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Iwami, Satone*; Yamashita, Takuma*; Mitsuyasu, Yusuke*; Ono, Kenta*; Oka, Toshitaka; Takahashi, Atsushi*; Kino, Yasushi*; Sekine, Tsutomu*; Shimizu, Yoshinaka*; Chiba, Mirei*; et al.
KEK Proceedings 2024-6, p.91 - 95, 2024/12
We aim to improve the detection limit of the ESR dosimetry method. In this study, the saturation behavior of each radical was investigated by varying the microwave power during ESR measurement. Based on the difference in spin relaxation time between carbonate radicals and native radicals, it is expected that the signal-to-noise ratio improves and the detection limit can be lowered when the microwave power is increased to 4.0 mW.
Yamashita, Takuma*; Iwami, Satone*; Mitsuyasu, Yusuke*; Ono, Kenta*; Oka, Toshitaka; Takahashi, Atsushi*; Kino, Yasushi*; Sekine, Tsutomu*; Shimizu, Yoshinaka*; Chiba, Mirei*; et al.
KEK Proceedings 2024-6, p.85 - 90, 2024/12
To clarify the radiation effects of the accident at the TEPCO's Fukushima Daiichi NPP on living organisms, it is important to accurately estimate the dose to each individual. We have developed a multi-component analysis program using random number optimization to extract only the components derived from carbonate radicals from the ESR spectra.
Kitamura, Yoshimasa; Oka, Toshitaka; Seito, Hajime*; Yokozuka, Eri*; Nagasawa, Naotsugu*; Kitatsuji, Yoshihiro
Radiation Protection Dosimetry, 200(16-18), p.1660 - 1665, 2024/11
Times Cited Count：0 Percentile：0.00(Environmental Sciences)In this work, we evaluated the applicability of hydroxyapatite, which is a main component of tooth enamel, as individual dosimeters that can detect from less than 1 Gy to several tens Gy. Commercially available hydroxyapatite was irradiated by 
Co gamma-ray up to 75 Gy and ESR spectrum of the irradiated sample was observed. The relationship between the intensity of produced carbonated radical and the absorbed dose shows a good linearity (
) from 0 to 75 Gy. The detection limit of this samples was estimated to be 99.7 mGy, and the radical intensity do not change for eight month from the irradiation. These results suggest that this sample can be used as a candidate of the individual dosimeter.
Seito, Hajime*; Yokozuka, Eri*; Oka, Toshitaka; Kitatsuji, Yoshihiro; Nagasawa, Naotsugu*
Radiation Protection Dosimetry, 200(16-18), p.1656 - 1659, 2024/11
Times Cited Count：0 Percentile：0.00(Environmental Sciences)We have examined dosimetric characteristics of bio-inspired carbonated hydroxyapatite (CO
HAp), which is a main component of calcified tissues like tooth enamel. COHAp powder samples were exposed to gamma-ray with radiation doses ranging from 1 Gy to 1000 Gy at room temperature, and ESR spectra were measured immediately after irradiation and subsequently measured each 1 day during 90 days. The post-irradiation fading resulted in significant 20% decay of the signal amplitude, which stabilised within 7 days after irradiation, and the intensity approached a constant. The sample has good linear dose response in the experiment range of 10 Gy - 1000 Gy. Our results indicate that the COHAp materials is suitable for chemical dosimetry.
Yomogida, Takumi; Ouchi, Kazuki; Morii, Shiori; Oka, Toshitaka; Kitatsuji, Yoshihiro; Koma, Yoshikazu; Konno, Katsuhiro*
Scientific Reports (Internet), 14, p.14945_1 - 14945_11, 2024/06
Times Cited Count：1 Percentile：48.55(Multidisciplinary Sciences)Particles containing alpha (
) nuclides were identified from sediment in stagnant water in the Unit 3 reactor building of the Fukushima Daiichi Nuclear Power Station (FDiNPS). We analyzed different concentrations of alpha nuclides samples collected at two sampling sites, torus room and Main steam isolation valve (MSIV) room. Most of the -nuclides in the stagnant water samples of the torus room and the MSIV room were present in particle fractions larger than 10 
m. We detected uranium-bearing particles in m-size by scanning electron microscopy-energy dispersive X-Ray (SEM-EDX) observation. Other short lived -nuclides were detected by alpha track detection. The -nuclide-containing particles with several tens to several hundred m in size were mainly comprised iron (Fe) by SEM-EDX analysis. This study clarifies that the morphologies of U and other -nuclides in the sediment of stagnant water in the FDiNPS's Unit 3 reactor building.
