The Hydrogen-bond network in sodium chloride tridecahydrate; Analogy with ice VI

Yamashita, Keishiro*; Nakayama, Kazuya*; Komatsu, Kazuki*; Ohara, Takashi; Munakata, Koji*; Hattori, Takanori; Sano, Asami; Kagi, Hiroyuki*

Acta Crystallographica Section B; Structural Science, Crystal Engineering and Materials (Internet), 79(5), p.414 - 426, 2023/10

https://doi.org/10.1107/S2052520623007199

The structure of a recently-found hyperhydrated form of sodium chloride, NaCl 13H(D)O, has been determined by single-crystal neutron diffraction at 1.7 GPa and 298 K. It has large hydrogen-bond networks and some water molecules have distorted bonding features such as bifurcated hydrogen bonds and five-coordinated water molecules. The hydrogen-bond network has similarities to ice VI in terms of network topology and disordered hydrogen bonds. Assuming the equivalence of network components connected by pseudo symmetries, the overall network structure of this hydrate can be expressed by breaking it down into smaller structural units which correspond to the ice VI network structure. This hydrogen-bond network contains orientational disorder of water molecules in contrast to the known salt hydrates. Here, we present an example for further insights into a hydrogen-bond network containing ionic species.

PSTEP: Project for solar-terrestrial environment prediction

Kusano, Kanya*; Ichimoto, Kiyoshi*; Ishii, Mamoru*; Miyoshi, Yoshizumi*; Yoden, Shigeo*; Akiyoshi, Hideharu*; Asai, Ayumi*; Ebihara, Yusuke*; Fujiwara, Hitoshi*; Goto, Tadanori*; et al.

Earth, Planets and Space (Internet), 73(1), p.159_1 - 159_29, 2021/12

https://doi.org/10.1186/s40623-021-01486-1

The PSTEP is a nationwide research collaboration in Japan and was conducted from April 2015 to March 2020, supported by a Grant-in-Aid for Scientific Research on Innovative Areas from the Ministry of Education, Culture, Sports, Science and Technology of Japan. It has made a significant progress in space weather research and operational forecasts, publishing over 500 refereed journal papers and organizing four international symposiums, various workshops and seminars, and summer school for graduate students at Rikubetsu in 2017. This paper is a summary report of the PSTEP and describes the major research achievements it produced.

Coexisting spin resonance and long-range magnetic order of Eu in EuRbFeAs

Iida, Kazuki*; Nagai, Yuki; Ishida, Shigeyuki*; Ishikado, Motoyuki*; Murai, Naoki; Christianson, A. D.*; Yoshida, Hiroyuki*; Inamura, Yasuhiro; Nakamura, Hiroki; Nakao, Akiko*; et al.

Physical Review B, 100(1), p.014506_1 - 014506_8, 2019/07

https://doi.org/10.1103/PhysRevB.100.014506

Magnetic excitations and magnetic structure of EuRbFeAs were investigated by neutron scattering measurements.

Improvement of fission gas analyzer

Uehara, Hiroyuki; Komuro, Kazuma; Usami, Koji; Nihei, Yasuo; Nakata, Masahito

Proceedings of 52nd Annual Meeting of Hot Laboratories and Remote Handling Working Group (HOTLAB 2015) (Internet), 5 Pages, 2015/09

For the accurate measurement of the released FP gas during RIA, Gas Chromatograph was improved with the hardware approach and the software one. As the hardware approach, PDD was added to the gas detector of GC and it can detect 50 times higher sensitivity compared with the TCD. As the software approach, ETG function was adopted to deconvolute the overlapped Kr peak from N one. With ETG estimation, Kr volume can be evaluated with the deconvolution from N peak in neither the long measurement time nor the changing measurement condition.

Plan and reports of coupled irradiation (JRR-3 and JOYO of research reactors) and hot facilities work (WASTEF, JMTR-HL, MMF and FMF); R&D project on irradiation damage management technology for structural materials of long-life nuclear plant

Matsui, Yoshinori; Takahashi, Hiroyuki; Yamamoto, Masaya; Nakata, Masahito; Yoshitake, Tsunemitsu; Abe, Kazuyuki; Yoshikawa, Katsunori; Iwamatsu, Shigemi; Ishikawa, Kazuyoshi; Kikuchi, Taiji; et al.

