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Journal Articles

Enhancement of electrical conductivity to metallization of Mn$$_{3-x}$$Fe$$_x$$O$$_4$$ spinel and postspinel with elevating pressure

Yamanaka, Takamitsu*; Rahman, S.*; Nakamoto, Yuki*; Hattori, Takanori; Jang, B. G.*; Kim, D. Y.*; Mao, H.-K.*

Journal of Physics and Chemistry of Solids, 167, p.110721_1 - 110721_10, 2022/08

High-pressure neutron diffraction proved that MnFe$$_2$$O$$_4$$ and Mn$$_2$$FeO$$_4$$ spinels transform into CaMn$$_2$$O$$_4$$-type structure above 18 GPa and 14 GPa, respectively. The transition pressure of Mn$$_{3-x}$$Fe$$_x$$O$$_4$$ solutions decreases with increasing Mn content. Synchrotron X-ray M$"{o}$ssbauer experiments revealed that Fe$$^{2+}$$ and Fe$$^{3+}$$ distribution at the tetrahedral (A) and octahedral (B) sites in the spinel structure changes with pressure. MnFe$$_2$$O$$_4$$ and Mn$$_2$$FeO$$_4$$ spinels are ferrimagnetic and the CaMn$$_2$$O$$_4$$-type phase is paramagnetic. The temperature dependence of resistivity indicates that both spinels are semiconductors wherein electrons hop between cations at the A and B sites. A pressure-induced shortening of B-B distance promoted conduction via greater electron mobility between adjacent B cations. The Fe$$^{2+}$$ and Fe$$^{3+}$$ occupancies at the B sites in MnFe$$_2$$O$$_4$$ are much larger than those in Mn$$_2$$FeO$$_4$$. The CaMn$$_2$$O$$_4$$-type phase is metallic. Theoretical calculation confirmed the metallic character and Fe d-orbitals strongly renormalized compared to Mn d-orbitals.

Journal Articles

Fe, Mn and $$^{238}$$U accumulations in ${it Phragmites australis}$ naturally growing at the mill tailings pond; Iron plaque formation possibly related to root-endophytic bacteria producing siderophores

Nakamoto, Yukihiro*; Doyama, Kohei*; Haruma, Toshikatsu*; Lu, X.*; Tanaka, Kazuya; Kozai, Naofumi; Fukuyama, Kenjin; Fukushima, Shigeru; Ohara, Yoshiyuki; Yamaji, Keiko*

Minerals (Internet), 11(12), p.1337_1 - 1337_17, 2021/12

Mine drainage is a vital water problem in the mining industry worldwide because of the heavy metal elements and low pH. Rhizofiltration using wetland plants is an appropriate method to remove heavy metals from the water via accumulation in the rhizosphere. ${it Phragmites australis}$ is one of the candidate plants for this method because of metal accumulation, forming iron plaque around the roots. At the study site, which was the mill tailings pond in the Ningyo-toge uranium mine, ${it P. australis}$ has been naturally growing since 1998. The results showed that ${it P. australis}$ accumulated Fe, Mn, and $$^{238}$$U in the nodal roots without/with iron plaque compared with other plant tissues. Among the 837 bacterial colonies isolated from nodal roots, 88.6% showed siderophore production activities. Considering iron plaque formation around ${it P. australis}$ roots, we hypothesized that microbial siderophores might influence iron plaque formation because bacterial siderophores have catechol-like functional groups. The complex of catechol or other phenolics with Fe was precipitated due to the networks between Fe and phenolic derivatives. The experiment using bacterial products of root endophytes, such as ${it Pseudomonas}$ spp. and ${it Rhizobium}$ spp., showed precipitation with Fe ions, and we confirmed that several ${it Ps.}$ spp. and ${it R.}$ spp. produced unidentified phenolic compounds. In conclusion, root-endophytic bacteria such as ${it Pseudomonas}$ spp. and ${it R.}$ spp., isolated from metal-accumulating roots of ${it P. australis}$, might influence iron plaque formation as the metal accumulation site. Iron plaque formation is related to tolerance in ${it P. australis}$, and ${it Ps.}$ spp. and ${it R.}$ spp. might indirectly contribute to tolerance.