Oka, Toshitaka; Oshima, Akihiro*; Washio, Masakazu*
Radiation Physics and Chemistry, 215, p.111364_1 - 111364_4, 2024/02
Times Cited Count：1 Percentile：30.19(Chemistry, Physical)The polymer electrolyte fuel cell (PEFC) is a promising electrochemical device to produce power through hydrogen and oxygen reaction. It has been expected as a leading future clean power source for a vehicle and a residential power generation. Proton exchange membrane (PEM) is a key material for the performance and the cost of PEFC, development of a high performance and a low-cost PEM is required. Poly(tetrafluoroethylene-co-hexafluoropropylene) (FEP) was irradiated by an electron beam under oxygen-free atmosphere at 25
C, grafted with styrene in liquid phase at 80, and then sulfonated with a mixture of chlorosulfonic acid in carbon-tetrachloride at 25 for 24 h. The free volume size and the o-Ps annihilation probability were affected by not only the amount of the grafted styrene but also the sulfonic acid group.
Morii, Shiori; Yomogida, Takumi; Asai, Shiho*; Ouchi, Kazuki; Oka, Toshitaka; Kitatsuji, Yoshihiro
KEK Proceedings 2023-2, p.132 - 137, 2023/11
New analytical method of a combination of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and isotope dilution mass spectrometry (IDMS) for quantification of Zr isotopes in a solid sample was investigated. Solid Zr-isotope reference was added to a simulated radioactive waste sample as a spike, then Zr isotope ratio was measured by LA-ICP-MS. As a result, we successfully quantify Zr isotopes in the simulated radioactive waste sample by new IDMS. There is a possibility that this new method can be applied for quantification of Zr-93 in difficult to dissolve radioactive wastes.
Morii, Shiori; Yomogida, Takumi; Asai, Shiho*; Ouchi, Kazuki; Oka, Toshitaka; Kitatsuji, Yoshihiro
Bunseki Kagaku, 72(10.11), p.441 - 448, 2023/10
Rapid analytical method for the determination of Zr-93 in radioactive wastes has been developed. Laser ablation (LA)-ICP-MS was applied to the analysis of Zr isotopes in simulated high-level radioactive waste (HLW). Sample preparation time was dramatically reduced by using a DGA resin as the adsorbent for Zr. Direct quantification of Zr isotopes in this resin sample was carried out by LA-ICP-MS. Laser settings were optimized to obtain a reliable isotope ratio of the sample by LA-ICP-MS. Quantification of Zr isotopes in the simulated HLW solution by isotope dilution mass spectrometry (IDMS) was examined. The amount of Zr-90 in the sample obtained by IDMS corresponded to a value calculated from the given concentration of Zr in the sample within uncertainty. Thus, this method can be applied for the quantification of Zr-93 in radioactive wastes.
Toyoda, Shin*; Inoue, Kazuhiko*; Yamaguchi, Ichiro*; Hoshi, Masaharu*; Hirota, Seiko*; Oka, Toshitaka; Shimazaki, Tatsuya*; Mizuno, Hideyuki*; Tani, Atsushi*; Yasuda, Hiroshi*; et al.
Radiation Protection Dosimetry, 199(14), p.1557 - 1564, 2023/09
Times Cited Count：1 Percentile：30.19(Environmental Sciences)Interlaboratory comparison studies are important for radiation dosimetry in order to demonstrate how the technique is universally available. The set of standard samples are examined in each participating laboratory in the present study. After a set of standard samples together with the samples with unknown doses, which were prepared in the same laboratory as the standard samples, are measured at a participating laboratory, those samples are sent to another participating laboratory for next measurement. There is some small difference observed in the sensitivity (the slope of the dose response line) of the standard samples while the differences in the obtained doses for the samples with unknown doses are rather systematic, implying that the difference is mostly due to the samples but not to measurements.
Mitsuyasu, Yusuke*; Oka, Toshitaka; Takahashi, Atsushi*; Kino, Yasushi*; Okutsu, Kenichi*; Sekine, Tsutomu*; Yamashita, Takuma*; Shimizu, Yoshinaka*; Chiba, Mirei*; Suzuki, Toshihiko*; et al.
