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Journal Articles

Study on optimizing microwave heating denitration method and powder characteristics of uranium trioxide

Segawa, Tomoomi; Kawaguchi, Koichi; Kato, Yoshiyuki; Ishii, Katsunori; Suzuki, Masahiro; Fujita, Shunya*; Kobayashi, Shohei*; Abe, Yutaka*; Kaneko, Akiko*; Yuasa, Tomohisa*

Proceedings of 2019 International Congress on Advances in Nuclear Power Plants (ICAPP 2019) (Internet), 9 Pages, 2019/05

A solution of plutonium nitrate and uranyl nitrate is converted into a mixed oxide by microwave heating denitration method. In the present study, for improving the efficiency of microwave heating and achieving high-temperature uniformity to produce homogeneous UO$$_{3}$$ powder, the microwave heating test of potassium chloride and uranyl nitrate solution, and numerical simulation analysis were conducted. The potassium chloride agar was adjusted to the dielectric loss, which is close to that of the uranyl nitrate solution and the optimum support table height was estimated to be 50 mm for denitration of the uranyl nitrate solution by microwave heating. The adiabator improved the efficiency of microwave heating denitration. Moreover, the powder yield was improved by using the adiabator owing to ease of scraping of the denitration product from the bottom of the denitration vessel.

Journal Articles

Mechanism of flashing phenomena by microwave heating and influence of high dielectric constant solution

Fujita, Shunya*; Abe, Yutaka*; Kaneko, Akiko*; Yuasa, Tomohisa*; Segawa, Tomoomi; Kato, Yoshiyuki; Kawaguchi, Koichi; Ishii, Katsunori

Proceedings of 11th Korea-Japan Symposium on Nuclear Thermal Hydraulics and Safety (NTHAS-11) (Internet), 7 Pages, 2018/11

Mixed uranium oxide and plutonium oxide powder is produced from uranyl nitrate and plutonium nitrate mixed solution by the microwave heating denitration method in the spent fuel reprocessing process. Since the microwave heating method is accompanied by a boiling phenomenon, it is necessary to fully grasp the operating conditions in order to avoid flashing and spilling in the mass production of denitrification technology for the future. In this research, it was clarified that the heat transfer coefficient became lower as the dielectric constant increased. The dominant factor of the blowing up phenomena is supposed to be generation of the innumerable bubble rather than bubble's growth.

Journal Articles

Mechanism of flashing phenomena induced by microwave heating

Fujita, Shunya*; Abe, Yutaka*; Kaneko, Akiko*; Yuasa, Tomohisa*; Segawa, Tomoomi; Yamada, Yoshikazu; Kato, Yoshiyuki; Ishii, Katsunori

Proceedings of 26th International Conference on Nuclear Engineering (ICONE-26) (Internet), 8 Pages, 2018/07

Mixed uranium oxide and plutonium oxide powder is produced from uranyl nitrate and plutonium nitrate mixed solution by the microwave heating denitration method in the spent fuel reprocessing process. Since the microwave heating method is accompanied by a boiling phenomenon, it is necessary to fully grasp the operating conditions in order to avoid flashing and spilling in the mass production of denitrification technology for the future. In this research, it was confirmed that a potassium chloride aqueous solution as a simulant of uranyl nitrate aqueous solution with high dielectric loss cause loss of microwave at the solution surface as the dielectric loss increased with the increase of KCl concentration by experimental and electromagnetic field analysis, and revealed that the change in the heating condition affects the generation of flushing.

JAEA Reports

Procedures of chemical analysis of radioactive waste for decommissioning of TEPCO'S Fukushima Daiichi Nuclear Power Station

Yonekawa, Minoru; Iwasaki, Maho; Shimada, Kozue; Yanagiya, Shoko; Tsukada, Manabu; Iizuka, Yoshiyuki; Kaneko, Munenori; Unno, Toshimichi

JAEA-Testing 2015-002, 151 Pages, 2016/03

JAEA-Testing-2015-002.pdf:4.29MB
JAEA-Testing-2015-002-appendix(CD-ROM).zip:5.7MB

Preparatory Office for Hot Laboratory Operation Management in Fukushima Research Infrastructural Creation Center has advanced research and development for decommissioning of TEPCO'S Fukushima Daiichi Nuclear Power Station. For this purpose, work procedure manual of chemical analysis for safety evaluation on processing, disposal and management of radioactive waste such as low dose level rubbles and fuel debris has been prepared. The manual will be used for personnel training and animation function of PowerPoint was used as the beginner of the chemical analysis to understand easily. This report describes about nuclides which were established analysis method and completed to make animation of work procedure.

