry & Molecular Biology)

The protonation states and hydration structures of the $$alpha$$-thrombin-bivalirubin complex were studied by joint XN refinement of the single crystal X-ray and neutron diffraction data at resolutions of 1.6 and 2.8 ${AA}$, respectively. The atomic distances were estimated by carrying out X-ray crystallographic analysis at 1.25 ${AA}$ resolution. The complex represents a model of the enzyme-product (EP) complex of $$alpha$$-thrombin. The neutron scattering length maps around the active site suggest that the side chain of H57/H was deuterated. The joint XN refinement showed that occupancies for D$$delta$$1 and D$$epsilon$$2 of H57/H were 1.0 and 0.7, respectively. However, no significant neutron scattering length density was observed around the hydroxyl oxygen O$$gamma$$ of S195/H, which was close to the carboxylic carbon atom of dFPR-COOH. These observations suggest that the O$$gamma$$ atom of S195/H is deprotonated and maintains its nucleophilicity in the EP complex. In addition to the active site, the hydration structures of the S1 subsite and the Exosite I, which are involved in the recognition of bivalirudin, are presented.

Journal Articles

Prevention of powder adhesion on substrate using nanoparticle coating

Suzuki, Michitaka*; Yoshikawa, Mao*; Iimura, Kenji*; Satone, Hiroshi*; Ishii, Katsunori

Funtai Kogakkai-Shi, 50(6), p.405 - 409, 2013/06

The glass substrate is coated by the silica nanoparticle suspension using dipping or spin coat method and dried in an electric oven. The glass substrate surface is covered with nanoparticle thin layer and the transparent and tiny rugged surface can be produced on a substrate. It was experimentally confirmed to prevent dust adhesion by covering the surface of the glass substrate with nanoparticle. The adhesion force between particle and substrate is measured by the centrifugal method and the relation between the adhesion force and the surface roughness is discussed from experimental and theoretical point of view. The measured and calculated results by Van der Waals force show that adhesion force decreased with the increment of the surface roughness. From the results, nanoparticle coating is very effective to prevent the dust adhesion on the substrate and the various application of nanoparticle coating can be expected.

JAEA Reports

Fabrication study of new irradiation facility for $$^{99}$$Mo production in JMTR

Takita, Kenji; Iimura, Koichi; Tomita, Kenji; Endo, Yasuichi; Kanno, Masaru

JAEA-Technology 2012-006, 41 Pages, 2012/03

JAEA-Technology-2012-006.pdf:6.8MB

At JAEA Oarai Research and Developnment Establishment (JAEA Oarai), JAEA Oarai was proceeding a plan to repair JMTR, which is to re-operate in fiscal 2012. Additionally, as an effective utilizati of JMTR, JAEA Oarai is planning to manufacture $$^{99}$$Mo, which is a parent nuclide of $$^{99}$$Tc. $$^{99m}$$Tc is most commonly used as a radiopharmaceution in the field of nuclear medicine. Currently $$^{99}$$Mo supply is dependent only on foreign imports, so JAEA is aiming for working on partially manufacturing $$^{99}$$Mo domestically with industrial circles in Japan. In this article, this report described the choice and fabric of irradiathion facility named Hydraulic Rabbit Facility for manufacturing $$^{99}$$Mo, the technical study of fabrication technique.

Journal Articles

Status of the design and investigation for hydraulic rabbit irradiation facility

Takita, Kenji; Iimura, Koichi; Tomita, Kenji; Endo, Yasuichi; Kanno, Masaru

UTNL-R-0480, p.7_4_1 - 7_4_6, 2012/03

no abstracts in English

Journal Articles

X-ray and neutron protein crystallographic analysis of the trypsin-BPTI complex

Kawamura, Kenji*; Yamada, Taro*; Kurihara, Kazuo; Tamada, Taro; Kuroki, Ryota; Tanaka, Ichiro*; Takahashi, Haruyuki*; Niimura, Nobuo*

Acta Crystallographica Section D, 67(2), p.140 - 148, 2011/02

 Times Cited Count:28 Percentile:88.53(Biochemical Research Methods)

JAEA Reports

Design of fuel transient test facility system

Hosokawa, Jinsaku; Iimura, Koichi; Ogawa, Mitsuhiro; Tomita, Kenji; Yamaura, Takayuki

JAEA-Technology 2010-018, 269 Pages, 2010/08

JAEA-Technology-2010-018.pdf:5.75MB

At Oarai Research and Development Center, Japan Atomic Energy Agency (JAEA) advances the plan of refurbishing Japan Materials Testing Reactor (JMTR) to start the operation in fiscal 2011. Fuel Transient Test Facility is scheduled to be set up as neutron irradiation test equipment of the light-water reactor fuel that uses JMTR after it operates again. The abnormal transition examination device is the irradiation facilities where the output sudden rise examination that makes the light-water reactor fuel an irradiation sample is done to use it to develop the safety evaluation technology and the damage influence evaluation technology of the light-water reactor fuel that reaches high burn-up. In this report, as for the system design, it is a summary to JMTR among detailed designs of the abnormal transition examination device of the installation schedule.