Radiation Protection Dosimetry, 199(14), p.1620 - 1625, 2023/09
Times Cited Count：1 Percentile：30.19(Environmental Sciences)We have been conducting dose assessments for Japanese macaques captured in Fukushima to reveal radiobiological effects on the low-dose expose animals. To accurately determine the external exposure dose, it is desirable to examine the analysis of the CO
radical intensity. We examined ESR spectra of teeth of 10 macaques captured in Fukushima by two spectrum-decomposition algorithms.
Goto, Aki*; Michishio, Koji*; Oka, Toshitaka; Tagawa, Masahito*; Yamashita, Shinichi*
Langmuir, 39(34), p.11954 - 11963, 2023/08
Times Cited Count：1 Percentile：13.12(Chemistry, Multidisciplinary)Atomic oxygen (AO) is one of the dominant components of the residual atmosphere in low Earth orbit. AO collides with spacecraft with translational energy of 5 eV, forming nanoscale protrusions on polymeric materials. This study investigated the size of free-volume holes and the layer thickness that interacted with AO for polyethylene (PE), polypropylene (PP), and polystyrene (PS) by positron annihilation lifetime spectroscopy. By the AO irradiation, oxidized layer formed in the surface, and the maximum depth of the oxidized layer for PE and PP were deeper than for PS. The different sizes of free-volume holes would affect the injection depths of AO, resulting in the oxidized layers' thicknesses and surface morphologies.
Oka, Toshitaka
Shitterutsumori No Hoshasen Dokuhon , p.215 - 216, 2023/04
In relation to the estimation of external doses to wild Japanese macaques using ESR dosimetry, the history, principles, and sample preparation methods of ESR dosimetry are described.
Kobayashi, Yoshinori*; Sato, Kiminori*; Yamawaki, Masato*; Michishio, Koji*; Oka, Toshitaka; Washio, Masakazu*
Radiation Physics and Chemistry, 202, p.110590_1 - 110590_6, 2023/01
Times Cited Count：6 Percentile：71.68(Chemistry, Physical)Because of their different charge states, positrons and positronium (Ps) behave quite differently in macromolecules. The behavior of positively charged positrons is strongly influenced by electrostatic interactions. In nonpolar macromolecules such as polyethylene, energetic positrons, if not incorporated into Ps, fall into a delocalized state. These positrons are sensitively trapped by polar groups, if any. On the other hand, charge-neutral Ps is localized in a free volume regardless of the macromolecule's chemical structure. In this study, we discuss the behavior and annihilation characteristics of positrons and Ps in various macromolecules, emphasizing their differences.
Okutsu, Kenichi*; Yamashita, Takuma*; Kino, Yasushi*; Miyashita, Konan*; Yasuda, Kazuhiro*; Oka, Toshitaka; Okada, Shinji*; Sato, Motoyasu*
JJAP Conference Proceedings (Internet), 9, p.011003_1 - 011003_7, 2023/00
Muon catalyzed fusion (CF) is a cyclic reaction where a negatively charged muon itself acts like a catalyst of nuclear fusion between hydrogen isotopes. In the CF reaction, muon transfer from deuteron to triton and muonic molecular formation are rate-limiting processes. In this work, we have investigated the role of resonance states of muonic molecule in the CF which affects the muonic deuterium atom population. Solving simultaneous rate equations numerically by the fourth-order Runge-Kutta method, we determined the muonic molecular formation rate so that the number of fusion events reproduces a latest experimental result. It is revealed that the resonance states play a role to enhance the fusion rate by accelerating the de-excitation of the muonic atoms.
Oka, Toshitaka
Isotope News, (784), p.43 - 44, 2022/12
We participated in Young Scientists Project Career Paths for Researchers held at the 59th Isotope and Radiation Research Presentation Meeting, where we heard from four lecturers and discussed how to encourage students to enter doctoral programs.
Ishikawa, Ryoya*; Suzuki, Masatoshi*; Kino, Yasushi*; Endo, Satoru*; Nakajima, Hiroo*; Oka, Toshitaka; Takahashi, Atsushi*; Shimizu, Yoshinaka*; Suzuki, Toshihiko*; Shinoda, Hisashi*; et al.
