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論文

エネルギーロスの小さなPd$$_{2}$$MnGaメタ磁性形状記憶合金の開発

伊東 達矢; Xu, X.*; 大森 俊洋*; 貝沼 亮介*

物性研だより, 63(3), p.8 - 10, 2023/10

メタ磁性形状記憶合金は磁場により駆動することが出来る形状記憶合金であり、センサーやアクチュエーター等での応用が期待されている。しかし、これまでに開発されてきた合金系ではマルテンサイト変態に伴うエネルギーロスが大きいという問題点があった。近年、我々の研究グループではPd$$_2$$MnGa合金において初めて相変態によるエネルギーロスの小さなメタ磁性形状記憶合金を発見した。本稿ではその内容を紹介する。

論文

Tough yet flexible superelastic alloys meet biomedical needs

Xu, X.*; 大平 拓実*; Xu, S.*; 平田 研二*; 大森 俊洋*; 植木 洸輔*; 上田 恭介*; 成島 尚之*; 長迫 実*; 貝沼 亮介*; et al.

Advanced Materials & Processes, 180(7), p.35 - 37, 2022/10

Metallic biomaterials are widely used to replace or support failing hard tissues due to excellent mechanical properties and high wear resistance, with demand increasing as the global population continues to age. It is widely accepted that successful metallic biomaterials should have good biocompatibility, high corrosion resistance, and strong wear resistance. In addition, a low Young's modulus similar to human bone is now recognized as another important factor, in order to avoid bone atrophy due to the stress shielding effect. While the Young's modulus of stainless steels and conventional fcc CoCr alloys is as high as 190-240 GPa, for $$beta$$-type Ti-base alloys it is generally in the range of 50-80 GPa. Young's modulus values are as low as 35 GPa for Ti-Nb-Ta-Zr, close to that of human bone at approximately 10-30 GPa. However, Ti-base alloys come with the compromise of low wear resistance. In fact, alloys that feature a low Young's modulus along with high wear resistance have been difficult to realize. This article explores the recently developed bcc CoCr-base alloy Co-Cr-Al-Si as a potential solution to these issues, i.e., the difficulty in combining a low Young's modulus with high wear resistance, and the challenge of realizing large superelastic strains.

論文

Non-Hookean large elastic deformation in bulk crystalline metals

Xu, S.*; 大平 拓実*; 佐藤 駿介*; Xu, X.*; 大森 俊洋*; Harjo, S.; 川崎 卓郎; Seiner, H.*; Zoubkov$'a$, K.*; 村上 恭和*; et al.

Nature Communications (Internet), 13, p.5307_1 - 5307_8, 2022/09

 被引用回数:3 パーセンタイル:68.76(Multidisciplinary Sciences)

Crystalline metals can have large theoretical elastic strain limits. However, a macroscopic block of conventional crystalline metals practically suffers a very limited elastic deformation of $$<$$0.5% with a linear stress-strain relationship obeying Hooke's law. Here, we report on the experimental observation of a large tensile elastic deformation with an elastic strain of $$>$$4.3% in a Cu-based single crystalline alloy at its bulk scale at room temperature. The large macroscopic elastic strain that originates from the reversible lattice strain of a single phase is demonstrated by in situ microstructure and neutron diffraction observations. Furthermore, the elastic reversible deformation, which is nonhysteretic and quasilinear, is associated with a pronounced elastic softening phenomenon. The increase in the stress gives rise to a reduced Young's modulus, unlike the traditional Hooke's law behaviour. The experimental discovery of a non-Hookean large elastic deformation offers the potential for the development of bulk crystalline metals as high-performance mechanical springs or for new applications via "elastic strain engineering."

論文

Flexible and tough superelastic Co-Cr alloys for biomedical applications

大平 拓実*; Xu, S.*; 平田 研二*; Xu, X.*; 大森 俊洋*; 植木 洸輔*; 上田 恭介*; 成島 尚之*; 長迫 実*; Harjo, S.; et al.

Advanced Materials, 34(27), p.2202305_1 - 2202305_11, 2022/07

 被引用回数:3 パーセンタイル:85.34(Chemistry, Multidisciplinary)

The demand for biomaterials has been increasing along with the increase in the population of elderly people worldwide. The mechanical properties and high wear resistance of metallic biomaterials makes them well-suited for use as substitutes or as support for damaged hard tissues. However, unless these biomaterials also have a low Young's modulus similar to that of human bones, bone atrophy inevitably occurs. Because a low Young's modulus is typically associated with poor wear resistance, it is difficult to realize a low Young's modulus and high wear resistance simultaneously. Also, the superelastic property of shape memory alloys makes them suitable for biomedical applications, like vascular stents and guide wires. However, due to the low recoverable strain of conventional biocompatible shape memory alloys, the demand for a new alloy system is high. The novel body-center-cubic cobalt-chromium-based alloys in this paper provide a solution to both of these problems. We believe our novel alloys are promising candidates for biomedical applications.

論文

Phase equilibria in the Be-V and Be-Ti binary systems

大沼 郁雄*; 貝沼 亮介*; 宇田 実*; 岩立 孝治*; 内田 宗範*; 河村 弘; 石田 清仁*

JAERI-Conf 2004-006, p.172 - 183, 2004/03

先進中性子増倍材料として期待されているベリリウム金属間化合物について、特にBe-Ti, Be-Vの2元系状態図について研究した。中性子増倍材料として実用可能な高Be側(Be-5$$sim$$23at%Ti,Be-5$$sim$$25at%V)の試料をアーク溶解法で作成し、1200$$sim$$1450$$^{circ}$$Cにて熱処理したものについて、電子プローブマイクロアナライザ(EPMA)を用いて生成する相を詳細に固定した。その結果、今まで不明であった特にBe-rich側での同系の状態図を明らかにした。

口頭

Mn-Zn二元系状態図の全組成域における実験的決定

今富 大介*; 石川 遼典*; 仲田 玲*; 伊東 達矢; Han, K.*; 長迫 実*; Xu, X.*; 大森 俊洋*; 貝沼 亮介*

no journal, , 

高Mn鋼への亜鉛めっき処理において界面反応の理解のためにFe-Mn-Zn状態図の決定が必要不可欠である。そこで本研究ではまず基本となるMn-Zn二元系状態図について決定した。

口頭

その場中性子回折によるCo-Cr-Al-Si超弾性合金におけるマルテンサイト変態過剰応力の調査

清水 来紀*; Xu, X.*; 伊東 達矢; Gong, W.; Harjo, S.; 大森 俊洋*; 貝沼 亮介*

no journal, , 

Co-Cr-Al-Si合金は約15%程度の超弾性回復ひずみを有するが、応力誘起マルテンサイト変態開始時の過剰な応力$$sigma^{mathrm{Extra}}$$が超弾性疲労特性を劣化させる可能性がある。本研究では中性子回折により$$sigma^{mathrm{Extra}}$$の起源を調査する。

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