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岩瀬 裕希*; 河合 里紗*; 守島 健*; 高田 慎一; 吉村 倫一*; 柴山 充弘*
Journal of Colloid and Interface Science, 538, p.357 - 366, 2019/03
被引用回数:13 パーセンタイル:41.52(Chemistry, Physical)We found that the wormlike micelles were oriented in the direction of the flow due to elongation and that changes to the precursor of the wormlike micelles did not affect the shear thickening. As a precursor structural change of shear thinning, the wormlike micelles elongated while maintaining their orientation. We found that an increase in the molecular curvature of the 12-2-12 due to the introduction of a spacer-group contributed to the unusual rheological behaviors of the wormlike micelles in a solution under shear flow.
成澤 雅紀*; 江夏 昌志; 武山 昭憲; 杉本 雅樹; 出崎 亮; 佐藤 隆博; 外薗 洋樹*; 河相 武利*; 岩瀬 彰宏*
Journal of the Ceramic Society of Japan, 123(9), p.805 - 808, 2015/09
Two kinds of Si-O-C(-H) ceramics particles having intrinsic photoluminescence (PL) spectra were prepared from silicone resin microspheres by heat treatment in a hydrogen atmosphere at 800 or 1100C. The obtained particles were painted on a Si substrate using a binder, and ion-beam-luminescence spectra were observed under proton beam irradiation with an acceleration energy in the ranges of 1-3 MeV. Observed spectra had peaks at wavelength of 520-540 nm. These peak wavelengths were larger than those observed under UV light irradiation. The luminescence of H 1100 (sample decarbonized at 1100C) was bright, and that of H 800 (sample decarbonized at 800C) was faint. However, the intensity of luminescence decreased rapidly at an early stage of the beam irradiation. In air, a sharp luminescence band with a peak at 300 nm appeared together with the main emission with a peak in the range of 520-540 nm. The existence of the sharp band at 300 nm was apparent in the H 800 spectra, whereas it appeared as a minor peak in the H 1100 spectra in air.