KEK Proceedings 2022-2, p.61 - 66, 2022/11
The balance between oxidative stress and antioxidant activity, which is a defense mechanism against oxidative stress, was investigated in the liver and bladder of wild Japanese macaques captured in Fukushima Prefecture. No significant induction of oxidative stress by exposure to environmental radionuclides after the Fukushima nuclear accident was observed, suggesting that the stress defense mechanism of the organism is activated in some organs.
Mitsuyasu, Yusuke*; Oka, Toshitaka; Takahashi, Atsushi*; Kino, Yasushi*; Okutsu, Kenichi*; Sekine, Tsutomu*; Yamashita, Takuma*; Shimizu, Yoshinaka*; Chiba, Mirei*; Suzuki, Toshihiko*; et al.
KEK Proceedings 2022-2, p.120 - 125, 2022/11
We investigate the effect of sample's anisotropy and measurement condition to obtain the higher reproducibility for the shape of the ESR spectrum and the intensity of CO radical.
Kobayashi, Yoshinori*; Sato, Kiminori*; Yamawaki, Masato*; Michishio, Koji*; Oka, Toshitaka; Washio, Masakazu*
Applied Physics Express, 15(7), p.076001_1 - 076001_4, 2022/07
Times Cited Count：2 Percentile：17.73(Physics, Applied)We discuss the energy dissipation of short-lived 
-positronium (
-Ps) in polymers and silica glass. The 
parameter characterizing the Doppler broadening of -Ps annihilation is determined from the previously reported systematic data of positron annihilation age momentum correlation for various polymers and silica glass. A comparison of the parameter with that expected for thermalized -Ps trapped in a free volume reveals that -Ps is not thermalized and possesses excess energy in fluorinated polymers and silica glass, indicating that it is difficult for Ps to lose energy in substances containing heavy elements such as fluorine and silicon.
Oka, Toshitaka; Takahashi, Atsushi*; Koarai, Kazuma; Kino, Yasushi*; Sekine, Tsutomu*; Shimizu, Yoshinaka*; Chiba, Mirei*; Suzuki, Toshihiko*; Osaka, Ken*; Sasaki, Keiichi*; et al.
Journal of Radiation Research (Internet), 63(4), p.609 - 614, 2022/07
Times Cited Count：3 Percentile：38.30(Biology)Electron spin resonance (ESR) dosimetry is one of the most powerful tools for radiation dose reconstruction. The detection limit of this technique using human teeth is reported to be 56 mGy or 67 mGy; however, the absorbed dose of Fukushima residents after the Fukushima Daiichi Nuclear Power Plant (FNPP) accident was estimated to be lower than this detection limit. Our aim is to assess the absorbed radiation dose of children in Fukushima Prefecture after the accident; therefore, it is important to estimate the detection limit for their teeth. The detection limit for enamel of deciduous teeth of Japanese children separated by the mechanical method is estimated to be 115.0 mGy. The density separation method can effectively separate enamel from third molars of Japanese people. As we have collected thousands of teeth from children in Fukushima, the present technique may be useful to examine their external absorbed dose after the FNPP accident.
Yomogida, Takumi; Ouchi, Kazuki; Oka, Toshitaka; Kitatsuji, Yoshihiro; Koma, Yoshikazu; Konno, Katsuhiro*
Scientific Reports (Internet), 12(1), p.7191_1 - 7191_10, 2022/05
Times Cited Count：8 Percentile：55.35(Multidisciplinary Sciences)Particles containing alpha () nuclides were identified from sediment in stagnant water at the torus room of the Fukushima Dai-ichi Nuclear Power Station (FDiNPS)'s Unit 2 reactor. Several uranium-bearing particles were identified by SEM observation. These particles contained Zr and other elements which constituted fuel cladding and structural materials. The 
U/
U isotope ratio in the solid fractions that included U particles was consistent with the nuclear fuel in the Unit 2 reactor, which indicated that the U particles had been derived from nuclear fuel. The particles with alpha-emitters detected by alpha track analysis were several tens to several hundred m in size. The EDX spectra showed that these particles mainly comprised iron, which indicated Pu, Am, and Cm were adsorbed on the Fe-baring particles. This study clarifies that the major morphologies of U and other -nuclides were differed in the sediment of stagnant water in the torus room of FDiNPS's Unit 2 reactor.