Journal Articles

Neutron diffraction study on martensitic transformation under compressive stress in an ordered Fe$$_{3}$$Pt

Fukuda, Takashi*; Yamaguchi, Takashi*; Kakeshita, Tomoyuki*; Harjo, S.; Nakamoto, Tatsushi*

Journal of Applied Physics, 126(2), p.025107_1 - 025107_6, 2019/07

AA2019-0505.pdf:1.15MB

 Times Cited Count:1 Percentile:10.83(Physics, Applied)

Journal Articles

Ultrasonic guided wave approach for inspecting concave surface of the laser butt-welded pipe

Furusawa, Akinori; Nishimura, Akihiko; Takebe, Toshihiko*; Nakamura, Masaki*; Takenaka, Yusuke*; Saijo, Shingo*; Nakamoto, Hiroyuki*

E-Journal of Advanced Maintenance (Internet), 9(2), p.44 - 51, 2017/08

The aim of this work is to investigate the applicability of ultrasonic guided wave for evaluation of laser beam butt-welding quality. Ten in total test pipes having welding seam is prepared. Two piece of pipe are jointed and continuous laser beam is irradiated on the edges, varying laser irradiation power, welding side and surface profile of the adjacent edges of the pipe. Ultrasonic guided wave testing experiment is performed on the pipes. Torsional mode guided wave is excited by EMAT. The experimental results are analyzed and issues are discussed. The reflection wave bullet from the poor interface of the welding seam is clearly observed, whereas no reflection from fine welded line. From the aspect of laser irradiation power, welding side and surface profile of the adjacent edges, the relation between the interface condition and detection wave bullet are analyzed. It is found that the ultrasonic guided wave technologies have the potential for evaluating laser beam butt-welding seam.

Journal Articles

Model magnet development of D1 beam separation dipole for the HL-LHC upgrade

Nakamoto, Tatsushi*; Sugano, Michinaka*; Xu, Q.*; Kawamata, Hiroshi*; Enomoto, Shun*; Higashi, Norio*; Idesaki, Akira; Iio, Masami*; Ikemoto, Yukio*; Iwasaki, Ruri*; et al.

IEEE Transactions on Applied Superconductivity, 25(3), p.4000505_1 - 4000505_5, 2015/06

 Times Cited Count:0 Percentile:0(Engineering, Electrical & Electronic)

Recently, development of superconducting magnet system with high radiation resistance has been demanded for application in accelerator facilities such as CERN LHC. In order to realize superconducting magnet system with high radiation resistance, it is necessary to develop electrical insulator with high radiation resistance because the electrical insulator is made of organic materials whose radiation resistance is inferior to that of inorganic materials. We developed a glass fiber reinforced plastic with bismaleimide-triazine resin. The developed material showed excellent radiation resistance; the material evolved gases of 5$$times$$10 $$^{-5}$$mol/g and maintained flexural strength of 640MPa (90% of initial value).

Journal Articles

Development of ITER CODAC compatible gyrotron local control system and its operation

Oda, Yasuhisa; Oshima, Katsumi; Nakamoto, Takashi*; Hashimoto, Yasunori*; Yamamoto, Tsuyoshi; Hayashi, Kazuo*; Ikeda, Yukiharu; Ikeda, Ryosuke; Kajiwara, Ken; Takahashi, Koji; et al.

Purazuma, Kaku Yugo Gakkai-Shi, 90(7), p.365 - 373, 2014/07

no abstracts in English

Journal Articles

Electrical and structural properties of YH$$_{x}$$(${it x}$ $$sim$$3) under high pressure

Matsuoka, Takehiro*; Kitayama, Takayasu*; Shimizu, Katsuya*; Nakamoto, Yuki*; Kagayama, Tomoko*; Aoki, Katsutoshi; Oishi, Yasuo*; Takemura, Kenichi*

High Pressure Research, 26(4), p.391 - 394, 2006/12

 Times Cited Count:1 Percentile:11.54(Physics, Multidisciplinary)

The electrical and structural properties of yttrium hydride YHx was studied by the in-situ measurements of the electrical resistance and X-ray diffraction up to 86 GPa. The electrical resistivity increased with applying pressure up to 10 GPa and showed a maximum which accompanied with the structural transition of metal lattice from hcp to fcc structure. In fcc phase the resistivity decreased significantly, however the value still remained larger by 4 orders of magnitude that that of pure yttrium metal. We could not confirm the insulator to metal transition up to 23 GPa. The resistivity showed another maximum in the large pressure region 40 $$sim$$ 60 GPa without the structural phase transition of metal lattice.

