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糸井 弘行*; Ninomiya, Takeru*; 長谷川 英之*; Maki, Shintaro*; Sakakibara, Akihiro*; 鈴木 隆太郎*; 笠井 湧斗*; 岩田 博之*; 松村 大樹; 大和田 真生*; et al.
Journal of Physical Chemistry C, 124(28), p.15205 - 15215, 2020/07
被引用回数:9 パーセンタイル:38.71(Chemistry, Physical)We demonstrate reversible charge/discharge in ruthenocene, RuCp (Cp = -CH), using activated carbon (AC) as a support. Upon subsequent electrochemical oxidation using an aqueous HSO electrolyte, the clusters are disassembled and the RuCp molecules are finely dispersed in the micropores. The resulting RuCp has a large contact area with conductive carbon surfaces, thereby realizing rapid charge transfer at the contact interface. Consequently, rapid charge storage occurs via the reversible redox reaction of the supported RuCp in aqueous HSO without dimerization or disproportionation reactions, which is confirmed by X-ray absorption spectroscopy. Since hybridization can produce different properties of the host and guest materials, their infinite combinations would have the possibility to yield properties far surpassing those of existing materials.
榊原 安英; 磯村 和利; 山下 卓哉; 渡士 克己; 土井 基尾; 大草 享一; 田川 明広; 平原 謙司
日本保全学会第3回学術講演会要旨集, p.283 - 286, 2006/06
原子力発電所の高経年化対策の充実を図るために、原子力学会の高経年化に関するロードマップに沿って、調査研究を、長期運転プラントや研究機関等が集積化する福井県下で実施した。