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Journal Articles

H$$_{2}$$ production from methane decomposition by fullerene at low temperature

Tokunaga, Tomoharu*; Kuno, Kohei*; Kawakami, Takumi*; Yamamoto, Takahisa*; Yoshigoe, Akitaka

International Journal of Hydrogen Energy, 45(28), p.14347 - 14353, 2020/05

 Times Cited Count:2 Percentile:6.57(Chemistry, Physical)

To understand the catalytic behavior of graphite and carbon black with mainly 6-membered rings with sp$$^{2}$$ bonds for H$$_{2}$$ production by CH$$_{4}$$ decomposition, fullerenes with 6-membered rings and also those comprising 5- and 7-membered rings with sp$$^{2}$$ bonds was investigated using gas chromatography, XPS and TEM analysis. From these analysis, it is anticipated that the ring structures without 6-membered rings in carbon materials with sp$$^{2}$$ bonding contribute to the catalytic behavior for CH$$_{4}$$ decomposition at a low temperature of 400$$^{circ}$$C.

Journal Articles

Status and perspective of the Nb$$_{3}$$Al development

Takeuchi, Takao*; Kikuchi, Akihiro*; Banno, Nobuya*; Kitaguchi, Hitoshi*; Iijima, Yasuo*; Tagawa, Kohei*; Nakagawa, Kazuhiko*; Tsuchiya, Kiyosumi*; Mitsuda, Shiori*; Koizumi, Norikiyo; et al.

Cryogenics, 48(7-8), p.371 - 380, 2008/07

 Times Cited Count:62 Percentile:87.94(Thermodynamics)

Nb$$_{3}$$Al has advantages of better tolerance to strain/stress and a higher critical magnetic field (30 T at 4.2 K) for stoichiometric composition over Nb$$_{3}$$Sn. The rapid-heating, quenching and transformation annealing (RHQT) process enables to form a stoichiometric Nb$$_{3}$$Al with fine grain structures via metastable bcc supersaturated-solid-solution. As a result a large critical current density of Nb$$_{3}$$Al is achieved over the whole range of magnetic fields without trading off the excellent strain tolerance. A long-length of RHQ processing has been established, and a rectangular but Cu stabilized Nb$$_{3}$$Al strand is about be commercially available for NMR uses. Ag or Cu internal stabilization and Cu ion-plating/electroplating techniques have been also developed to enable the stabilized round wire for accelerator and fusion magnets. Successfully energized test coils that were manufactured with a wind-and-react technique have demonstrated that a long piece of Cu stabilized RHQT Nb$$_{3}$$Al wire is really available for practical applications.

JAEA Reports

Design study on H.L.W. geologic repository, IV; for 1984

Ara, Hiroshige*; Fukumitsu, Kenji*; Iizuka, Yunosuke*; Ishii, Takashi*; Izumiya, Yasushi*; Imazu, Masanori*; Utsugida, Yoshizo*; Hasegawa, Makoto*; Maeda, Masaya*; Yabe, Yukio*; et al.

PNC TJ199 84-04VOL1, 20 Pages, 1984/03

PNC-TJ199-84-04VOL1.pdf:0.88MB

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