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論文

Direct measurement of nanoscale lithium diffusion in solid battery materials using radioactive tracer of $$^{8}$$Li

石山 博恒*; Jeong, S.-C.*; 渡辺 裕*; 平山 賀一*; 今井 伸明*; Jung, H. S.*; 宮武 宇也*; 小柳津 充広*; 長 明彦; 乙川 義憲; et al.

Nuclear Instruments and Methods in Physics Research B, 376, p.379 - 381, 2016/06

https://doi.org/10.1016/j.nimb.2015.12.036
 被引用回数：8 パーセンタイル：56.75(Instruments & Instrumentation)

We have developed an in situ and nanoscale Li diffusion measurement method in Li battery materials using an $$alpha$$-emitting radioactive $$^{8}$$Li tracer. In this method, while implanting a low-energy (8 keV) $$^{8}$$Li beam, the $$alpha$$ particles emitted at a small angle (10$$^{circ}$$) relative to the sample surface were detected as a function of time. Measurement for Li diffusion coefficients in a spinel phase LiMn$$_4$$O$$_4$$ (LMO) thin film has been started, which is used as an electrode in a Li ion secondary battery. An obvious Li diffusion effect in LMO was observed at the sample temperature of 623 K, and the further measurement is underway.

論文

Nanoscale diffusion tracing by radioactive $$^{8}$$Li tracer

石山 博恒*; Jeong, S.-C.*; 渡辺 裕*; 平山 賀一*; 今井 伸明*; 宮武 宇也*; 小柳津 充広*; 片山 一郎*; 長 明彦; 乙川 義憲; et al.

Japanese Journal of Applied Physics, 53(11), p.110303_1 - 110303_4, 2014/11

https://doi.org/10.7567/JJAP.53.110303
 被引用回数：5 パーセンタイル：21.38(Physics, Applied)

We have developed a nanoscale diffusion measurement method using an $$alpha$$-emitting radioactive $$^{8}$$Li tracer. In this method, while implanting a pulsed 8 keV $$^{8}$$Li beam, the $$alpha$$ particles emitted at a small angle (10$$^{circ}$$) relative to the sample surface were detected as a function of time. The method has been successfully applied to measuring lithium diffusion coefficients for an amorphous Li$$_{4}$$SiO$$_{4}$$-Li$$_{3}$$VO$$_{4}$$ (LVSO) thin film with a thickness of several hundred nanometers, demonstrating that the present method is sensitive to diffusion coefficients down on the order of 10$$^{-12}$$cm$$^{2}$$/s, which is more sensitive by about two orders of magnitude than that previously achieved.

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