Journal Articles

The H-Invitational Database (H-InvDB); A Comprehensive annotation resource for human genes and transcripts

Yamasaki, Chisato*; Murakami, Katsuhiko*; Fujii, Yasuyuki*; Sato, Yoshiharu*; Harada, Erimi*; Takeda, Junichi*; Taniya, Takayuki*; Sakate, Ryuichi*; Kikugawa, Shingo*; Shimada, Makoto*; et al.

Nucleic Acids Research, 36(Database), p.D793 - D799, 2008/01

 Times Cited Count:52 Percentile:71.15(Biochemistry & Molecular Biology)

Here we report the new features and improvements in our latest release of the H-Invitational Database, a comprehensive annotation resource for human genes and transcripts. H-InvDB, originally developed as an integrated database of the human transcriptome based on extensive annotation of large sets of fulllength cDNA (FLcDNA) clones, now provides annotation for 120 558 human mRNAs extracted from the International Nucleotide Sequence Databases (INSD), in addition to 54 978 human FLcDNAs, in the latest release H-InvDB. We mapped those human transcripts onto the human genome sequences (NCBI build 36.1) and determined 34 699 human gene clusters, which could define 34 057 protein-coding and 642 non-protein-coding loci; 858 transcribed loci overlapped with predicted pseudogenes.

Journal Articles

The preliminary edition of nuclear criticality safety handbook of Japan, 4; Development of a computer code for analysing nuclear criticality safety on array system

Kaneko, Yoshiyuki*; Naito, Yoshitaka

Proc.Int.Seminar on Nuclear Criticality Safety, p.150 - 155, 1987/00

no abstracts in English

Oral presentation

Effect of mixed phosphate corrosion inhibitor on corrosion of PCV steel in diluted sea water

Fujii, Kazumi*; Iwanami, Masaru*; Ishioka, Shinichi*; Kaneko, Tetsuji*; Tanaka, Norihiko*; Kawaharada, Yoshiyuki*; Yokoyama, Yutaka*; Umehara, Ryuji*; Kato, Chiaki; Ueno, Fumiyoshi; et al.

no journal, , 

no abstracts in English

Oral presentation

Effect of tungstate inhibitor and molybdate-containing mixed phosphate-based inhibitor on corrosion of PCV steel in diluted sea water

Kaneko, Tetsuji*; Tanaka, Norihiko*; Kawaharada, Yoshiyuki*; Fujii, Kazumi*; Iwanami, Masaru*; Ishioka, Shinichi*; Yokoyama, Yutaka*; Umehara, Ryuji*; Kato, Chiaki; Ueno, Fumiyoshi; et al.

no journal, , 

no abstracts in English

Oral presentation

Effect of $$gamma$$-ray irradiation on inhibition of steel corrosion in diluted sea water

Sato, Tomonori; Kato, Chiaki; Motooka, Takafumi; Ueno, Fumiyoshi; Nakano, Junichi; Kaneko, Tetsuji*; Tanaka, Norihiko*; Kawaharada, Yoshiyuki*; Fujii, Kazumi*; Iwanami, Masaru*; et al.

no journal, , 

no abstracts in English

Oral presentation

Corrosion behavior of reactor core spray pipe steel in flowing water, 2

Yokoyama, Yutaka*; Umehara, Ryuji*; Tanaka, Norihiko*; Kawaharada, Yoshiyuki*; Kaneko, Tetsuji*; Fujii, Kazumi*; Iwanami, Masaru*; Ishioka, Shinichi*; Kato, Chiaki; Ueno, Fumiyoshi; et al.

no journal, , 

no abstracts in English

Oral presentation

Effect of tungstate inhibitor and molybdate-containing mixed phosphate-based inhibitor on corrosion of PCV steel in diluted sea water, 2

Kaneko, Tetsuji*; Tanaka, Norihiko*; Kawaharada, Yoshiyuki*; Fujii, Kazumi*; Iwanami, Masaru*; Ishioka, Shinichi*; Yokoyama, Yutaka*; Umehara, Ryuji*; Kato, Chiaki; Ueno, Fumiyoshi; et al.

no journal, , 

no abstracts in English

Oral presentation

Effect of mixed phosphate corrosion inhibitor on corrosion of PCV steel in diluted sea water, 2

Fujii, Kazumi*; Iwanami, Masaru*; Ishioka, Shinichi*; Kaneko, Tetsuji*; Tanaka, Norihiko*; Kawaharada, Yoshiyuki*; Yokoyama, Yutaka*; Umehara, Ryuji*; Kato, Chiaki; Ueno, Fumiyoshi; et al.

no journal, , 

no abstracts in English

Oral presentation

Effect of later added inhibitors of the steel corrosion in the diluted artificial seawater under $$gamma$$-ray irradiation