JAEA-Technology 2009-072, 144 Pages, 2010/03

JAEA-Technology-2009-072.pdf:45.01MB

"R&D Project on Irradiation Damage Management Technology for Structural Materials of Long-life Nuclear Plant" was carried out from FY2006 in a fund of a trust enterprise of the Ministry of Education, Culture, Sports, Science and Technology. The coupled irradiations or single irradiation by JOYO fast reactor and JRR-3 thermal reactor were performed for about two years. The irradiation specimens are very important materials to establish of "Evaluation of Irradiation Damage Indicator" in this research. For the acquisition of the examination specimens irradiated by the JOYO and JRR-3, we summarized about the overall plan, the work process and the results for the study to utilize these reactors and some facilities of hot laboratory (WASTEF, JMTR-HL, MMF and FMF) of the Oarai Research-and-Development Center and the Nuclear Science Research Institute in the Japan Atomic Energy Agency.

PIE technique of fuel cladding fracture toughness test

Endo, Shinya; Usami, Koji; Nakata, Masahito; Fukuda, Takuji*; Onozawa, Atsushi; Harada, Akio; Kizaki, Minoru; Kikuchi, Hiroyuki

HPR-366, Vol.1 (CD-ROM), 10 Pages, 2007/03

no abstracts in English

Hydrogen concentration measurement in fuel cladding by backscattered electron image analysis

Onozawa, Atsushi; Harada, Akio; Honda, Junichi; Yasuda, Ryo; Nakata, Masahito; Kanazawa, Hiroyuki; Nishino, Yasuharu

JAEA-Technology 2006-010, 19 Pages, 2006/03

JAEA-Technology-2006-010.pdf:2.3MB

A measurement technique for hydrogen concentration using Backscattered Electron Image analysis (BEI method) had been developed by Studsvik Nuclear AB, Sweden. The hydrides in claddings are identified using BEIs which are imaged with Scanning Electron Microscope, and the hydrogen concentrations are calculated from the area fractions of the hydrides in the matrix. The BEI method is very useful for the measurement in local hydrogen concentrations of fuel claddings. In the Reactor Fuel Examination Facility, a sample preparation, imaging conditions of SEM and image analysis procedures for the BEI method were improved. In addition, the hydrogen concentrations obtained by the improved BEI method and Hot Vacuum Extraction (HVE) method were compared to confirm the reliability of the improved BEI method. The results showed, the improved BEI method has the same reliability as that of HVE method and can be applied for the Post-Irradiation Examination.

Fabrication of instrumented capsule with spent fuel for re-irradiation experiments using NSRR and JMTR

; Nakata, Masahito; ; Kanazawa, Hiroyuki;

ASRR-V: Proc., 5th Asian Symp. on Research Reactors, 2, p.871 - 875, 1996/00

no abstracts in English

R&D project on irradiation damage management technology for structural materials of long-life nuclear plant, 2; Plan and execution of coupling irradiation (JRR-3 and JOYO) and Hot facilities work (WASTEF, JMTR-HL, MMF and FMF)

Matsui, Yoshinori; Nabeya, Hideaki; Kusunoki, Tsuyoshi; Takahashi, Hiroyuki; Aizawa, Masao; Nakata, Masahito; Numata, Masami; Usami, Koji; Endo, Shinya; Ito, Kazuhiro; et al.

no journal, , 

We are proceeding with the study of "R&D Project on Irradiation Damage Management Technology for Structural Materials of Long-life Nuclear Plant". For the study, it is important that the irradiated specimens are gotten by the coupling of JRR-3 and JOYO. This reports the total irradiation plan in the study, and the executed work for the coupling irradiation (JRR-3 and JOYO) including the Hot facilities work of Tokai and Oarai in the 2006 fiscal year.

A Trend of investigation methods for understanding ground flow system

Azuma, Hiroyuki*; Ando, Makoto*; Sakai, Ryutaro; Munakata, Masahiro; Kimura, Hideo

no journal, , 

In the safety assessment for a geological disposal of long-lived radioactive waste such as high-level radioactive waste it is important to develop the method evaluating of groundwater flow effect on the repository system. Japan Atomic Energy Agency has investigated more than 500 literatures to summarize 70 investigative techniques for effectiveness on the evaluation of geological and hydrological environment in the form of two-dimensional matrix table. As a result it demonstrates that electric prospecting techniques have been commonly used for evaluating of the groundwater flow system in the geophysical survey field in the past.