JAEA Reports

Dose evaluation for fuel transient test

Iimura, Koichi; Ogawa, Mitsuhiro; Tomita, Kenji; Tobita, Masahiro

JAEA-Technology 2009-021, 71 Pages, 2009/05

JAEA-Technology-2009-021.pdf:4.34MB

The preparation of a fuel transient test using the JMTR is advanced to conduct its irradiation test from 2011 F.Y. after re-operation of the JMTR. The fuel behavior for high burn-up BWR's under power ramping condition will be evaluated in simulating the BWR environmental condition using the shroud irradiation facility (Oarai Shroud Facility No.1) and $$^{3}$$He power-control type BOCA (Boiling Water Capsule) irradiation facility, which is composed of the capsule control device, $$^{3}$$He power-control device and boiling water capsule. In order to change the fuel irradiation conditions so as to treat high burn-up fuels (from 50 GWD/t-UO$$_{2}$$ to 110 GWD/t-U), it is necessary to revaluate the dose for the safety evaluation at the test fuel failure. In this report, evaluations for equivalent dose rate of each device and exposure dose of handling operators when all fission products released in the coolant of the capsule control device and the BOCA at fuel failure in the fuel transient test are summarized.

JAEA Reports

Dose evaluation of external exposure by direct and skyshine gamma rays of nuclear fuel handling facilities at JMTR

Ogawa, Mitsuhiro; Iimura, Koichi; Tomita, Kenji; Tobita, Masahiro

JAEA-Technology 2009-017, 254 Pages, 2009/05

JAEA-Technology-2009-017.pdf:15.04MB

In JMTR, upgrade of irradiation facilities is advanced to re-operate from 2011 F.Y. In order to irradiate test fuels of high-burnup, external exposure reassessment by direct and skyshine gamma rays of the nuclear fuel handling facility at JMTR was performed. In evaluation method, radiation source of maximum use of the nuclear fuel was calculated by using ORIGEN2 code. Dose equivalent rate for supervised area boundary was calculated by modeling reactor building at using shielding calculation codes QAD-CGGP2 and G33-GP2. As a result of evaluation, it was confirmed that the effective dose equivalent during year was low enough at supervised area boundary of the JMTR site.

Oral presentation

Creating a database of irradiation facilities troubles

Ogawa, Mitsuhiro; Hosokawa, Jinsaku; Tomita, Kenji; Iimura, Koichi; Sakuta, Yoshiyuki

no journal, , 

no abstracts in English

Oral presentation

Measuring of capping phenomena in powder compaction process using X-ray computed tomography

Suzuki, Michitaka*; Tanaka, Yutaka*; Iimura, Kenji*; Satone, Hiroshi*; Ishii, Katsunori

no journal, , 

The capping phenomenon is one of the important causes of the powder molding trouble. The research of the capping such as how to occur and what kind of condition related to the phenomena is not cleared still now. The packing particles for our tests were 20-150um spherical Alumina granules and the sieved narrow sized granules were also used. The compression tests were performed by a material-tester. The capping region could be detected from X-ray computed tomographic images and the depth of capping area was measured. It's clear that the capping phenomena are easy to occur at small compression displacement in the case of wider size distributed granules 20-150um. It comes from the higher adhesion force between fine powder and the piston or the mold surface. The depth of capping is decreasing with the increase in displacement. In the conclusion, the capping phenomena can be prevented to use coarser mono-sized granules for compression molding.

Oral presentation

Evaluation of the effects of granulated alumina powder characteristics and die wall lubricant on compaction behavior using X-ray computed tomography

Segawa, Tomoomi; Kawaguchi, Koichi; Ishii, Katsunori; Nishina, Masahiro; Makino, Takayoshi; Iimura, Kenji*; Satone, Hiroshi*; Suzuki, Michitaka*; Natori, Yuri*

no journal, , 

Japan Atomic Energy Agency has developed a simplified pelletizing fuel fabrication system. In this system, the flowability of a MOX raw powder is improved by wet granulation for the pelletizing process, and the die wall lubrication method directly presses the granulated MOX powder into green pellets without adding any lubricant into the powder. The homogeneous compression is important to fabricate high-density green pellets. However, it is difficult to observe the compaction behavior in situ. Therefore, the capping phenomenon was investigated by using X-ray computed tomography and alumina powder that is highly transparent against X-rays. When lubricant was used, the breakage of the particles extended to the bottom compared with not used. This result indicates that the die wall lubrication is effective for the homogeneous compression of granulated powders.

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