Journal Articles

A Correlation between isomer shifts of $$^{237}$$Np Moessbauer spectra and coordination numbers of Np atoms in neptunyl(V) compounds

Saeki, Masakatsu; Nakada, Masami; Nakamoto, Tadahiro*; Yamashita, Toshiyuki; ; Krot, N. N.*

Journal of Radioanalytical and Nuclear Chemistry, 239(2), p.221 - 225, 1999/00

 Times Cited Count:5 Percentile:41.94(Chemistry, Analytical)

no abstracts in English

Journal Articles

Coordination chemistry of neptunyl(V) compounds by means of Moessbauer spectroscopy

Saeki, Masakatsu; Nakada, Masami; Nakamoto, Tadahiro*; ; Yamashita, Toshiyuki

Journal of Alloys and Compounds, 271-273, p.176 - 179, 1998/00

 Times Cited Count:4 Percentile:40.44

no abstracts in English

Journal Articles

$$^{237}$$Np Moessbauer spectroscopic study on pentavalent neptunium glycolate complex

Nakamoto, Tadahiro*; Nakada, Masami; ; Saeki, Masakatsu; Yamashita, Toshiyuki

Journal of Radioanalytical and Nuclear Chemistry, 227(1-2), p.137 - 141, 1998/00

 Times Cited Count:2 Percentile:38.16(Chemistry, Analytical)

no abstracts in English

Journal Articles

Synthesis and properties of some neptunyl(V) phthalates

Saeki, Masakatsu; Nakada, Masami; Yamashita, Toshiyuki; Nakamoto, Tadahiro*; Krot, N. N.*

Radiochimica Acta, 80(2), p.89 - 94, 1998/00

no abstracts in English

Oral presentation

Neutron diffraction measurement during stress induced phase transformation

Harjo, S.; Tsuchida, Noriyuki*; Nakamoto, Tatsushi*; Aizawa, Kazuya; Abe, Jun*; Gong, W.

no journal, , 

Oral presentation

Applicability study of laser beam butt welding for pipe structure maintenance with ultrasonic guided wave

Furusawa, Akinori; Nishimura, Akihiko; Torimoto, Kazuhiro; Takenaka, Yusuke*; Toyama, Ryoji*; Nakamoto, Hiroyuki*

no journal, , 

The aim of this work presented here is to investigate the applicability of ultrasonic guided wave for evaluation of laser beam butt welding quality. First, laser beam butt welded pipes are prepared. Two pipes are jointed and continuous wave laser beam is irradiated on the line. The test pipes are divided into two groups according to the difference in laser welding quality. One group is fine quality welded, another group is poor. Second, ultrasonic guided wave testing experiment is performed on the pipes. Torsional mode guided wave is excited by Electromagnetic Acoustic Transducers. Finally, the experimental results are analyzed and issues are discussed. The reflection wave bullet from the poor welded line is clearly observed, whereas no reflection from fine welded line. It is found that the ultrasonic guided wave technologies have the potential for laser beam butt welding line evaluation.

Oral presentation

Water purification influence of aquatic plants naturally growing in the slag accumulation site, Ningyo-toge mine

Yamaji, Keiko*; Nakamoto, Yukihiro*; Haruma, Toshikatsu*; Doyama, Kohei*; Ohara, Yoshiyuki; Tanaka, Kazuya; Fukuyama, Kenjin; Fukushima, Shigeru

no journal, , 

no abstracts in English

Oral presentation

Elucidation of radionuclide ($$^{238}$$U) and heavy metal (Fe, Mn) accumulation mechanism in phragmites australis influenced by root endophytic bacteria

Nakamoto, Yukihiro*; Yamaji, Keiko*; Haruma, Toshikatsu*; Doyama, Kohei*; Ohara, Yoshiyuki; Tanaka, Kazuya; Fukuyama, Kenjin; Fukushima, Shigeru

no journal, , 

no abstracts in English

Oral presentation

Elucidation of uranium and heavy metal (Fe, Mn) accumulation mechanism in ${it Phragmites australis}$ influenced by root endophytic bacteria

Nakamoto, Yukihiro*; Yamaji, Keiko*; Haruma, Toshikatsu; Doyama, Kohei*; Ohara, Yoshiyuki; Fukuyama, Kenjin; Fukushima, Shigeru

no journal, , 

no abstracts in English

Oral presentation

Heavy metal accumulations in ${it Phragmites australis}$ growing at the ore-sedimentary site; Iron plaque formation possibly related to endophytic bacteria

Nakamoto, Yukihiro*; Doyama, Kohei*; Haruma, Toshikatsu*; Lu, X.*; Tanaka, Kazuya; Kozai, Naofumi; Fukuyama, Kenjin; Fukushima, Shigeru; Ohara, Yoshiyuki; Yamaji, Keiko*

no journal, , 

no abstracts in English

17 (Records 1-17 displayed on this page)
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