Kato, Chiaki; Sato, Tomonori; Ueno, Fumiyoshi; Kaneko, Tetsuji*; Tanaka, Norihiko*; Kawaharada, Yoshiyuki*; Fujii, Kazumi*; Iwanami, Masaru*; Ishioka, Shinichi*; Yokoyama, Yutaka*; et al.

no journal, , 

no abstracts in English

Oral presentation

Evaluation of effect of corrosion inhibitors on reactor core spray pipe steel in flowing diluted sea water

Yokoyama, Yutaka*; Umehara, Ryuji*; Kaneko, Tetsuji*; Tanaka, Norihiko*; Kawaharada, Yoshiyuki*; Fujii, Kazumi*; Iwanami, Masaru*; Ishioka, Shinichi*; Kato, Chiaki; Ueno, Fumiyoshi; et al.

no journal, , 

no abstracts in English

Oral presentation

Heating characteristics of high dielectric solution by microwave heating

Fujita, Shunya*; Abe, Yutaka*; Kaneko, Akiko*; Yuasa, Tomohisa*; Segawa, Tomoomi; Kato, Yoshiyuki; Yamada, Yoshikazu

no journal, , 

A mixed solution of uranyl nitrate and plutonium nitrate is converted to MOX raw powder by the microwave heating de-nitration method in nuclear fuel reprocessing. Since the microwave heating causes a boiling phenomenon, it is necessary to sufficiently confirm operating conditions to prevent flushing and overflow phenomena of solution, and it is necessary to evaluate the influence of the dielectric property of the object on the microwave heating characteristics and to optimize the equipment and operating conditions. In this study, the visualization observation using a potassium chloride aqueous solution and agar as a high dielectric constant solution and evaluation of a heating portion, and the electromagnetic field analysis are performed for the purpose of evaluating the influence of the dielectric constant of the material and the installation position on microwave heating characteristics.

Oral presentation

Mechanism of flashing phenomena in microwave heating

Fujita, Shunya*; Abe, Yutaka*; Kaneko, Akiko*; Yuasa, Tomohisa*; Segawa, Tomoomi; Yamada, Yoshikazu; Kato, Yoshiyuki; Ishii, Katsunori

no journal, , 

Mixed uranium oxide and plutonium oxide (MOX) powder is produced from uranyl nitrate and plutonium nitrate mixed solution by the microwave heating denitration method in the spent fuel reprocessing process. Since the MH method is accompanied by a boiling phenomenon, it is necessary to fully grasp the operating conditions in order to avoid flashing and spilling in the mass production of denitrification technology for the future. In this research, for the purpose of clarifying the mechanism of flashing phenomenon during microwave heating, the generation mechanism of bubbles that innumerably occur at the time of flashing is considered. When the contact angle at the heterogeneous nucleation of bubbles was 177 $$^{circ}$$C, the theoretical value of the heterogeneous nucleation approximately agreed with the experimental value at the time the superheat degree was found to be close to 35 $$^{circ}$$C.

Oral presentation

Mechanism of flashing induced by microwave heating

Fujita, Shunya*; Abe, Yutaka*; Kaneko, Akiko*; Yuasa, Tomohisa*; Segawa, Tomoomi; Kato, Yoshiyuki; Kawaguchi, Koichi; Ishii, Katsunori

no journal, , 

The microwave heating denitration method is used in the spent fuel reprocessing process of the nuclear fuel cycle. Since the microwave heating method is accompanied by a transient boiling phenomenon, it is necessary to grasp the operating conditions and to clarify the mechanism of flashing and spilling in order to avoid it. In this study, by assuming the flashing model for the purpose of the clarification of the flashing mechanism by microwave heating, the flashing mechanism of instantaneous generation and growth is considered by calculating the generation frequency and volume of bubble from the visualization result at flushing. The mechanism of flashing phenomenon during microwave heating is thought that the significant flushing phenomenon occurs by the process that a large amount of nanobubbles are generated at a solid-fluid interface in a overheated liquid phase, the bubble group grows exponentially and collapses, and its internal pressure releases.

Oral presentation

Effect of permittivity on microwave heating characteristics

Kobayashi, Shohei*; Fujita, Shunya*; Abe, Yutaka*; Kaneko, Akiko*; Yuasa, Tomohisa*; Segawa, Tomoomi; Kato, Yoshiyuki; Kawaguchi, Koichi; Ishii, Katsunori

no journal, , 

The microwave heating denitration method is used in the spent fuel reprocessing process. In order to develop the mass production of denitrification technology for the future, it is necessary to fully grasp the operating conditions to avoid flashing and overflow phenomena of solution. In this research, the conditions of the generation of flashing are evaluated using the potassium chloride aqueous solution as the simulated solution, and the concentration of potassium chloride and the microwave output as parameters. It is found that it is difficult to occur the flashing phenomenon as the concentration of potassium chloride increases.

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